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ChemicalBook--->CAS DataBase List--->80-62-6

80-62-6

80-62-6 Structure

80-62-6 Structure
IdentificationMore
[Name]

Methyl methacrylate
[CAS]

80-62-6
[Synonyms]

2-METHYLACRYLIC ACID METHYL ESTER
METHACRYLIC ACID METHYL ESTER
METHYL 2-METHYL-2-PROPENOATE
METHYL 2-METHYLPROPENOATE
METHYL A-METHYLACRYLATE
METHYL METHACRYLATE
METHYL METHACRYLATE, MONOMER
MMA
monocite Methacrylate monomer
2-(methoxycarbonyl)-1-propene
2-Methyl-2-propenoic acid methyl ester
2-methyl2-propenoicacid,methylester
2-methyl-2-propenoicacidmethylester
2-methyl-2-propenoicacimethylester
2-Methylacrylic, methyl ester
2-methyl-acrylicacimethylester
2-methylpropenoicacid,methylester
2-Methylpropenoicacidmethylester
2-Propenoicacid,2-methyl-,methylester
Acrylic acid, 2-methyl-, methyl ester
[EINECS(EC#)]

201-297-1
[Molecular Formula]

C5H8O2
[MDL Number]

MFCD00008587
[Molecular Weight]

100.12
[MOL File]

80-62-6.mol
Chemical PropertiesBack Directory
[Appearance]

Methyl methacrylate is a colorless liquid. Acrid, fruity odor. The odor threshold is 0.050.083 ppm
[Melting point ]

-48 °C (lit.)
[Boiling point ]

100 °C (lit.)
[density ]

0.943 g/mL at 20 °C
[vapor density ]

3.5 (vs air)
[vapor pressure ]

29 mm Hg ( 20 °C)
[FEMA ]

4002
[refractive index ]

n20/D 1.414(lit.)
[Fp ]

50 °F
[storage temp. ]

Refrigerator
[solubility ]

15g/l
[form ]

Crystalline Powder or Crystals
[color ]

White to pale yellow
[Odor]

at 0.10 % in dipropylene glycol. acrylic aromatic fruity
[explosive limit]

2.1-12.5%(V)
[Odor Threshold]

0.21ppm
[Odor Type]

acrylate
[Water Solubility ]

15.9 g/L (20 ºC)
[Detection Methods]

GC
[JECFA Number]

1834
[Merck ]

14,5941
[BRN ]

605459
[Henry's Law Constant]

2.46 x 10-4 atm?m3/mol at 20 °C (approximate - calculated from water solubility and vapor pressure)
[Dielectric constant]

2.9(20℃)
[Exposure limits]

NIOSH REL: TWA 100 ppm (410 mg/m3), IDLH 1,000 ppm; OSHA PEL: TWA 100 ppm; ACGIH TLV: TWA 100 ppm with intended TWA and STEL values of 50 and 100 ppm, respectively.
[Stability:]

Volatile
[InChIKey]

VVQNEPGJFQJSBK-UHFFFAOYSA-N
[LogP]

1.38 at 20℃
[CAS DataBase Reference]

80-62-6(CAS DataBase Reference)
[IARC]

3 (Vol. Sup 7, 60) 1994
[NIST Chemistry Reference]

2-Propenoic acid, 2-methyl-, methyl ester(80-62-6)
[EPA Substance Registry System]

80-62-6(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

F,Xi,T
[Risk Statements ]

R11:Highly Flammable.
R37/38:Irritating to respiratory system and skin .
R43:May cause sensitization by skin contact.
R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S24:Avoid contact with skin .
S37:Wear suitable gloves .
S46:If swallowed, seek medical advice immediately and show this container or label .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves .
S16:Keep away from sources of ignition-No smoking .
S7:Keep container tightly closed .
[RIDADR ]

UN 1247 3/PG 2
[WGK Germany ]

1
[RTECS ]

OZ5075000
[Autoignition Temperature]

815 °F
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29161410
[Safety Profile]

