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ChemicalBook--->CAS DataBase List--->107-31-3

107-31-3

107-31-3 Structure

107-31-3 Structure
IdentificationMore
[Name]

Methyl formate
[CAS]

107-31-3
[Synonyms]

FORMIC ACID METHYL ESTER
METHANOIC ACID-METHYL ESTER
METHYL FORMATE
METHYL METHANOATE
Formiate de methyle
formiatedemethyle
formiatedemethyle(french)
HCOOCH3
Methyl ester of formic acid
[EINECS(EC#)]

203-481-7
[Molecular Formula]

C2H4O2
[MDL Number]

MFCD00003291
[Molecular Weight]

60.05
[MOL File]

107-31-3.mol
Chemical PropertiesBack Directory
[Appearance]

Methyl formate is a colorless liquid with a pleasant odor.
[Melting point ]

-100 °C (lit.)
[Boiling point ]

32-34 °C (lit.)
[density ]

0.974 g/mL at 20 °C(lit.)
[vapor density ]

2.1 (vs air)
[vapor pressure ]

32.91 psi ( 55 °C)
[refractive index ]

n20/D 1.343(lit.)
[Fp ]

−16 °F
[storage temp. ]

Flammables area
[solubility ]

300g/l
[form ]

Liquid
[color ]

Clear colorless
[Odor]

Pleasant; agreeable.
[PH]

4-5 (200g/l, H2O, 20℃)
[Stability:]

Stable. Extremely flammable. Readily forms explosive mixtures with air. Note low flash point and very wide explosion limits. Incompatible with oxidizing agents.
[explosive limit]

5-23%(V)
[Odor Threshold]

130ppm
[Odor Type]

fruity
[Water Solubility ]

300 G/L (20 ºC)
[λmax]

λ: 259 nm Amax: 1.00
λ: 260 nm Amax: 0.70
λ: 265 nm Amax: 0.20
λ: 270 nm Amax: 0.04
λ: 310-400 nm Amax: 0.01
[Merck ]

14,6077
[BRN ]

1734623
[Henry's Law Constant]

0.90 at 5.00 °C, 1.18 at 10.00 °C, 1.51 at 15.00 °C, 1.91 at 20.00 °C, 2.36 at 25.00 °C (column stripping-UV, Kutsuna et al., 2005)
[Dielectric constant]

8.5(20℃)
[Exposure limits]

TLV-TWA 100 ppm (~250 mg/m3) (ACGIH, MSHA, and OSHA); TLV-STEL 150 ppm (~375 mg/m3) (ACGIH); IDLH 5000 ppm (NIOSH).
[LogP]

-0.21 at 25℃
[CAS DataBase Reference]

107-31-3(CAS DataBase Reference)
[NIST Chemistry Reference]

Methyl formate(107-31-3)
[EPA Substance Registry System]

107-31-3(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

F+,Xn
[Risk Statements ]

R12:Extremely Flammable.
R20/22:Harmful by inhalation and if swallowed .
R36/37:Irritating to eyes and respiratory system .
[Safety Statements ]

S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking .
S24:Avoid contact with skin .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S33:Take precautionary measures against static discharges .
[OEB]

A
[OEL]

TWA: 100 ppm (250 mg/m3), STEL: 150 ppm (375 mg/m3)
[RIDADR ]

UN 1243 3/PG 1
[WGK Germany ]

1
[RTECS ]

LQ8925000
[Autoignition Temperature]

842 °F
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

I
[HS Code ]

2915 13 00
[Safety Profile]

Moderately toxic by ingestion. Inhalation of vapor can cause irritation to nasal passages and conjunctiva, optic neuritis, narcosis, retching, and death from pulmonary irritation. Industrial fatalities have occurred only with exposure to high concentrations. Flammable liquid. Very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. Explosive in the form of vapor when exposed to heat or flame. Reacts with methanol + sodium methoxide to form an explosive product. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
[Hazardous Substances Data]

107-31-3(Hazardous Substances Data)
[Toxicity]

LD50 orally in Rabbit: 1500 mg/kg LD50 dermal Rat > 4000 mg/kg
[IDLA]

4,500 ppm
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Iridium
[Preparation Products]

