Propoxur (ISO)
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Propoxur (ISO) Eigenschaften
- Schmelzpunkt:
- 91°C
- Siedepunkt:
- 348.6°C (rough estimate)
- Dichte
- 1.1200
- Dampfdruck
- 1.3 x 10-3 Pa (20 °C)
- Brechungsindex
- 1.5080 (estimate)
- Flammpunkt:
- -18 °C
- storage temp.
- 2-8°C
- L?slichkeit
- Chloroform: slightly; Methanol: slightly
- pka
- 12.28±0.46(Predicted)
- Aggregatzustand
- Minute Crystals
- Farbe
- White to off-white
- Wasserl?slichkeit
- Slightly soluble. 0.2 g/100 mL
- Merck
- 13,7929
- BRN
- 1879891
- Expositionsgrenzwerte
- OSHA TWA: 0.5 mg/m3; ACGIH TLV: TWA 0.5 mg/m3.
- CAS Datenbank
- 114-26-1
- NIST chemische Informationen
- 2-Isopropoxyphenyl N-methylcarbamate(114-26-1)
- EPA chemische Informationen
- Propoxur (114-26-1)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher | T;N,N,T,Xn,F | ||
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R-S?tze: | 25-50/53-67-65-38-11 | ||
S-S?tze: | 37-45-60-61-62 | ||
RIDADR | UN 2811/2588 | ||
OEB | C | ||
OEL | TWA: 0.5 mg/m3 | ||
WGK Germany | 3 | ||
RTECS-Nr. | FC3150000 | ||
HazardClass | 6.1(b) | ||
PackingGroup | III | ||
Giftige Stoffe Daten | 114-26-1(Hazardous Substances Data) | ||
Toxizit?t | LD50 orally in male, female rats: 83, 86 mg/kg (Gaines) |
Bildanzeige (GHS) |
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Propoxur (ISO) Chemische Eigenschaften,Einsatz,Produktion Methoden
ERSCHEINUNGSBILD
WEISSES, KRISTALLINES PULVER.CHEMISCHE GEFAHREN
Zersetzung beim Erhitzen oder Verbrennen unter Bildung giftiger Rauche mit Methylisocyanat und Stickstoffoxiden.ARBEITSPLATZGRENZWERTE
TLV: 0.5 mg/m?(als TWA); Krebskategorie A3 (best?tigte krebserzeugende Wirkung beim Tier mit unbekannter Bedeutung für den Menschen); BEI vorhanden; (ACGIH 2005).MAK: (Einatembare Fraktion) 2 mg/m? Spitzenbegrenzung: überschreitungsfaktor II(8); (DFG 2005).
AUFNAHMEWEGE
Aufnahme in den K?rper durch Inhalation, über die Haut und durch Verschlucken.INHALATIONSGEFAHREN
Verdampfung bei 20°C vernachl?ssigbar; eine gesundheitssch?dliche Partikelkonzentration in der Luft kann jedoch beim Versprühen oder Dispergieren schnell erreicht werden, vor allem als Pulver.WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION:M?glich sind Auswirkungen auf Nervensystem, Leber und Nieren mit nachfolgendem Atemversagen, Kr?mpfen und Gewebesch?den. Cholinesterasehemmer. Exposition kann zum Tod führen.
LECKAGE
NICHT in die Kanalisation spülen. Verschüttetes Material in abdichtbaren Beh?ltern sammeln; falls erforderlich durch Anfeuchten Staubentwicklung verhindern. Reste sorgf?ltig sammeln. An sicheren Ort bringen. Pers?nliche Schutzausrüstung: Vollschutzanzug mit umgebungsluftunabh?ngigem Atemschutzger?t.R-S?tze Betriebsanweisung:
R25:Giftig beim Verschlucken.R50/53:Sehr giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.
R67:D?mpfe k?nnen Schl?frigkeit und Benommenheit verursachen.
R65:Gesundheitssch?dlich: kann beim Verschlucken Lungensch?den verursachen.
R38:Reizt die Haut.
R11:Leichtentzündlich.
S-S?tze Betriebsanweisung:
S37:Geeignete Schutzhandschuhe tragen.S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Beh?lter sind als gef?hrlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S62:Bei Verschlucken kein Erbrechen herbeiführen. Sofort ?rztlichen Rat einholen und Verpackung oder dieses Etikett vorzeigen.
