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Calciumdihydroxid

Calcium hydroxide  Struktur
1305-62-0
CAS-Nr.
1305-62-0
Bezeichnung:
Calciumdihydroxid
Englisch Name:
Calcium hydroxide
Synonyma:
Ca(OH)2;HYDRATED LIME;SLAKED LIME;LIME WATER;carboxide;CARBIDE LIME;CALCIUM HYDRATE;Calciumhydroxid8;Calcium Hydroxide Topical Solution;calvit
CBNumber:
CB9853016
Summenformel:
CaH2O2
Molgewicht:
74.09
MOL-Datei:
1305-62-0.mol

Calciumdihydroxid Eigenschaften

Schmelzpunkt:
580 °C
Siedepunkt:
2850 °C
Dichte
2.24 g/mL at 25 °C (lit.)
storage temp. 
Store at +5°C to +30°C.
L?slichkeit
1.7g/l
Aggregatzustand
Solid
pka
12.6[at 20 ℃]
Farbe
White
Geruch (Odor)
Odorless
S?ure-Base-Indikators(pH-Indikatoren)
12.4
PH
11.27(1 mM solution);12.2(10 mM solution);12.46(100 mM solution);
Wasserl?slichkeit
1.65 g/L (20 ºC)
Sensitive 
Air Sensitive
Merck 
14,1673
Solubility Product Constant (Ksp)
pKsp: 5.26
Expositionsgrenzwerte
ACGIH: TWA 5 mg/m3
OSHA: TWA 15 mg/m3; TWA 5 mg/m3
NIOSH: TWA 5 mg/m3
Stabilit?t:
Stable. Incompatible with strong acids.
CAS Datenbank
1305-62-0(CAS DataBase Reference)
NIST chemische Informationen
Calcium dihydroxide(1305-62-0)
EPA chemische Informationen
Calcium hydroxide (1305-62-0)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xi,C
R-S?tze: 41-34-37/38
S-S?tze: 26-39-45-36/37/39-27
RIDADR  3262
OEB B
OEL TWA: 5 mg/m3
WGK Germany  1
RTECS-Nr. EW2800000
34
TSCA  Yes
HS Code  2825 90 19
HazardClass  8
PackingGroup  III
Giftige Stoffe Daten 1305-62-0(Hazardous Substances Data)
Toxizit?t LD50 orally in rats: 7.34 g/kg (Smyth)
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H318 Verursacht schwere Augensch?den. Schwere Augensch?digung Kategorie 1 Achtung GHS hazard pictogramssrc="/GHS05.jpg" width="20" height="20" /> P280, P305+P351+P338, P310
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P271 Nur im Freien oder in gut belüfteten R?umen verwenden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P302+P352 BEI BERüHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckm??ig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.

Calciumdihydroxid Chemische Eigenschaften,Einsatz,Produktion Methoden

ERSCHEINUNGSBILD

FARBLOSE KRISTALLE ODER WEISSES PULVER.

CHEMISCHE GEFAHREN

Zersetzung beim Erhitzen unter Bildung von Calciumoxid. Mittelstarke Base in w?ssriger L?sung. Reagiert sehr heftig mit S?uren. Greift viele Metalle in Gegenwart von Wasser an unter Bildung entzündlichen/explosionsf?higen Gases (Wasserstoff, s. ICSC-Nr. 0001).

ARBEITSPLATZGRENZWERTE

TLV: 5 mg/m?(als TWA) (ACGIH 2005).

AUFNAHMEWEGE

Aufnahme in den K?rper durch Inhalation des Aerosols und durch Verschlucken.

INHALATIONSGEFAHREN

Verdampfung bei 20°C vernachl?ssigbar; eine gesundheitssch?dliche Partikelkonzentration in der Luft kann jedoch beim Dispergieren schnell erreicht werden.

WIRKUNGEN BEI KURZZEITEXPOSITION

WIRKUNGEN BEI KURZZEITEXPOSITION:
Die Substanz reizt die Atemwege und ver?tzt die Augen und die Haut. ?rztliche Beobachtung notwendig.

WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION

Wiederholter oder andauernder Hautkontakt kann Dermatitis hervorrufen. Risiko der Lungensch?digung bei wiederholter oder l?ngerer Exposition gegenüber Staubpartikeln.

LECKAGE

Verschüttetes Material in Beh?ltern sammeln. An sicheren Ort bringen. Pers?nliche Schutzausrüstung: Atemschutzger?t, P2-Filter für sch?dliche Partikel.

R-S?tze Betriebsanweisung:

R41:Gefahr ernster Augensch?den.
R34:Verursacht Ver?tzungen.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S39:Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S27:Beschmutzte, getr?nkte Kleidung sofort ausziehen.

Beschreibung

Calcium Hydroxide is a colorless crystal or white powder, obtained when CaO (called lime or quicklime) is mixed, or “slaked” with water. It can also be precipitated by mixing CaCl2 andNaOH.The nameof the natural,mineral formis “portlandite”. It is a relatively rare mineral, known from some volcanic, plutonic, and metamorphic rocks. It has also been known to be formed in burning coal dumps.

Chemische Eigenschaften

Calcium hydroxide occurs as a white or almost white, crystalline or granular powder. It has a bitter, alkaline taste. Calcium hydroxide readily absorbs carbon dioxide to form calcium carbonate.

Physikalische Eigenschaften

Soft white crystalline powder; hexagonal; density 2.34 g/cm3; slightly bitter taste; loses water when heated at elevated temperatures (580°C); slightly soluble in water; Ksp 1.2x10-14; aqueous solution alkaline; soluble in glycerol and acids; insoluble in alcohol.

