| Identification | More | [Name]
2-Bromocinnamaldehyde | [CAS]
5443-49-2 | [Synonyms]
2-BROMO-3-PHENYLACRYLALDEHYDE
(2Z)-2-BROMO-3-PHENYLACRYLALDEHYDE
AKOS BBS-00003210
ALPHA-BROMOCINNAMALDEHYDE
(2Z)-2-Bromo-3-phenyl-2-propenal
2-bromo-3-phenyl-2-propena
2-bromo-3-phenyl-2-propenal
Alphabrocine
alpha-bromo-cinnamaldehyd
alpha-Bromocinnamic Aldehyde
alpha-bromocinnamicaldehyde
B 37
b36
b37
Cinnamaldehyde, alpha-bromo-
BROMOCINNAMAL
a-Bromocinnamaldehyde
alpha-Bromocinnamaldehyde,98%
à-bromocinnamaldehyde
α-bromocinnamaldehyde | [EINECS(EC#)]
226-637-6 | [Molecular Formula]
C9H7BrO | [MDL Number]
MFCD00006965 | [Molecular Weight]
211.06 | [MOL File]
5443-49-2.mol |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S22:Do not breathe dust . | [RIDADR ]
UN 3335 | [WGK Germany ]
3
| [RTECS ]
GD6480000
| [HS Code ]
29130000 |
| Hazard Information | Back Directory | [Chemical Properties]
light yellow to ochre crystalline powder | [Uses]
α-Bromocinnamaldehyde was used in the synthesis of 3,4-diaryl 1 H -pyrazoles. 1 It was also used in the preparation of spiro imidazolidine-oxazolidine intermediate via guanidinium ylide mediated aziridination. 2 | [General Description]
α-Bromocinnamaldehyde is commonly employed as an anti-mildew agent in commercial products. | [Hazard]
Causes somnolence in oral, intraperitoneal, and subcutaneous lethal-dose
studies of rats; A skin and strong eye irritant; Toxic by
ingestion; | [Synthesis]
The synthesis of α-Bromocinnamaldehyde is as follows:
The cinnamaldehyde and glacial acetic acid were stirred and bromine was added after cooling. Then add anhydrous potassium carbonate, reactants heated reflux for half an hour, cooling, precipitation coarse product. The crude product is dissolved by ethanol and recrystallized to obtain the finished product with a yield of about 80%.
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