Moderately toxic by inhalation and intraperitoneal routes. Mildly toxic by ingestion. Human systemic effects by inhalation: sleep effects, excitement, anorexia, and blood pressure decrease. Experimental teratogenic and reproductive effects. Mutation data reported. A skin and eye irritant. Questionable carcinogen with experimental tumorigenic data. A common air contaminant. A very dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. Explosive in the form of vapor when exposed to heat or flame. The monomer may undergo spontaneous, explosive polymerization. Reacts in air to form a heat-sensitive explosive product (explodes on evaporation at 6OOC). May ignite on contact with benzoyl peroxide. Potentially violent reaction with the polymerization initiators azoisobutyronitrile, dibenzoyl peroxide, di-tert-butyl peroxide, propionaldehyde. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
[Hazardous Substances Data]

80-62-6(Hazardous Substances Data)
[IDLA]

1,000 ppm
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Methanol-->Sulfuric acid-->Sodium cyanide-->CARBON MONOXIDE-->Isobutylene-->Isobutyraldehyde-->HYDROGEN CYANIDE-->Acetone cyanohydrin-->Methyl isobutyrate-->methacrylammonium hydrogen sulphate
[Preparation Products]

Poly(acrylic acid)-->2,2-DICHLORO-1-METHYLCYCLOPROPANAMINE-->Styrene-acrylic latex-->Neoprene adhesive-->4-CHLORO-7-METHYLTHIENO[3,2-D]PYRIMIDINE-->7-Methylthieno[3,2-d]pyrimidin-4(3H)-one-->1-BENZYL-3-METHYL-4-PIPERIDONE-->conductive coating-composite system of acrylic copolymer and cuprous iodide-->CC-2SH adhesive composite used in anterior teeth-->microdispersoid acrylate resin filling emulsion-->GD visible light curing composite resin-->3-CHLORO-4-METHYL-2-THIOPHENECARBOXYLIC ACID-->METHYL 3-CHLORO-4-METHYLTHIOPHENE-2-CARBOXYLATE-->optical diskbase material modified PMMA copolymer-->Procymidone-->binding agent for screen printing-->2,3-DIHYDROXYPROPYL METHACRYLATE-->Poly(methyl methacrylate)-->Thymine-->carboxyl type cation exchange resin-->Methyl 3-amino-4-methylthiophene-2-carboxylate-->Pressure sensitive adhesive-->Leather lustering agent-->THERMOPLASTIC ACRYLIC RESIN-->Bicalutamide-->3-Methacryloxypropyltrimethoxysilane-->thickening agent PAE-->DIHYDROTHYMINE
Hazard InformationBack Directory
[General Description]

A clear colorless liquid. Slightly soluble in water and floats on water. Vapors heavier than air. Vapors irritate the eyes and respiratory system. Containers must be heavily insulated or shipped under refrigeration. An inhibitor such as hydroquinone, hydroquinone methyl ester and dimethyl t-butylphenol is added to keep the chemical from initiating polymerization. The chemical may polymerize exothermically if heated or contaminated with strong acid or base. If the polymerization takes place inside a container, the container may rupture violently. Used to make plastics.
[Reactivity Profile]

METHYL METHACRYLATE MONOMER(80-62-6), may polymerize if contaminated or subjected to heat. If polymerization takes place in a container, the container is subject to violent rupture. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979. p.151-154, 164]. Peroxides may also initiate exothermic polymierization of the bulk material [Bretherick 1979. p. 160]. Benzoyl peroxide was weighed into a beaker that had previously been rinsed with methyl methacrylate. The peroxide catalyzed polymerization of the methyl methacrylate and the build-up of heat ignited the remaining peroxide [MCA Case History 996. 1964].
[Air & Water Reactions]

Highly flammable. Very slightly soluble in water.
[Hazard]

Flammable, dangerous fire risk, explosivelimits in air 2.1–12.5%. Eye and upper respiratorytract irritant, body weight effects, and pulmonaryedema. Questionable carcinogen.
[Health Hazard]

Irritation of eyes, nose, and throat. Nausea and vomiting. Liquid may cause skin irritation.
[Potential Exposure]