Verwenden

calcium hydroxide is an inorganic base used to adjust the pH of a product, it can also serve as a topical astringent and alkali in solutions or lotions. It can burn the skin and eyes.

Definition

Lime water: A solution of calcium hydroxide in water. If carbon dioxide is bubbled through lime water a milky precipitate of calcium carbonate forms. Prolonged bubbling of carbon dioxide turns the solution clear again as a result of the formation of soluble calcium hydrogencarbonate (Ca(HCO3)2).

Vorbereitung Methode

Calcium hydroxide is manufactured by adding water to calcium oxide, a process called slaking.

Allgemeine Beschreibung

Odorless white granules. Sinks in water.

Air & Water Reaktionen

Water soluble. The amount of heat generated by hydrolysis may be large.

Reaktivit?t anzeigen

The nitroparaffins, nitromethane, nitropropane, etc. form salts with inorganic bases such as Calcium hydroxide . The dry salts are explosive [Chem. Eng. news 30:2344 1952]. Bases are chemically similar to sodium hydroxide (NaOH) or sodium oxide (Na2O). They neutralize acids exothermically to form salts plus water. When soluble in water they give solutions having a pH greater than 7.0. Mixing these materials with water can generate troublesome amounts of heat as the base is dissolved or diluted. Bases react with certain metals (such as aluminum and zinc) to form oxides or hydroxides of the metal and generate gaseous hydrogen. Bases may initiate polymerization reactions in polymerizable organic compounds, especially epoxides). They may generate flammable and/or toxic gases with ammonium salts, nitrides, halogenated organics, various metals, peroxides, and hydroperoxides. Materials of this group often serve as catalysts. A strong base. Forms caustic solution in water [Merck 11th ed. 1989].

Hazard

Skin, eye, and upper respiratory tract irri- tant, avoid inhalation.

Health Hazard

Dust irritates eyes, nose and throat.

Pharmazeutische Anwendungen

Calcium hydroxide is a strong alkali and is used as a pharmaceutical pH adjuster/buffer and antacid in topical medicinal ointments, creams, lotions, and suspensions, often as an aqueous solution (lime water). It forms calcium soaps of fatty acids, which produce water-in-oil emulsions (calamine liniment), and it is also used as a topical astringent.
Calcium hydroxide is a common cosmetic ingredient in hairstraightening and hair-removal products, and in shaving preparations.
1) In dentistry, it is used as a filling agent and in dental pastes to encourage deposition of secondary dentine. Calcium hydroxide was traditionally used as an escharotic in Vienna Paste.

Landwirtschaftliche Anwendung

Calcium hydroxide, [Ca(OH)2], also called slaked lime or hydrated lime, is a white solid that dissolves sparingly in water. It is manufactured by adding water to calcium oxide, a process that emits heat and is known as slaking.
Calcium hydroxide is a cheap alkali, used for neutralizing the acidity of acid soils and in the manufacture of mortar, white wash, bleaching powder and glass. It is an excellent absorbent for carbon dioxide to produce insoluble calcium carbonate and has a neutralizing value of 179%, compared to 100% of pure calcium carbonate.

Sicherheitsprofil

Mildly toxic by ingestion. A severe eye irritant. A skin, mucous membrane, and respiratory system irritant. Mutation data reported. Causes dermatitis. Dust is considered to be a significant industrial hazard. A common air contaminant. Violent reaction with maleic anhydride, nitroethane, nitromethane, nitroparaffins, nitropropane, phosphorus. Reaction with polychloiinated phenols + potassium nitrate forms extremely toxic products. See also CALCIUM COMPOUNDS

Sicherheit(Safety)

Calcium hydroxide is used in oral and topical pharmaceutical formulations. It is mildly toxic by ingestion. In the pure state, calcium hydroxide is a severe skin, eye, and respiratory irritant, and it is corrosive, causing burns. Typical exposure limits are TVL 5 mg/m3 in air.
LD50 (mouse, oral): 7.3 g/kg
LD50 (rat, oral): 7.34 g/kg

m?gliche Exposition

Calcium hydroxide is used in agriculture and in fertilizer manufacture; it is used in the formulation of mortar, plasters, and cements; it is used as a scrubbing and neutralizing agent in the chemical industry. For making insecticides, acaricides, and products to control arthropods

Lager

Calcium hydroxide should be stored in an airtight container, in a cool, dry, well-ventilated place. Calcium hydroxide powder may be sterilized by heating for 1 hour at a temperature of at least 1608℃.

Versand/Shipping

UN3262 Corrosive solid, basic, inorganic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name required

l?uterung methode

Heat analytical grade calcium carbonate at 1000o during 1hour. Allow the resulting oxide to cool and add slowly to water. Heat the suspension to boiling, cool and filter through a sintered glass funnel of medium porosity (to remove soluble alkaline impurities). Dry the solid at 110o and crush it to a uniformly fine powder. [Ehrlich in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 934 1963.]

Inkompatibilit?ten

Incompatible with strong acids, maleic anhydride, phosphorus, nitroethane, nitromethane, nitroparaffins, and nitropropane. Calcium hydroxide can be corrosive to some metals.

Waste disposal

Landfill or admixture with acid industrial wastes prior to lagooning

Regulatory Status

GRAS listed. Accepted for use as a food additive in Europe. Included in the FDA Inactive Ingredients Database (intravenous and subcutaneous injections; oral suspensions and tablets; topical emulsions and creams). Included in parenteral preparations licensed in the UK.

Calciumdihydroxid Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Calciumdihydroxid Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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1305-62-0(Calciumdihydroxid)Verwandte Suche:


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