成人免费xx,国产又黄又湿又刺激不卡网站,成人性视频app菠萝网站,色天天天天

ChemicalBook--->CAS DataBase List--->79-20-9

79-20-9

79-20-9 Structure

79-20-9 Structure
IdentificationMore
[Name]

Methyl acetate
[CAS]

79-20-9
[Synonyms]

ACETIC ACID METHYL ESTER
FEMA 2676
LABOTEST-BB LT00785639
METHYL ACETATE
RARECHEM AL BF 0544
Acetate de methyle
acetatedemethyle
acetatedemethyle(french)
CH3COOCH3
Devoton
ethanoicacid,methylester
Ethyl ester of monoacetic acid
ethylesterofmonoaceticacid
femanumber2676
Methyl acetic ester
Methyl ester of acetic acid
Methyl ethanoate
Methylacetaat
Methylacetat
methylaceticester
[EINECS(EC#)]

201-185-2
[Molecular Formula]

C3H6O2
[MDL Number]

MFCD00008711
[Molecular Weight]

74.08
[MOL File]

79-20-9.mol
Chemical PropertiesBack Directory
[Appearance]

Methyl acetate is a colorless liquid with a fruity odor.
[Melting point ]

-98 °C (lit.)
[Boiling point ]

57-58 °C (lit.)
[density ]

0.932 g/mL at 25 °C(lit.)
[vapor density ]

2.55 (vs air)
[vapor pressure ]

165 mm Hg ( 20 °C)
[FEMA ]

2676
[refractive index ]

n20/D 1.361(lit.)
[Fp ]

3.2 °F
[storage temp. ]

Flammables area
[solubility ]

250g/l
[form ]

Solution
[color ]

Clear colorless to slightly pale yellow
[Odor]

Slightly acrid, sweet; fragrant.
[Relative polarity]

0.253
[Stability:]

Stable. Extremely flammable-readily forms explosive mixtures with air. Note low flash point and wide explosion limits. Incompatible with strong oxidizing agents, strong bases, strong acids, nitrates. May be moisture sensitive.
[explosive limit]

3.1-16%(V)
[Odor Threshold]

1.7ppm
[Odor Type]

ethereal
[Water Solubility ]

250 g/L (20 ºC)
[λmax]

λ: 255 nm Amax: 1.0
λ: 275 nm Amax: 0.1
λ: 300 nm Amax: 0.01
[JECFA Number]

125
[Merck ]

14,6008
[BRN ]

1736662
[Henry's Law Constant]

0.90 at 20.00 °C, 1.56 at 30.00 °C (headspace-GC, Hovorka et al., 2002)
[Dielectric constant]

7.3(20℃)
[Exposure limits]

TLV-TWA 200 ppm (~610 mg/m3) (ACGIH, MSHA, and OSHA); TLV-STEL 250 ppm (~760 mg/m3) (ACGIH); IDLH 10,000 ppm (NIOSH).
[LogP]

0.18 at 20℃
[CAS DataBase Reference]

79-20-9(CAS DataBase Reference)
[NIST Chemistry Reference]

Acetic acid, methyl ester(79-20-9)
[EPA Substance Registry System]

79-20-9(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

F,Xi
[Risk Statements ]

R11:Highly Flammable.
R36:Irritating to the eyes.
R66:Repeated exposure may cause skin dryness or cracking.
R67:Vapors may cause drowsiness and dizziness.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S29:Do not empty into drains .
S33:Take precautionary measures against static discharges .
[RIDADR ]

UN 1231 3/PG 2
[WGK Germany ]

1
[RTECS ]

AI9100000
[Autoignition Temperature]

936 °F
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29153900
[Safety Profile]

Moderately toxic by several routes. A human systemic irritant by inhalation. A moderate skin and eye irritant. Mutation data reported. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderate explosion hazard when exposed to heat or flame. When heated to decomposition it emits acrid smoke and fumes. See also ESTERS.
[Hazardous Substances Data]

79-20-9(Hazardous Substances Data)
[Toxicity]

LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rat > 2000 mg/kg
[IDLA]

3,100 ppm [10% LEL]
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Methanol-->Acetic acid-->Dehydrolyzing agent
[Preparation Products]