Beschreibung
Propoxur, 2-isopropoxyphenyl methylcarbamate (IUPAC),forms colorless crystals, which are moderately soluble in most organic solvents.Chemische Eigenschaften
Propoxur is a white to tan crystalline solid or powder. Faint characteristic odorVerwenden
Propoxur is a non-systematic carbamate insecticide. Propoxur is used against a wide range of insects such as fleas, mosquitoes, ants, gypsy moths, and other agricultural pests. Propoxur functions by r eversibly inactivating the enzyme acetylcholinesterase in insects.Definition
ChEBI: A carbamate ester that is phenyl methylcarbamate substituted at position 2 by a propan-2-yloxy group.synthetische
Propoxur is prepared by reaction of 2-isopropoxyphenol with methylisocyanate.Allgemeine Beschreibung
White to tan crystalline powder with a faint, characteristic odor. Used as an insecticide.Reaktivit?t anzeigen
Propoxur is incompatible with the following: Strong oxidizers, alkalis [Note: Emits highly toxic methyl isocyanate fumes when heated to decomposition.] .Hazard
Toxic by ingestion and inhalation. Cholinesterase inhibitor. Possible carcinogen.Health Hazard
A highly toxic substance by ingestion, andpossibly by most other routes of exposure;moderately toxic by inhalation and skin contact; cholinesterase inhibitor; toxic effects aresimilar to those of other carbamate pesticidesand include excessive salivation, lacrimation, slow heart rate, blurred vision, twitchingof muscle and lack of coordination, nausea,weakness, diarrhea and abdominal pain; oralintake of probably 1.5–3 g could be fatal toadult humans; a teratogenic substance, producing adverse reproductive effects in experimental animals.LD50 oral (rat): 70 mg/kg
LD50 skin (rat): 800 mg/kg
LC50 inhalation (rat): 1440 mg/m3/1 hr.
Landwirtschaftliche Anwendung
Insecticide, Molluscicide: Not approved for use in EU countries. A non-systemic insecticide compatible with most fungicides and insecticides except those that are alkaline. It is often used in combination with azinphosmethyl, chlorpyrifos, cyfluthrin, dichlorvos, disulfoton or methocarb. It is used on sugar cane, cocoa, pome and stone fruit, grapes, maize, hops, rice, sugar beets, vegetables, cotton, and forestry and ornamentals to control pests such as chewing and sucking insects, ants, crickets, flies, mosquitoes, millepedes, jassids and cockroaches.Handelsname
(There are currently 695 registered active and/or canceled and/or transferred products in the U.S.) ARPROCARB®; BAY®; BAY® 5122; BAYER®; BAYER® B 5122; BAYGON®; BIFEX®; BLATTANEX®; BLATTOSEP®; BOLFO®; BO Q 5812-315®; BORUHO®; BORUHO® 50; BRIFUR®; BRYGOU®; CHEMAGRO® 9010; COMPOUND 39007; DALF DUST®; INVISI-GARD®; PILLARGON®; PRENTOX CARBAMATE®; PROPOGON®; PROPOTOX®; PROPOXYLOR®; PROPYON®; RHODEN®; SENDRAN®; SUNCIDE®; TENDEX®; TUGEN®; UNDEN®; UNDENE®m?gliche Exposition
Personnel engaged in the manufacture, formulation and application of this organonitrogen agricul- tural chemical and pesticide.Environmental Fate
Groundwater. According to the U.S. EPA (1986) propoxur has a high potential to leach to groundwater.Photolytic. Though no products were identified, the half-life in UV irradiated water (λ >290 nm) was 87.9 hours (Jensen-Korte et al., 1987). When propoxur in ethanol was irradiated by UV light, only one unidentified cholinesterase inhibitor formed. Exposure to sunlight for 3 hours yielded no photodecomposition products (Crosby et al., 1965).
Chemical/Physical. Decomposes at elevated temperatures forming methyl isocyanate (Windholz et al., 1983) and nitrogen oxides (Lewis, 1990). Hydrolyzes in water to 1- naphthol and 2-isopropoxyphenol (Miles et al., 1988). At pH 6.9, half-lives of 78 and 124 days were reported under aerobic and anaerobic conditions, respectively (Kanazawa, 1987). Miles et al. (1988) studied the rate of hydrolysis of propoxur in phosphate-buffered water (0.01 M) at 26°C with and without a chlorinating agent (10 mg/L hypochlorite solution). The hydrolysis half-lives at pH 7 and 8 with and without chlorine were 3.5 and 10.3 days and 0.05 and 1.2 days, respectively (Miles et al., 1988). The reported hydrolysis half-lives of propoxur in water at pH 8, 9 and 10 were 16.0 days, 1.6 days and 4.2 hours, respectively (Aly and El-Dib, 1971). In a 0.50 N sodium hydroxide solution at 20°C, the hydrolysis half-life was reported to be 3.0 days (El-Dib and Aly, 1976).
