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(+)-Menthol

(+)-MENTHOL Struktur
15356-60-2
CAS-Nr.
15356-60-2
Bezeichnung:
(+)-Menthol
Englisch Name:
(+)-MENTHOL
Synonyma:
(1S,2R,5S)-2-ISOPROPYL-5-METHYLCYCLOHEXANOL;C00553;(1S,2R,5S)-;(+)-MENTHOL;(+)-menthol;MENTHOL, (+)-;dextro-menthol;(1S)-(+)-menthol;D-P-MENTHAN-3-OL;(+)-p-Menthan-3-ol
CBNumber:
CB4116411
Summenformel:
C10H20O
Molgewicht:
156.27
MOL-Datei:
15356-60-2.mol

(+)-Menthol Eigenschaften

Schmelzpunkt:
43-44 °C (lit.)
Siedepunkt:
103-104 °C/9 mmHg (lit.)
Dichte
0.890
Dampfdruck
0.8 mm Hg ( 20 °C)
Brechungsindex
50 ° (C=10, EtOH)
Flammpunkt:
196 °F
storage temp. 
2-8°C
L?slichkeit
Chloroform (Slightly), Methanol (Slightly)
Aggregatzustand
Solid
pka
15.30±0.60(Predicted)
Farbe
Colourless to Off-White Oil
Geruch (Odor)
mentholic
Optische Aktivit?t
[α]23/D +48°, c = 10 in ethanol
Wasserl?slichkeit
Soluble in methanol (almost transparency), chloroform, alcohols, water (456 mg/L at 25°C), and ether.
BRN 
1902292
Dielectric constant
3.2(Ambient)
LogP
3.15 at 25℃
CAS Datenbank
15356-60-2(CAS DataBase Reference)
EPA chemische Informationen
Cyclohexanol, 5-methyl-2-(1-methylethyl)-, (1S,2R,5S)- (15356-60-2)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xi
R-S?tze: 37/38-41
S-S?tze: 26-39
RIDADR  UN1230 - class 3 - PG 2 - Methanol, solution
WGK Germany  2
RTECS-Nr. OT0700000
TSCA  Yes
HS Code  29061100
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H318 Verursacht schwere Augensch?den. Schwere Augensch?digung Kategorie 1 Achtung GHS hazard pictogramssrc="/GHS05.jpg" width="20" height="20" /> P280, P305+P351+P338, P310
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.

(+)-Menthol Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R37/38:Reizt die Atmungsorgane und die Haut.
R41:Gefahr ernster Augensch?den.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S39:Schutzbrille/Gesichtsschutz tragen.

Beschreibung

(+)-Menthol is a monoterpene alcohol that has been found in Cannabis and has antifungal activity. It inhibits the growth of F. verticillioides (MIC = 1.5 mM). Unlike (–)-menthol, (+)-menthol does not exhibit analgesia, antibacterial, anticancer, or cholinesterase inhibitory activities.

Chemische Eigenschaften

(+)-MENTHOL is white low melting solid

Verwenden

(+)-MENTHOL is used for oral gel patch or film containing herb extracts or Chinese medicine, fruit extract, spearmint, and menthol for smoking cessation.

Allgemeine Beschreibung

(1S,2R,5S)-(+)-menthol is a chiral secondary alcohol. Its alcohol group can be protected as 2-tetrahydrofuranyl ether by reacting with bromotrichloromethane and tetrahydrofuran.

Synthese

Prod.: by Meerwein-Ponndorf-Verley reduction of l-Menthone, resuhing in approximately two-thirds d-Neomenthol plus one-third i-Menthol. It can also be produced by reduction of d-Menthone.

(+)-Menthol Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


(+)-Menthol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 219)Lieferanten
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15356-60-2((+)-Menthol)Verwandte Suche:


  • (1S,2R,5S)-(+)-MENTHOL
  • (+)-MENTHOL, TERPENE STANDARD
  • (1S,2R,5S)-(+)-MENTHOL, 99% (96% EE/GLC)
  • (+)-Menthol=D-Menthol
  • (1S)-(+)-menthol
  • 5-methyl-2-(1-methylethyl)-,[1S-(1.alpha.,2.beta.,5.alpha.)]-Cyclohexanol
  • 5-methyl-2-(1-methylethyl)-,[1s-(1alpha,2beta,5alpha)]-cyclohexano
  • C00553
  • (+)-Menthol, (1S,2R,5S)-2-Isopropyl-5-methylcyclohexanol
  • (1S,3S,4R)-p-Menthane-3-ol
  • (1S,3S,4R)-p-Menthane-3α-ol
  • [1S,2R,5S,(+)]-2-Isopropyl-5-methylcyclohexan-1-ol
  • [1S-(1.alpha.,2.beta.,5.alpha.)]-p-Menthan-3-ol
  • Cyclohexanol, 5-methyl-2-(1-methylethyl)-, (1S,2R,5S)-
  • (1S,2R,5S)-
  • (1S,2R,5S)-5-Methyl-2-(propan-2-yl)cyclohexan-1-ol
  • D-P-MENTHAN-3-OL
  • (+)-MENTHOL
  • MENTHOL, (+)-
  • (1S,2R,5S)-(+)-Menthol 99%
  • TIANFUCHEM--15356-60-2--(+)-MENTHOL in stock
  • (+)-menthol
  • dextro-menthol
  • (+)-p-Menthan-3-ol
  • (+)-Menthol solution
  • (1S,2R,5S)-(+)-Menthol, 99%, for synthesis
  • (2R)-5-methyl-2-propan-2-yl-1-cyclohexanol
  • (1S,2R,5S)-2-ISOPROPYL-5-METHYLCYCLOHEXANOL
  • (1s,2r,5s)-5-methyl-2-(1-met
  • NOOLISFMXDJSKH-AEJSXWLSSA-N
  • mtricitabine Impurity 9
  • (+)-Menthol, ≥ 99.0%
  • Nano-Liposomal MENTHOL
  • Antazoline Impurity 12
  • 15356-60-2
  • Optical Resolution
  • Terpenes
  • for Resolution of Acids
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