Identification | More | [Name]
Methyl glycolate | [CAS]
96-35-5 | [Synonyms]
GLYCOLIC ACID METHYL ESTER HYDROXYACETIC ACID METHYL ESTER METHYL 2-HYDROXYACETATE METHYL GLYCOLATE METHYL HYDROXYACETATE MG Aceticacid,hydroxy-,methylester hydroxy-aceticacimethylester Methyl ester of hydroxyacetic acid Methylglycolate,98% 2-hydroxyethanoate 2-Hydroxyacetic acid methyl ester Glycolic acid methyl Hydroxyacetic acid methyl | [EINECS(EC#)]
202-502-7 | [Molecular Formula]
C3H6O3 | [MDL Number]
MFCD00004667 | [Molecular Weight]
90.08 | [MOL File]
96-35-5.mol |
Chemical Properties | Back Directory | [Appearance]
clear colourless liquid | [Melting point ]
149-151 °C
| [Boiling point ]
149-151 °C(lit.)
| [density ]
1.167 g/mL at 25 °C(lit.)
| [vapor density ]
3.12 (vs air)
| [vapor pressure ]
17 mm Hg ( 52 °C)
| [refractive index ]
n20/D 1.417(lit.)
| [Fp ]
153 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Chloroform, Methanol | [form ]
Liquid | [pka]
13.00±0.10(Predicted) | [color ]
Clear colorless | [Water Solubility ]
Miscible with water. | [Detection Methods]
GC,NMR | [BRN ]
1699571 | [InChIKey]
GSJFXBNYJCXDGI-UHFFFAOYSA-N | [CAS DataBase Reference]
96-35-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Acetic acid, hydroxy-, methyl ester(96-35-5) | [EPA Substance Registry System]
96-35-5(EPA Substance) |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) . S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
29181990 |
Hazard Information | Back Directory | [Chemical Properties]
Clear colorless liquid | [Uses]
Methyl glycolate is a chemical reagent used in the synthesis of taxol and rapamycin. It is used in leather tanning and textile dyeing. It acts as a flavoring agent, preservative in food processing, in water treatment industries and as chemical intermediates. Further, it is used in emulsion polymers, ink and paint additive to improve flow properties and impart gloss. It plays an important role in producing triisopropylsilanyloxy-acetic acid methyl ester using imidazole as reagent. | [General Description]
Synthesis of methyl glycolate from the carbonylation of HCHO using heteropoly acids (HPAs) as catalysts, followed by esterification with methanol was reported. Size-selective vibrational spectroscopy of methyl glycolate clusters was reported. |
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