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ChemicalBook--->CAS DataBase List--->15879-93-3

15879-93-3

15879-93-3 Structure

15879-93-3 Structure
IdentificationMore
[Name]

alpha-Chloralose
[CAS]

15879-93-3
[Synonyms]

1,2-O-[2,2,2-TRICHLOROETHYLIDENE]-ALPHA-D-GLUCOFURANOSE
1,2-O-(2,2,2-TRICHLOROETHYLIDENE)-D-GLUCOFURANOSE
A-CHLORALOSE
A-D-GLUCOCHLORALOSE
A-D-GLUCOCHLOROLOSE
ALFA-4(R)
ALFAMAT(R)
ALFA Z(R)
ALPHA-CHLORALOSE
ALPHA-D-CHLORALOSE
ALPHA-D-(+)-GLUCOCHLORALOSE
ALPHA-D-GLUCOCHLORALOSE
ANHYDRO-D-GLUCOCHLORAL
ANHYDROGLUCOCHLORAL
CHLORALOSE
CHLORALOSE, A-
GLUCOCHLORAL
GLUCOCHLORALOSE
(R)-1,2-O-(2,2,2-TRICHLOROETHYLIDENE)-A-D-GLUCOFURANOSE
(r)-1,2-o-(2,2,2-trichloroethylidene)-alpha-d-glucofuranose
[EINECS(EC#)]

240-016-7
[Molecular Formula]

C8H11Cl3O6
[MDL Number]

MFCD00005542
[Molecular Weight]

309.53
[MOL File]

15879-93-3.mol
Chemical PropertiesBack Directory
[Appearance]

needle-like crystals or powder
[Melting point ]

178-182 °C
[alpha ]

18 º (c=2, 95% C2H5OH)
[Boiling point ]

424.33°C (rough estimate)
[density ]

1.6066 (rough estimate)
[vapor pressure ]

Negligible at room temperature
[refractive index ]

1.5320 (estimate)
[solubility ]

ethanol: 10 mg/mL or yellow-brown, clear to slightly hazy, colorless to faintly yellow
[form ]

neat
[pka]

12.89±0.60(Predicted)
[color ]

White to Almost white
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[optical activity]

[α]20/D +17±2°, 5 hr, c = 2% in ethanol
[Water Solubility ]

0.44 g/100 mL (15 ºC)
[Merck ]

14,2072
[BRN ]

85418
[LogP]

1.020
[Uses]

Coating seeds to protect them from birds.
[CAS DataBase Reference]

15879-93-3(CAS DataBase Reference)
[EPA Substance Registry System]

15879-93-3(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20/22:Harmful by inhalation and if swallowed .
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S24/25:Avoid contact with skin and eyes .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
[RIDADR ]

3249
[WGK Germany ]

1
[RTECS ]

FM9450000
[TSCA ]

Yes
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[HS Code ]

29400090
[Safety Profile]

Poison by ingestion, subcutaneous, and intraperitoneal routes. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of Cl-.
[Toxicity]

LD50 orally in mice: 400 mg/kg (Schafer)
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1,2-O-(2,2,2-Trichloroethylidene)-alpha-D-glucofuranose(15879-93-3).msds
Hazard InformationBack Directory
[Hazard]

May cause addiction, highly toxic.
[Description]

Chloralose, (R)-1,2-O-(2,2,2-trichloroethylidene)- α-D-glucofuranose, is a crystalline powder which is soluble in water, fairly soluble in alcohol, diethyl ether, glacial acetic acid, sparingly soluble in chloroform, practically insoluble in petroleum ether.
Chloralose is produced by reaction of glucose with waterfree chloral under heating (21).
[Chemical Properties]

needle-like crystals or powder
[Metabolic pathway]

Chloralose is effectively a chloral generator which, in turn, affords trichloroethanol by metabolism. This is the narcotic agent. Sleep is induced in mice before death and therefore the compound is regarded as a humane mouse killer. It is particularly effective when a quick clearout is required but there is evidence that mice can become tolerant.
[Degradation]

Chloralose is hydrolysed by acid and base to glucose and chloral (2, trichloroacetaldehyde).
Spectrum DetailBack Directory
[Spectrum Detail]

α-Chloralose(15879-93-3)MS
α-Chloralose(15879-93-3)1HNMR
α-Chloralose(15879-93-3)IR1
α-Chloralose(15879-93-3)IR2
α-Chloralose(15879-93-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

alpha-Chloralose, 97%(15879-93-3)
[Alfa Aesar]

alpha-Chloralose, 98+%, beta anomer ca 15%(15879-93-3)
[Sigma Aldrich]

15879-93-3(sigmaaldrich)
[TCI AMERICA]

alpha-Chloralose  (contains beta-isomer),>85.0%(GC)(15879-93-3)
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