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ChemicalBook--->CAS DataBase List--->462-08-8

462-08-8

462-08-8 Structure

462-08-8 Structure
IdentificationMore
[Name]

3-Aminopyridine
[CAS]

462-08-8
[Synonyms]

3-AMINOPYRIDINE
3APY
3-pyridinamine
3-PYRIDYLAMINE
AKOS 90977
AMINOPYRIDINE, 3-
BETA-AMINOPYRIDINE
B-PYRIDYLAMINE
m-Aminopyridine
PYRIDIN-3-YLAMINE
TIMTEC-BB SBB004395
3-amino-pyridin
Amino-3 pyridine
amino-3pyridine
Pyridine, 3-amino-
3-AMINOPYRIDINE PESTANAL
3-AMINOPYRIDINE 99+%
AMINOPYRIDINE, 2-(PRIMARY STANDARD)
3-AMINO PYRIDINE FOR SYNTHESIS
pyridin-3-amine
[EINECS(EC#)]

207-322-2
[Molecular Formula]

C5H6N2
[MDL Number]

MFCD00006400
[Molecular Weight]

94.11
[MOL File]

462-08-8.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powder
[Melting point ]

60-63 °C(lit.)
[Boiling point ]

248 °C(lit.)
[density ]

1.0308 (estimate)
[refractive index ]

1.5560 (estimate)
[Fp ]

124 °C
[storage temp. ]

Poison room
[solubility ]

>1000g/l
[form ]

Liquid
[pka]

6.04(at 25℃)
[color ]

Clear colorless to yellow
[PH]

10 (100g/l, H2O, 20℃)
[Water Solubility ]

It is soluble in water as well as soluble in alcohol, benzene.
[Sensitive ]

Air Sensitive & Hygroscopic
[Detection Methods]

GC,NMR
[Merck ]

14,473
[BRN ]

105692
[InChIKey]

CUYKNJBYIJFRCU-UHFFFAOYSA-N
[LogP]

0.110
[CAS DataBase Reference]

462-08-8(CAS DataBase Reference)
[NIST Chemistry Reference]

3-Pyridinamine(462-08-8)
[EPA Substance Registry System]

462-08-8(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T,Xi
[Risk Statements ]

R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R33:Danger of cumulative effects.
R36/37/38:Irritating to eyes, respiratory system and skin .
R25:Toxic if swallowed.
[Safety Statements ]

S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RIDADR ]

UN 2671 6.1/PG 2
[WGK Germany ]

3
[RTECS ]

US1650000
[F ]

3-8-9-23
[Hazard Note ]

Toxic/Irritant
[TSCA ]

T
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

29333999
[Safety Profile]

Poison by ingestion, intraperitoneal, subcutaneous, and intravenous routes. When heated to decomposition it emits toxic fumes of NOx,.
[Toxicity]

LD50 ipr-mus: 28 mg/kg JMCMAR 8,296,65
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Potassium hydroxide-->tert-Butanol-->Aluminum oxide-->Nicotinamide-->Lead tetraacetate-->3-Piperidinamine, 6-chloro--->Sulfuric acid-->2-Chloro-5-nitropyridine-->5-Amino-2-chloropyridine-->5-Amino-2-bromopyridine
[Preparation Products]

3-IODO-2-NITROPYRIDINE-->6-BROMO-2-METHOXY-PYRIDIN-3-YLAMINE-->N-(4-FORMYL-PYRIDIN-3-YL)-2,2-DIMETHYL-PROPIONAMIDE-->TERT-BUTYL 4-FORMYLPYRIDIN-3-YLCARBAMATE-->Pirenzepine-->2,6-Dichloropyridin-3-amine-->3-HYDRAZINOPYRIDINE Dihydrochloride-->3-Iodopyridine-->2,6-Dibromopyridin-3-amine-->1,5-NAPHTHYRIDINE-2-CARBOXYLICACID -->2-Chloro-3-fluoropyridine-->2,6-Dibromopyridine
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

3-Pyridinamine(462-08-8).msds
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powder
[Uses]

3-Aminopyridine is a monosubstituted pyridine that shows convulsive effects on cortical Neurons. 3-Aminopyridine is used in the synthesis of of organic ligand 3-Pyridylnicotinamide. 3-Aminopyridine al ong with other aminopyridines have been shown to reversibly block voltage-dependent potassium channels,
[Uses]

manufacture of pharmaceuticals and dyes.
[Synthesis Reference(s)]

Tetrahedron Letters, 39, p. 1313, 1998 DOI: 10.1016/S0040-4039(97)10877-2
The Journal of Organic Chemistry, 57, p. 5254, 1992 DOI: 10.1021/jo00045a047
[Purification Methods]

It crystallises from *benzene, CHCl3/pet ether (b 60-70o), or *benzene/pet ether (4:1). [Beilstein 22/9 V 3.]
Spectrum DetailBack Directory
[Spectrum Detail]

3-Aminopyridine(462-08-8)MS
3-Aminopyridine(462-08-8)1HNMR
3-Aminopyridine(462-08-8)13CNMR
3-Aminopyridine(462-08-8)IR1
3-Aminopyridine(462-08-8)IR2
3-Aminopyridine(462-08-8)IR3
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

3-Aminopyridine, 99%(462-08-8)
[Alfa Aesar]

3-Aminopyridine, 99%(462-08-8)
[Sigma Aldrich]

462-08-8(sigmaaldrich)
[TCI AMERICA]

3-Aminopyridine,>99.0%(GC)(T)(462-08-8)
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