METHYL 3-(2,2-DICHLOROVINYL)-2,2-DIMETHYL-(1-CYCLOPROPANE)CARBOXYLATE-->ethyl 3-(2,2-dichlorovinyl)-2,2-dimethyl-1-cyclopropanecarboxylate-->methyl(±)cis,trans-2,2-dimethyl-3-(2-methyl-1-propenyl cyclopropane carboxylate)-->Ethyl chrysanthemumate-->Sulindac-->Misoprostol-->Lornoxicam-->Benalaxyl-->Clopidogrel-->METHYL 3-(THIEN-2-YL)ACRYLATE-->dimethyl trans,trans-chrysanthemumdicarboxylate-->Methyl nicotinoylacetate-->METHYL 3,3-DIMETHOXYPROPIONATE-->1,1-Dimethoxyethane-->2-METHYL-2-IMIDAZOLINE-->METHYLPHOSPHONICACIDMETHYL-1-METHYLETHYLESTER-->CIS-10-PENTADECENOIC ACID METHYL ESTER (C15:1)-->Methyl cyclopropane carboxylate
Hazard InformationBack Directory
[General Description]

A clear colorless liquid with a fragrant odor. Moderately toxic. Flash point 14°F. Vapors heavier than air.
[Reactivity Profile]

METHYL ACETATE(79-20-9) presents a fire or explosion hazard when exposed to strong oxidizing agents. Emits irritating fumes and acrid smoke when heated to decomposition, [Lewis, 3rd ed., 1993, p. 826]. METHYL ACETATE(79-20-9) reactivity is consistent with other compounds of the ester group.
[Air & Water Reactions]

Highly flammable. Water soluble.
[Hazard]

Flammable, dangerous fire and explosion risk, explosive limits in air 3–16%. Irritant to respiratory tract. Headache, dizziness, nausea, eye damage (degeneration of ganglion cells in the retina).
[Health Hazard]

(Very similar to those of methyl alcohol, which constitutes 20% of commercial grade.) Inhalation causes headache, fatigue, and drowsiness; high concentrations can produce central nervous system depression and optic nerve damage. Liquid irritates eyes and may cause defatting and cracking of skin. Ingestion causes headache, dizziness, drowsiness, fatigue; may cause severe eye damage.
[Potential Exposure]

Methyl acetate is used as a solvent in lacquers and paint removers; and as an intermediate in pharmaceutical manufacture.
[Fire Hazard]

Behavior in Fire: Vapor is heavier than air and may travel a considerable distance to a source of ignition and flash back.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.
[Shipping]

UN1231 Methyl acetate, Hazard Class: 3; Labels: 3-Flammable liquid.
[Incompatibilities]

Vapor may form explosive mixture with air. A Strong reducing agent. Incompatible water, acids, nitrates, strong oxidizers; alkalis. Attacks some plastics. Attacks many metals in presence of water. Reacts slowly with water, forming acetic acid and methanol. Decomposes in heat; on contact with air, bases, strong oxidizers; UV-light; possible fire and explosion hazard
[Description]

Methyl acetate, also known as MeOAc , acetic acid methyl ester or methyl ethanoate, is a carboxylate ester with the formula CH3COOCH3. It is a flammable liquid with a characteristically pleasant smell reminiscent of some glues and nail polish removers. Methyl acetate is occasionally used as a solvent, being weakly polar and lipophilic, but its close relative ethyl acetate is a more common solvent being less toxic and less soluble in water. Methyl acetate has a solubility of 25% in water at room temperature. At elevated temperature its solubility in water is much higher. Methyl acetate is not stable in the presence of strong aqueous bases or aqueous acids. Methyl acetate is VOC exempt.
[Chemical Properties]

Methyl acetate has a pleasant, fruity odor and slightly bitter flavor.
[Chemical Properties]

Methyl acetate has a pleasant, fruity odor and slightly bitter flavor. May be prepared by boiling acetic acid and methanol in the presence of acid catalysts; or by heating methanol with an excess carbon monoxide under pressure in the presence of a catalyst (phosphoric acid, cobalt salts).
Methyl acetate occurs naturally in low concentrations in mint, fungus,grapes, banana, coffee (Furia and Bellanca, 1975) and is a volatile constituent of nectarines (Takeoka et al., 1988). It is also present in some distilled alcoholic beverages (Shimoda et al., 1993). It is produced industrially via the carbonylation of methanol as a byproduct of acetic acid production or by esterification of acetic acid with methanol in the presence of strong acid such as sulfuric acid.
[Waste Disposal]

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
[Physical properties]

Colorless liquid with a pleasant odor. An odor threshold concentration of 48 ppbv was reported by Nagata and Takeuchi (1990). Cometto-Mu?iz and Cain (1991) reported an average nasal pungency threshold concentration of 112,500 ppmv.
[Occurrence]

Reported found in apple, banana, sweet and sour cherry, tangerine juice, black currants, guava, grapes, melon, peach, pear, pineapple, strawberry, cabbage, tomato, clove bud, peppermint oil, vinegar, bread, cheeses, butter, yogurt, beef, beer, cognac, rum, whiskies, cider, sherry, grape wines, cocoa, coffee, filbert, peanut, honey, soybean, olive, passion fruit, fruit brandies, fig, gin, kiwifruit, clary sage, arrack and nectarine.
[Uses]