Virtually all of the methyl methacrylate monomer produced is used in the production of polymers, such as surface coating resins; plastics (Plexiglas and Lucite); ion exchange resins; and plastic dentures.
[Fire Hazard]

Behavior in Fire: Vapor is heavier than air and may travel a considerable distance to a source of ignition and flash back. Containers may explode in fire or when heated because of polymerization.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN1247 Methyl methacrylate monomer, stabilized, Hazard Class: 3; Labels: 3-Flammable liquid.
[Incompatibilities]

Vapor may form explosive mixture with air. Reacts in air to form a heat-sensitive explosive product @ 60C. Incompatible with nitrates, oxidizers, peroxides, strong acids; strong alkalis; oxidizers, reducing agents; amines, moisture. Contact with benzoyl peroxide may cause ignition, fire and explosion. May polymerize if subjected to heat, polymerization catalysts e. g., azoisobutyronitrile, dibenzoyl peroxide; di-tert-butyl peroxide, propionaldehyde); strong oxidizers; or ultraviolet light. May contain an inhibitor, such as hydroquinone.
[Description]

Methyl methacrylate is an organic compound with the formula CH2=C(CH3)COOCH3. This colourless liquid, the methyl ester of methacrylic acid (MAA) is a monomer produced on a large scale for the production of poly(methyl methacrylate) (PMMA).
[Chemical Properties]

Methyl 2-methyl-2-propenoate has an acrid, penetrating odor. In another report this compound is reported to possess a sharp, fruity odor
[Chemical Properties]

Methyl methacrylate is a colorless liquid. Acrid, fruity odor. The odor threshold is 0.050.083 ppm
[Chemical Properties]

Methyl methacrylate is a methyl ester of methacrylic acid. It is a colourless, volatile liquid with an acrid fruity odour. It has a relatively high vapour pressure (4 kPa at 20°C), moderate water solubility (15.8 g/litre), and a low log octanol/water partition coefficient (Kow = 1.38) . Methyl methacrylate is typically 99.9% pure and contains small amounts of inhibitor to retard polymerization.
[Waste Disposal]

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform to EPA regulations governing storage, transportation, treatment, and waste disposal. Incineration may be allowed.
[Physical properties]

Clear, colorless liquid with a penetrating, fruity odor. An experimentally determined odor threshold concentration of 210 ppbv was reported by Leonardos et al. (1969). Experimentally determined detection and recognition odor threshold concentrations were 200 μg/m3 (49 ppbv) and 1.4 mg/m3 (340 ppbv), respectively (Hellman and Small, 1974).
[Uses]

  1. Methyl methacrylate is a volatile synthetic chemical that is used principally in the production of cast acrylic sheet, acrylic emulsions, and moulding and extrusion resins.
  2. In the manufacture of methacrylate resins and plastics. Methyl methacrylate is transesterified into higher methacrylates such as n-butyl methacrylate or 2-ethylhexyl methacrylate.
  3. methyl methacrylate monomer is used in the production of methylmethacrylate polymers and copolymers, polymers and copolymers are also used in waterborne, solvent, and undissolved surface coatings, adhesives, sealants, leather and paper coatings, inks, floor polishes, textile finishes, dental prostheses, surgical bone cements, and leaded acrylic radiation shields and in the preparation of synthetic fingernails and orthotic shoe inserts. Methyl methacrylate is also used as a starting material to manufacture other esters of methacrylic acid.
  4. Granules for injection and extrusion blow moulding which for their outstanding optical clarity, weathering and scratch resistance are used in lighting, office equipment and electronics (cell phone displays and hi-fi equipment), building and construction (glazing and window frames), contemporary design (furniture, jewellery and tableware), cars and transportation (lights and instrument panels), health and safety (jars and test tubes) and household appliances (microwave oven doors and mixer bowls).
  5. Impact modifiers for clear rigid polyvinyl chloride.
[Uses]

