ETHYLIDENECYCLOHEXANE synthesis
- Product Name:ETHYLIDENECYCLOHEXANE
- CAS Number:1003-64-1
- Molecular formula:C8H14
- Molecular Weight:110.2
Yield:-
Reaction Conditions:
with hydrogen in decane at 200; under 38787.1 Torr; for 2.33333 h;Kinetics;Catalytic behavior;
Steps:
2.3.2. HDO of anisole, 4-ethylphenol and benzofuran
General procedure: Catalytic HDO of anisole, 4-ethylphenol and benzofuran was performedin a stirred stainless steel autoclave reactor (100 mL, ParrInstruments), outfitted with a gas entrainment impeller. HDO wasconducted using a similar protocol to our previous work [43]. Eachexperiment was performed at a reaction temperature of 200 °C, pressureof 750 psi, and a stir rate of 1100 rpm. Initially, the reactor contained53.9 mL of 4 wt.% model compound diluted in decane, 0.1 g of reducedcatalyst and 1.1 mL of octane, which was used as an internal standard.Prior to heating, the reactor was purged with Ar, and then H2. Thereactor was pressurized to check for leaks, then purged and heated to200 °C. After achieving the desired reaction temperature, it was pressurized,the impeller was engaged and the reaction clock started. Initialreactant concentration was measured directly after heating, such thatany conversion or product formation during heating could be accountedfor. H2 was continuously supplied to maintain reactor pressure for theduration of the experiment. Liquid samples (～2 mL) were collectedfrom the reactor using a custom-made sample entrainment system. Thesampling unit was purged with Ar prior to each sample to avoid exposingthe reactor contents to air. Liquid samples were collected every20 min (unless otherwise noted), diluted in isopropanol and filtered toremove catalyst. The total reaction duration was 140 min.
References:
Gamliel, David P.;Karakalos, Stavros;Valla, Julia A. [Applied Catalysis A: General,2018,vol. 559,p. 20 - 29]
695-12-5
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$53.00/5mL
1003-64-1
40 suppliers
$139.00/10g
695-12-5
96 suppliers
$53.00/5mL
1678-91-7
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$36.00/25mL
1003-64-1
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$139.00/10g
5664-20-0
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$132.00/500mg
695-12-5
96 suppliers
$53.00/5mL
1003-64-1
40 suppliers
$139.00/10g