Methyl acetate is used as a solvent forlacquers, resins, oils, and nitrocellulose; inpaint removers; as a flavoring agent; and inthe manufacture of artificial leather.
[Uses]

Solvent for lacquers, oils, and resins
[Uses]

Solvent for nitrocellulose, acetylcellulose, and many resins and oils; manufacture of artificial leather.
[Application]

Methyl acetate may be used for the preparation of fatty acid methyl esters and triacetin from rapeseed oil via non-catalytic trans-esterification reaction under super-critical conditions.
Methyl acetate may be used in the following:
As acyl acceptor in the preparation of biodiesel.
Synthesis of ethanol.
Preparation of n-butyl acetate, via transesterification reaction with n-butanol in the presence of acidic catalysts.
It may also be used as a precursor in the synthesis of the following:
acetic anhydride
methyl acrylate
vinyl acetate
ethyl amide
[Definition]

ChEBI: Methyl acetate is an acetate ester resulting from the formal condensation of acetic acid with methanol. A low-boiling (57°C) colourless, flammable liquid, it is used as a solvent for many resins and oils. It has a role as a polar aprotic solvent, a fragrance and an EC 3.4.19.3 (pyroglutamyl-peptidase I) inhibitor. It is an acetate ester, a methyl ester and a volatile organic compound.
[Preparation]

Methyl acetate is produced industrially via the carbonylation of methanol as a byproduct of the production of acetic acid.Methyl acetate also arises by esterification of acetic acid with methanol in the presence of strong acids such as sulfuric acid, this production process is famous because of Eastman Kodak's intensified process using a reactive distillation.
2–1-Reactions
In the presence of strong bases such as sodium hydroxide or strong acids such as hydrochloric acid or sulfuric acid it is hydrolyzed back into methanol and acetic acid, especially at elevated temperature. The conversion of methyl acetate back into its components, by an acid , is a first-order reaction with respect to the ester. The reaction of methyl acetate and a base, for example sodium hydroxide, is a second-order reaction with respect to both reactants.
3-Applications
A major use of methyl acetate is as a volatile low toxicity solvent in glues, paints, and nail polish removers. Acetic anhydride is produced by carbonylation of methyl acetate in a process that was inspired by the Monsanto acetic acid synthesis.
[Aroma threshold values]

Detection: 1.5 to 47 ppm
[Taste threshold values]

Taste characteristics at 60 ppm: green, ethereal, fruity, fresh, rum and whiskey-like.
[Chemical Reactivity]

Reactivity with Water Reacts slowly to form acetic acid and methyl alcohol; the reaction is not violent; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
[Synthesis]

By boiling acetic acid and methanol in the presence of acid catalysts, or by heating methanol with an excess of carbon monoxide under pressure in the presence of a catalyst (phosphoric acid, cobalt salts).
[Environmental Fate]

Photolytic. A rate constant of 2.00 x 10-13 cm3/molecule?sec was reported for the reaction of methyl acetate and OH radicals in aqueous solution (Wallington et al., 1988b).
Chemical/Physical. Slowly hydrolyzes in water yielding methyl alcohol and acetic acid (NIOSH, 1997). The estimated hydrolysis half-life in water at 25 °C and pH 7 is 2.5 yr (Mabey and Mill, 1978).
At an influent concentration of 1,030 mg/L, treatment with GAC resulted in an effluent concentration of 760 mg/L. The adsorbability of the carbon used was 54 mg/g carbon (Guisti et al., 1974).
[storage]

(1) Color Code—Red: Flammability Hazard: Store in a flammable liquid storage area or approved cabinet away from ignition sources and corrosive and reactive materials. (2) Color Code—Yellow Stripe (strong reducing agent): Reactivity Hazard; Store separately in an area isolated from flammables, combustibles, or other yellow coded materials. Prior to working with this chemical you should be trained on its proper handling and storage. Before entering confined space where this chemical may be present, check to make sure that an explosive concentration does not exist. Methyl acetate must be stored to avoid contact with strong oxidizers (such as chlorine, bromine, and fluorine) and strong acids (such as hydrochloric, sulfuric and nitric), since violent reactions occur. Store in tightly closed containers in a cool, well-ventilated area away from strong alkalis and nitrates. Sources of ignition, such as smoking and open flames, are prohibited where methyl acetate is used, handled, or stored in a manner that could create a potential fire or explosion hazard. Use only nonsparking tools and equipment, especially when opening and closing containers of methyl acetate.
[Purification Methods]