Methyl methacrylatec is used in acrylic bone cements used in orthopedic surgery; in the production of acrylic polymers, polymethylmethacrylate and copolymers used in acrylic surface coatings; in the manufaeture of emulsion polymers; in the modification of unsaturated polyester resins; in the production of higher methacrylate, acrylic fibers, acrylic film, inks, radiation-polymerized impregnants for wood, and solvent-based adhesives and binders; as an impact modifier of PVC; in medicinal spray adhesives; in nonirritant bandage solvents; in dental technology as ceramic filler or cement; to coat corneal contact lenses; in intraocular lenses, artificial nails, and hearing aids; as a monomer for polymethaerylate resins; in the impregnation of concretc.
[Uses]

The principal application, consuming approximately 80% of the MMA, is the manufacture of poly methyl methacrylate acrylic plastics (PMMA). Methyl methacrylate is also used for the production of the co-polymer methyl methacrylate-butadiene-styrene (MBS), used as a modifier for PVC. Another application is as cement used in total hip replacements as well as total knee replacements. Used as the "grout" by orthopedic surgeons to make the bone inserts fix into bone, it greatly reduces post-operative pain from the insertions but has a finite lifespan. Typically the lifespan of methyl methacrylate as bone cement is 20 years before revision surgery is required. Cemented implants are usually only done in elderly populations that require more immediate short term replacements. In younger populations, cementless implants are used because their lifespan is considerably longer. Also used in fracture repair in small exotic animal species using internal fixation.
[Definition]

ChEBI: An enoate ester having methacrylic acid as the carboxylic acid component and methanol as the alcohol component.
[Definition]

methyl methacrylate: An ester ofmethacrylic acid (2-methylpropenoicacid), CH2:C(CH3)COOCH3, used inmaking methacrylate resins.
[Definition]

The methyl ester of methacrylic acid. The compound is used in the manufacture of a number of acrylic polymers, such as Plexiglas (polymethylmethacrylate).
[Preparation]

Prepared by the esterification of methacrylamide sulfate with methanol.
[Aroma threshold values]

Detection at 0.024 to 0.058 ppm (water); recognition at 0.7 to 1.4 mg/m3 (air); detection at 0.2 to 0.62 mg/m3.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 70, p. 1153, 1948 DOI: 10.1021/ja01183a082
The Journal of Organic Chemistry, 33, p. 2525, 1968 DOI: 10.1021/jo01270a082
[Flammability and Explosibility]

Flammable
[Industrial uses]

Initiators for methyl methacrylate polymerization include AIBN, dilauroyl peroxide (LPO), and 2,2'-Azobis[2-(2-imidazolin-2- yl)propane].
[Carcinogenicity]

In several lifetime animal studies, there was no evidence that methyl methacrylate is carcinogenic.
[Environmental Fate]

Chemical/Physical. Polymerizes easily (Windholz et al., 1983). Methyl methacrylate undergoes nucleophilic attack by OH ions in water (hydrolysis) resulting in the formation of methacrylic acid and methanol (Kollig, 1993). Hydrolysis occurs at a rate of 171/M?h at 25 °C (Sharma and Sharma, 1970). No measurable hydrolysis was observed at 85.0 °C (pH 7) and 25 °C (pH 7.07). Hydrolysis half-lives of 9 and 134 min were observed at 66.0 °C (pH 9.86) and 25.0 °C (pH 11.3), respectively (Ellington et al., 1987).
[Purification Methods]

Wash the ester twice with aqueous 5% NaOH (to remove inhibitors such as hydroquinone) and twice with water. Dry it with CaCl2, Na2CO3, Na2SO4 or MgSO4, then with CaH2 under nitrogen under reduced pressure. The distillate is stored at low temperatures and redistilled before use. Prior to distilling, inhibitors such as hydroquinone (0,004%), .-naphthylamine (0.2%) or di--naphthol are sometimes added. Also purify it by boiling with aqueous H3PO4 solution and finally with saturated NaCl solution. It is dried for 24hours over anhydrous CaSO4, distilled at 0.1mm Hg at room temperature and stored at -30o [Albeck et al. J Chem Soc, Faraday Trans 1 1 1488 1978]. [Beilstein 2 II 398, 2 III 1279, 2 IV 1519.]
[Toxicity evaluation]

