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Benzylthiocyanat

Benzyl thiocyanate Struktur
3012-37-1
CAS-Nr.
3012-37-1
Bezeichnung:
Benzylthiocyanat
Englisch Name:
Benzyl thiocyanate
Synonyma:
Troeolin;solvat14;Solvat 14;Tropeolin;Benzylrhodonid;BENZYL RHODANIDE;Benzylthiocyanide;Beazyl thiocyanate;BENZYL THIOCYANATE;a-Thiocyanatotoluene
CBNumber:
CB6774554
Summenformel:
C8H7NS
Molgewicht:
149.21
MOL-Datei:
3012-37-1.mol

Benzylthiocyanat Eigenschaften

Schmelzpunkt:
39-41 °C (lit.) 39-41 °C
Siedepunkt:
230-235 °C (lit.)
Dichte
1.32
Brechungsindex
1.6000 (estimate)
Flammpunkt:
>230 °F
storage temp. 
Store at <= 20°C.
L?slichkeit
diethyl ether: soluble0.5g/10 mL, clear to very faintly turbid, colorless to almost colorless
Aggregatzustand
Solid
Farbe
Orange-red crystals or solid
Wasserl?slichkeit
insoluble
Sensitive 
Moisture Sensitive
BRN 
1859726
CAS Datenbank
3012-37-1(CAS DataBase Reference)
NIST chemische Informationen
Thiocyanic acid benzyl ester(3012-37-1)
EPA chemische Informationen
Thiocyanic acid, phenylmethyl ester (3012-37-1)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xn
R-S?tze: 20/21/22-32
S-S?tze: 13-36/37-50A
RIDADR  UN 1759 8/PG 2
WGK Germany  3
RTECS-Nr. XK8155000
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29309070
Toxizit?t LDLo ipr-rat: 40 mg/kg ARZNAD 16,870,66ipr-mus LD50:17 mg/kg PCBPBS 2,95,72scu-mus LD50:100 mg/kg JJPAAZ 3,99,54
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H412 Sch?dlich für Wasserorganismen, mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 3 P273, P501
Sicherheit
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.

Benzylthiocyanat Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R20/21/22:Gesundheitssch?dlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R32:Entwickelt bei Berührung mit S?ure sehr giftige Gase.

S-S?tze Betriebsanweisung:

S13:Von Nahrungsmitteln, Getr?nken und Futtermitteln fernhalten.
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.

Beschreibung

Benzyl thiocyanate undergoes regioselective bond dissociation during its electrochemical reduction in acetonitrile at an inert electrode. It is added to stimulate the chlortetracycline biosynthesis during industrial fermentations. It undergoes biotransformation into dibenzyl disulphide by Streptomyces aureofaciens.

Chemische Eigenschaften

ALMOST WHITE TO YELLOW CRYSTALS OR CRYST. POWDER

Verwenden

Benzyl Thiocyanate is found to increase the protein production of Streptomyces aureofaciens. Inhibits methylazoxymethanol acetate-induced intestinal carcinogenesis and reduces unscheduled DNA synthesi s for some genotoxic carcinogens in rats.

Application

Benzyl thiocyanate was used to study the effects of various dietary compounds on the α-hydroxylation of N-nitrosopyrrolidine in male F344 rats in vitro.

Allgemeine Beschreibung

Benzyl thiocyanate undergoes regioselective bond dissociation during its electrochemical reduction in acetonitrile at an inert electrode. It is added to stimulate the chlortetracycline biosynthesis during industrial fermentations. It undergoes biotransformation into dibenzyl disulphide by Streptomyces aureofaciens.

Hazard

Strong irritant to skin, tissue. Moderate fire hazard.

Sicherheitsprofil

Poison by subcutaneous andintraperitoneal routes. Whenheated to decomposition it emits very toxic fumes ofNOx, SOx, and CN??.

l?uterung methode

Crystallise the thiocyanate from EtOH or aqueous EtOH. [Beilstein 6 H 460, 6 IV 2680.]

Benzylthiocyanat Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Benzylthiocyanat Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 133)Lieferanten
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3012-37-1(Benzylthiocyanat)Verwandte Suche:


  • alpha-Thiocyanatotoluene
  • BENZYL THIOCYANATE(SG)
  • Beazyl thiocyanate
  • Benzyl thiocyanate, 98+%
  • a-Thiocyanatotoluene
  • Benzylrhodonid
  • Thiocyanatomethylbenzene
  • Troeolin
  • Benzyl thiocyanate,97%
  • Benzyl thiocyanate, 97% 100GR
  • Benzyl thiocyanate >=95.0% (GC)
  • Benzylthiocyanide
  • Solvat 14
  • solvat14
  • Thiocyanic acid, phenylmethyl ester
  • Thiocyanicacid,phenylmethylester
  • Toluene, alpha-thiocyanato-
  • Tropeolin
  • LABOTEST-BB LT00053217
  • Benzyl Thiocyanate, 94+%
  • 2-Thiocyanatotoluene
  • BENZYL RHODANIDE
  • BENZYL THIOCYANATE
  • THIOCYANIC ACID BENZYL ESTER
  • BENZYL THIOCYANATE 98% MIN
  • Benzyl Thiocyanate >
  • 2-Propen-1-one,1-[(2R,5R)-2-(methoxymethyl)-5-(7H-pyrrolo[2,3-d]pyrimidin-4-ylamino)-1-piperidinyl]-
  • 3012-37-1
  • C6H5CH2SCN
  • Building Blocks
  • Sulfur Compounds
  • Thiocyanates/Isothiocyanates
  • Organic Building Blocks
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