Stoffwechselwegen
The principal pathways of propoxur metabolism in plants and animals are deisopropylation, hydrolysis of the carbamate ester to form a phenol and conjugation. Minor metabolites are formed by hydroxylation of the N-methyl group and the phenyl ring. Only insects form metabolites hydroxylated at the isopropoxy group.Versand/Shipping
UN2757 Carbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.Inkompatibilit?ten
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo- sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, alkalis, heat, and mois- ture. Emits highly toxic methyl isocyanate fumes when heated to decomposition.Waste disposal
In accordance with 40CFR165, follow recommendations for the disposal of pes- ticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contact- ing your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations govern- ing storage, transportation, treatment, and waste disposal.Propoxur (ISO) Upstream-Materialien And Downstream Produkte
Upstream-Materialien
METHYL ISOCYANATE
2-Brompropan
Methylamin, gasf?rmig
Chlor
Kaliumcarbonat
Chloroformate
N,N-Diethylethanamin
Methylisocyanat
Methylcarbamoylchlorid
Tetrachlormethan
1,4-Dioxan
1,2-Dihydroxybenzol
Ethandiol
Dilute hydrochloric acid
2-Isopropylphenol
o-Isopropoxyphenol
Ligroin
Carbaryl (ISO)
2-Chlorpropan
Downstream Produkte
Propoxur (ISO) Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 252)Lieferanten
Firmenname | Telefon | Land | Produktkatalog | Edge Rate | |
---|---|---|---|---|---|
Shaanxi TNJONE Pharmaceutical Co., Ltd | +86-17396673057 |
linda@tnjone.com | China | 1143 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21628 | 55 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28172 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22963 | 58 |
Alchem Pharmtech,Inc. | 8485655694 |
sales@alchempharmtech.com | United States | 63687 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49732 | 58 |
SIMAGCHEM CORP | +86-13806087780 |
sale@simagchem.com | China | 17346 | 58 |
TargetMol Chemicals Inc. | +1-781-999-5354 +1-00000000000 |
marketing@targetmol.com | United States | 32268 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 |
sales@tnjchem.com | China | 34563 | 58 |
HANGZHOU CLAP TECHNOLOGY CO.,LTD | 86-571-88216897,88216896 13588875226 |
sales@hzclap.com | CHINA | 6312 | 58 |
114-26-1(Propoxur (ISO))Verwandte Suche:
3-Aminophenol
Phenol
Urethan
POLYURETHANE
Phenolrot
Methylanthranilat
4-Aminobenzoesure
2-Aminophenol
Methylcarbamat
Anthranilic acid
Bendiocarb (ISO)
2,3-Dihydro-2,2-dimethyl-7-benzofuryl-2,4-dimethyl-6-oxa-5-oxo-3-thia-2,4-diazadecanoat
Carbosulfan
Carbofuran (ISO)
Propoxur (ISO)
- PROPOXUR (2-ISOPROPOXYPHENYL METHYL CARBAMATE)
- Propoxur (ISO)
- propoxur (ISO) 2-isopropyloxyphenyl N-methylcarbamate 2-isopropoxyphenyl methylcarbamate
- Baygon(R)
- (2-propan-2-yloxyphenyl) N-methylcarbamate
- N-methylcarbamic acid (2-isopropoxyphenyl) ester
- Baygon (TM) 1g [114-26-1]
- Baygon,Propoxur,
- 2-(1-Methylethoxy)phenol 1-(N-MethylcarbaMate)
- Baygon G
- bay39007
- bay5122
- bay9010
- Bayer B 5122
- bayerb5122
- Bifex
- Blattanex
- Blattanex 20
- Blattosep
- Bolfo
- Boruho
- Boruho 50
- Boygon
- Brygou
- Carbamic acid, methyl-, 2-(1-methylethoxy)phenyl ester
- Carbamic acid, methyl-, o-isopropoxyphenyl ester
- Chemagro 9010
- chemagro9010
- Dalf Dust
- n-methylcarbamicacid,2-(1-methylethoxy)phenylester
- n-methylcarbamicacid,o-isopropoxyphenylester
- O-(2-Isopropoxyphenyl) N-methylcarbamate
- o-(2-isopropoxyphenyl)n-methylcarbamate
- o-Impc
- o-isopropoxy-phenomethylcarbamate
- o-Isopropoxyphenyl N-methylcarbamate
- o-isopropoxyphenyln-methylcarbamate
- OMS 33
- oms33
- oms-33
- phc(carbamate)
- phc7
- Phenol, o-isopropoxy-, methylcarbamate
- phenol,2-(1-methylethoxy)-,methylcarbamate
- Pillargon
- Propoksuru
- propoksuru(polish)
- Propotox
- Propotox M
- Propoxylor
- Propyon
- Rhoden
- Sendran
- Suncide
- Tendex
- Tugen
- Tugon fliegenkugel
- tugonfliegenkugel