The mitochondria are regarded as the main intracellular target of MMA. If isolated rat liver mitochondria are incubated with MMA, oxygen consumption increases. This is the result of an uncoupling of the mitochondrial respiratory chain, as seen from the expected influence on state 4 and state 3 respiration. State 4 respiration is stimulated. As has been reported for organic solvents, MMA attacks complex I of the respiratory chain close to the rotenonebinding site. This means that substrates which are oxidized in conjunction with nicotinamide adenine dinucleotide inhibit the flow of electrons and thus also ATP synthesis. Unlike classical uncouplers, MMA stimulates the Mg2+- dependent ATPase bound to the inner mitochondrial membrane. Structural changes in the inner membrane, as found with nonionic detergents, were observed by electron micro scopy. The release of enzymes indicates disintegration of the membrane.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

MMA(80-62-6).msds
Questions and Answers (Q&A)Back Directory
[Production Methods]

Methyl methacrylate (MMA) is the most important ester of methacrylic acid. It can be homo- and copolymerised to produce acrylic resins with good strength, transparency and with excellent weather resistance. The first commercial process for making MMA (1930's), the acetone cyanohydrin route, remains the predominant process in use today. In the acetone cyanohydrin route, acetone cyanohydrin reacts with sulfuric acid at low temperature to produce the sulfuric monoester of 2-hydroxy-2-methyl-propionamide, which forms methacrylamide sulphate after exposure to higher temperatures (100° - 140°C). The liquid phase is maintained by using an excess of 0.2 - 0.7 moles of 100% sulfuric acid. The first step of the reaction is strongly exothermic while the rearrangement of the sulfuric ester is endothermic.
During the synthesis of methacrylamide, a portion of the acetone cyanohydrin decomposes to carbon monoxide during the first part of the reaction. Additionally other by-products are formed and react due to the strength of the acid and high temperature in the second step. About 92 - 94% of the acetone cyanohydrin is converted to useful products and 6 - 8% is consumed in the formation of organic by-products (acetone, acetone sulphonates, olygomers, polymers, others). Methacrylamide sulphate is esterified with a mixture of water and methanol to form MMA and an aqueous solution of ammonium hydrogensulphate, sulfuric acid and the organic by-products. The ammonium hydrogensulphate is an unavoidable by-product of the reaction.
[Toxicity]

The acute toxicity of methyl methacrylate is low. Irritation of the skin, eye, and nasal cavity has been observed in rodents and rabbits exposed to relatively high concentrations of methyl methacrylate. The chemical is a mild skin sensitizer in animals. The effect observed most frequently at lowest concentration after repeated inhalation exposure to methyl methacrylate is irritation of the nasal cavity. Effects on the kidney and liver at higher concentrations have also been reported.
[storage]

Methyl methacrylate is a reactive chemical that must be stored and handled with care. It is stable under recommended storage conditions. Heat can cause polymerization. Inhibitor is added to methyl methacrylate monomer to prevent polymerization. For the inhibitor to be effective, the oxygen concentration in the vapor space must be at least 5%. Store material in containers made of stainless steel, carbon steel, glass, or aluminum. Avoid contact with acids, bases, oxidizing agents, reducing agents, UV light (ultraviolet light, which is found in sunlight), free-radical initiators, and organic peroxides.
Spectrum DetailBack Directory
[Spectrum Detail]

Methyl methacrylate(80-62-6)MS
Methyl methacrylate(80-62-6)1HNMR
Methyl methacrylate(80-62-6)13CNMR
Methyl methacrylate(80-62-6)IR1
Methyl methacrylate(80-62-6)IR2
Methyl methacrylate(80-62-6)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Methylmethacrylate,stabilized,99%(80-62-6)
[Alfa Aesar]

Methyl methacrylate, 99%, stab.(80-62-6)
[TCI AMERICA]

Methyl Methacrylate  (stabilized with 6-tert-Butyl-2,4-xylenol),>99.8%(GC)(80-62-6)
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