| Identification | More | [Name]
1,1-Dimethylpropargylamine | [CAS]
2978-58-7 | [Synonyms]
1,1-DIMETHYL-PROP-2-YNYLAMINE
1,1-DIMETHYLPROPARGYLAMINE
2-AMINO-2-METHYLBUTYN-1
3-AMINO-3-METHYL-1-BUTYNE
3-AMINO-3-METHYLBUTYNE
CBI-BB ZERO/005787
TIMTEC-BB SBB000001
1,1-dimethyl-2-propynylamin
1,1-Dimethyl-2-propynylamine
1,1-dimethylpropynylamine
2-methyl-3-butyn-2-amin
2-methyl-3-Butyn-2-amine
30-d-11
1,1-dimethylprop-3-ynylamine
3-AMINI-3-METHYL-1-BUTYNE
1,1-Dimethylpropargylamine, 90% ( remainder water)
1,1-Dimethyl-2-propynyl-1-amine
1,1-Dimethylpropargylamine, 3-Amino-3-methyl-1-butyne
1,1-Dimethyl-2-propyn-1-amine
2-Methylbut-3-yn-2-amine | [EINECS(EC#)]
221-029-7 | [Molecular Formula]
C5H9N | [MDL Number]
MFCD00008052 | [Molecular Weight]
83.13 | [MOL File]
2978-58-7.mol |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,C,F | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R34:Causes burns.
R22:Harmful if swallowed.
R11:Highly Flammable.
R43:May cause sensitization by skin contact. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
UN 2733 | [WGK Germany ]
3 | [RTECS ]
ER9543533 | [TSCA ]
Yes | [HazardClass ]
3.1 | [PackingGroup ]
II | [HS Code ]
29211999 | [Toxicity]
LD50 oral in rat: 1470mg/kg |
| Hazard Information | Back Directory | [Hazard]
Moderately toxic by ingestion. A moderate
eye irritant. | [Chemical Properties]
Clear colorless to yellow liquid | [Uses]
1,1-Dimethylpropargylamine is used as an organic chemical synthesis intermediate. | [Purification Methods]
Dissolve the amine in Et2O, dry over anhydrous K2CO3, filter, evaporate and distil (preferably under N2). Store it away from CO2. The hydrochloride [2978-59-8] has m 234o (from EtOH/Et2O). The benzoyl derivative has m 152-153o (from EtOH). [Hennion & Teach J Am Chem Soc 75 1653 1953, Hennion & DiGiovanna J Org Chem 30 2645 1965.] |
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