Methanol in methyl acetate can be detected by measuring its solubility in water. At 20o, the solubility of methyl acetate in water is ca 35g per 100mL, but 1% MeOH confers complete miscibility. Methanol can be removed by conversion to methyl acetate, by refluxing for 6hours with acetic anhydride (85mL/L), followed by fractional distillation. Acidic impurities can be removed by shaking with anhydrous K2CO3 and distilling. An alternative treatment is with acetyl chloride, followed by washing with concentrated NaCl and drying with CaO or MgSO4. (Solid CaCl2 cannot be used because it forms a crystalline addition compound.) Distillation from copper stearate destroys peroxides. Free alcohol or acid can be eliminated from methyl acetate by shaking with strong aqueous Na2CO3 or K2CO3 (three times), then with aqueous 50% CaCl2 (three times), saturated aqueous NaCl (twice), drying with K2CO3 and distilling it from P2O5. [Beilstein 2 IV 122.]
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

methyl acetate(79-20-9).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Methyl acetate(79-20-9)MS
Methyl acetate(79-20-9)1HNMR
Methyl acetate(79-20-9)13CNMR
Methyl acetate(79-20-9)IR1
Methyl acetate(79-20-9)IR2
Methyl acetate(79-20-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Methyl acetate, AcroSeal?, Extra Dry, 99+%(79-20-9)
[Alfa Aesar]

Methyl acetate, 99%(79-20-9)
[Sigma Aldrich]

79-20-9(sigmaaldrich)
[TCI AMERICA]

Methyl Acetate  [Standard Material],>99.5%(GC)(79-20-9)
79-20-9 suppliers list
Company Name: ShanDong Look Chemical Co.,Ltd.
Tel: +8617653113219 , +8617653113219
Website: https://www.sdlookchem.com/
Company Name: Shaanxi Didu New Materials Co. Ltd
Tel: +86-89586680 +86-13289823923 , +86-13289823923
Website: https://www.dideu.com/en/
Company Name: Hebei Chuanghai Biotechnology Co,.LTD
Tel: +86-13131129325 , +86-13131129325
Website: www.chuanghaibio.com
Company Name: PT CHEM GROUP LIMITED
Tel: +86-85511178; +86-85511178; , +86-85511178;
Website: http://m.is0513.com/manufacturer/henan-lihao-chem-plant-25020/
Company Name: Wuhan Quanjinci New Material Co.,Ltd.
Tel: +86-15271838296; +8615271838296 , +8615271838296
Website: http://www.quanjinci.com/
Company Name: Yujiang Chemical (Shandong) Co.,Ltd.
Tel: +86-17736087130 +86-18633844644 , +86-18633844644
Website:
Company Name: Hebei Fengmu Trading Co., Ltd.
Tel: +8613393234347 , +8613393234347
Website: www.fengmuchem.com/
Company Name: Runte International Trade Limited
Tel: 19565631292 19565631292 , 19565631292
Website:
Company Name: Hebei Weibang Biotechnology Co., Ltd
Tel: +8615531157085 , +8615531157085
Website: www.weibangbio.com/
Company Name: Hebei Mojin Biotechnology Co., Ltd
Tel: +86 13288715578 +8613288715578 , +8613288715578
Website: http://www.mojinchemical.com
Company Name: Qingdao RENAS Polymer Material Co., Ltd.
Tel: +86-0532-86867058 +86-18562606086 , +86-18562606086
Website: www.qdrenas.com
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: +86-0371-55170693 +86-19937530512 , +86-19937530512
Website: https://www.tianfuchem.com/
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
Tel: +86-0551-65418679 +8618949832763 , +8618949832763
Website: www.tnjchem.com
Company Name: Tianjin Zhongxin Chemtech Co., Ltd.
Tel: +86-022-66880623 +8618622897568 , +8618622897568
Website: http://www.tjzxchem.com
Company Name: Shanxi Naipu Import and Export Co.,Ltd
Tel: +86-13734021967 +8613734021967 , +8613734021967
Website: http://m.is0513.com/manufacturer/Chisure/
Company Name: career henan chemical co
Tel: +86-0371-86658258 +8613203830695 , +8613203830695
Website: www.coreychem.com/
Company Name: SHANDONG ZHI SHANG CHEMICAL CO.LTD
Tel: +86 18953170293 , +86 18953170293
Website: https://www.zhishangchem.com/
Company Name: Hubei Jusheng Technology Co.,Ltd.
Tel: 18871490254
Website: www.hubeijusheng.com
Tags:79-20-9 Related Product Information
140-11-4 105-34-0 127-09-3 141-78-6 96-32-2 123-86-4 96-33-3 631-61-8 108-05-4 107-31-3 93-58-3 108-21-4 101-41-7 2365-48-2 142-72-3 55896-93-0 67-56-1 122-46-3