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ChemicalBook--->CAS DataBase List--->101-39-3

101-39-3

101-39-3 Structure

101-39-3 Structure
IdentificationMore
[Name]

alpha-Methylcinnamaldehyde
[CAS]

101-39-3
[Synonyms]

2-METHYL-3-PHENYL-2-PROPEN-1-AL
2-methyl-3-phenyl-2-propenal
2-METHYL-3-PHENYLACROLEIN
2-METHYL-3-PHENYLPROPENAL
2-METHYL CINNAMIC ALDEHYDE
3-Phenyl-2-methyl acrolein
3-PHENYLMETHACROLEIN
AKOS BBS-00003193
ALPHA-METHYLCINNAMALDEHYDE
ALPHA-METHYL CINNAMIC ALDEHYDE
ALPHA-METHYL-TRANS-CINNAMALDEHYDE
A-METHYLCINNAMALDEHYDE
FEMA 2697
LABOTEST-BB LT00928083
METHYL CINNAMIC ALDEHYDE
METHYL CINNAMIC ALDEHYDE, ALPHA
(2E)-2-Methyl-3-phenyl-2-propenal
2-methyl-3-phenyl-2-propena
2-Methyl-3-phenylacrylaldehyde
2-methyl-3-phenyl-prop-2-enal
[EINECS(EC#)]

202-938-8
[Molecular Formula]

C10H10O
[MDL Number]

MFCD00006976
[Molecular Weight]

146.19
[MOL File]

101-39-3.mol
Chemical PropertiesBack Directory
[Appearance]

yellow liquid
[Boiling point ]

148-149 °C27 mm Hg(lit.)
[density ]

1.047 g/mL at 25 °C(lit.)
[FEMA ]

2697
[refractive index ]

n20/D 1.605(lit.)
[Fp ]

175 °F
[storage temp. ]

Inert atmosphere,2-8°C
[solubility ]

Chloroform, Methanol (Slightly)
[form ]

Oil
[color ]

Colourless
[Odor]

at 100.00 %. sweet cinnamon spicy cassia
[Stability:]

Stable. Combustible. Incompatible with strong oxidizing agents, strong bases.
[biological source]

synthetic
[Odor Type]

spicy
[Water Solubility ]

<0.1 g/100 mL at 21 ºC
[Sensitive ]

Air Sensitive
[JECFA Number]

683
[BRN ]

507514
[InChIKey]

VLUMOWNVWOXZAU-VQHVLOKHSA-N
[LogP]

2.68
[CAS DataBase Reference]

101-39-3(CAS DataBase Reference)
[NIST Chemistry Reference]

2-Propenal, 2-methyl-3-phenyl-(101-39-3)
[EPA Substance Registry System]

101-39-3(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

1
[RTECS ]

GD6600000
[TSCA ]

Yes
[HS Code ]

29122900
[Safety Profile]

Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium carbonate-->CAUSTIC SODA FLAKES 99%MIN
Hazard InformationBack Directory
[General Description]

Clear yellow liquid.
[Reactivity Profile]

ALPHA-METHYLCINNAMALDEHYDE(101-39-3) is incompatible with strong oxidizing agents and strong bases.
[Air & Water Reactions]

Insoluble in water.
[Fire Hazard]

This chemical is combustible.
[Description]

α-Methylcinnamaldehyde has a characteristic cinnamon-type odor with a soft, spicy flavor. May be synthesized by condensing benzaldehyde with propionic aldehyde in the presence of a 1% caustic soda solution; also by the controlled hydrogenation of α-methylcinnamic aldehyde.
[Chemical Properties]

yellow liquid
[Chemical Properties]

α-Methylcinnamaldehyde has a characteristic cinnamon-type odor and a soft, spicy flavor.
[Occurrence]

Reported found in peppermint oil, sherry and mint
[Uses]

alpha-Methyl-trans-cinnamaldehyde is a compound with antifungal activity for proteomics research use.
[Preparation]

By condensing benzaldehyde with propionic aldehyde in the presence of a 1% caustic soda solution; also by the controlled hydrogenation of α-methylcinnamic aldehyde
[Taste threshold values]

Taste characteristics at 30 ppm: spice, cinnamon, sweet, woody with a slight pungent and hot bite
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 55, p. 2878, 1990 DOI: 10.1021/jo00296a059
Tetrahedron Letters, 28, p. 1263, 1987 DOI: 10.1016/S0040-4039(00)95341-3
[Biochem/physiol Actions]

α-Methyl trans cinnamaldehyde has antifungal activity. It is self coupled and complexed with Co(II) and Ni(II) to synthesize ligand and complexes.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

3-Phenyl-2-methyl acrolein(101-39-3).msds
Spectrum DetailBack Directory
[Spectrum Detail]

alpha-Methylcinnamaldehyde(101-39-3)MS
alpha-Methylcinnamaldehyde(101-39-3)1HNMR
alpha-Methylcinnamaldehyde(101-39-3)13CNMR
alpha-Methylcinnamaldehyde(101-39-3)IR1
alpha-Methylcinnamaldehyde(101-39-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

alpha-Methylcinnamaldehyde, 98%(101-39-3)
[Alfa Aesar]

alpha-Methylcinnamaldehyde, predominantly (E), 97%(101-39-3)
[Sigma Aldrich]

101-39-3(sigmaaldrich)
[TCI AMERICA]

alpha-Methylcinnamaldehyde,>95.0%(GC)(T)(101-39-3)
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