N,N-Dimethylformamide-->Formic acid-->Formamide-->Bensulfuron methyl-->METSULFURON METHYL-->1,2,4-Triazole-->Tribenuron methyl-->3,4-Dimethylpyrazole phosphate-->3,5-DIFLUOROPYRIDINE-4-CARBALDEHYDE-->2-Fluoropyridine-5-carboxaldehyde-->5-methoxy-2-(methylthio)pyrimidin-4-ol ,97%-->2,4-Dichloro-5-methoxypyrimidine-->2-Bromo-5-fomylthiazole-->Sulfometuron-methyl-->Nicarbazin-->Olaquindox-->Procymidone-->Imidazole-2-carboxaldehyde-->4-CHLORO-5-METHOXY-2-(METHYLSULFANYL)PYRIMIDINE-->N-Methylformamide-->Ethametsulfuron-methyl-->2,3-Quinoline dicarboxylic acid-->5-ETHYL-2-THIOURACIL-->4(1H)-Pyrimidinone, 2-methyl- (8CI,9CI)-->1,1-Dichlorodimethyl ether-->5-METHOXY-2-SULFANYL-4-PYRIMIDINOL-->1-Formylhomopiperazine-->Methyl 4-acetamido-5-chloro-2-methoxybenzoate-->2-[2-[4-[(4-ethoxyphenyl)methylamino]phenyl]vinyl]-5-(methoxycarbonyl)-1,3,3-trimethyl-3H-indolium chloride-->4-Formylmorpholine-->Methyl 2-amino-3,5-dibromobenzoate-->1,4-DIFORMYLPIPERAZINE-->pyrante
Hazard InformationBack Directory
[General Description]

Methyl formate(107-31-3) appears as a clear colorless liquid with an agreeable odor. Flash point -27 °F. Less dense than water Vapors heavier than air.
[Reactivity Profile]

METHYL FORMATE(107-31-3) reacts with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated with caustic solutions. Flammable hydrogen is generated by mixing with alkali metals and hydrides.
[Air & Water Reactions]

Highly flammable. Water soluble. Reacts slowly with water to give formic acid, a corrosive material, and methanol, a flammable liquid. Both products are dissolved in the water.
[Hazard]

Flammable, dangerous fire and explosionrisk, explosive limits in air 5.9–20%. Eye, upperand lower respiratory tract irritant.
[Health Hazard]

Inhalation causes irritation of mucous membranes. Prolonged inhalation can produce narcosis and central nervous symptoms, including some temporary visual disturbance. Contact with liquid irritates eyes and may irritate skin if allowed to remain. Ingestion causes irritation of mouth and stomach and central nervous system depression, including visual disturbances.
[Potential Exposure]

Methyl formate is used as a solvent; as an intermediate in pharmaceutical manufacture; and as a fumigant
[Fire Hazard]

Behavior in Fire: Vapor is heavier than air and may travel considerable distance to a source of ignition and flash back.
[Incompatibilities]

May form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Reacts slowly with water to form methanol and formic acid. Contact with water, steam releases formic acid. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates isocyanates, mercaptans, nitrides, and sulfides (releasing heat, toxic, and possibly flammable gases), thiosulfates and dithionites (releasing hydrogen sulfate and oxides of sulfur)
[Chemical Properties]

Methyl formate is a colorless liquid with a pleasant odor. Its solubility in water is 230 g/l at 25 °C (Riddick et al., 1985), but it reacts slowly with water to form formic acid and methyl alcohol (DOT, 1984). It is soluble in ether, chloroform, and is miscible with ethanol (Lide, 2000).
[Waste Disposal]

Incineration; atomizing in a suitable combustion chamber.
[Physical properties]

Clear, colorless, mobile liquid with a pleasant, etheral odor. An odor threshold concentration of 130 ppmv was reported by Nagata and Takeuchi (1990).
[Uses]

Methyl formate is used as a fumigant, as alarvicide for food crops, and as a solvent forcellulose acetate.
[Uses]

Methyl formate(107-31-3) is used primarily to manufacture formamide, dimethyl formamide, and formic acid. Because of its high vapor pressure, it is used for quick - drying finishes. It is also used as an insecticide and to manufacture certain pharmaceuticals. Foam Supplies, Inc. has trademarked Ecomate, which is used as a blowing agent for foam insulation, as a replacement for CFC, HCFC, or HFCs, with zero ozone depletion potential and < 25 global warming potential.
A historical use of methyl formate, which sometimes brings it attention, was in refrigeration. Before the introduction of less-toxic refrigerants, methyl formate was used as an alternative to sulfur dioxide in domestic refrigerators, such as some models of the famous GE Monitor Top. Owners of methyl formate refrigerators should keep in mind that, even though they operate below atmospheric pressure, if evidence of a leak develops, they should take measures to avoid exposure to the ether-smelling liquid and vapor.
[Definition]

ChEBI: Methyl formate is a formate ester resulting from the formal condensation of formic acid with methanol. A low-boiling (31.5 ℃) colourless, flammable liquid, it has been used as a fumigant and larvicide for tobacco and food crops. It has a role as a polar aprotic solvent, a fumigant, an insecticide and a refrigerant. It is a formate ester, a methyl ester and a volatile organic compound. It is functionally related to a methanol.
[Production Methods]

In the laboratory, methyl formate can be produced by the condensation reaction of methanol and formic acid, as follows:
HCOOH + CH3OH → HCOOCH3 + H2O
Industrial methyl formate, however, is usually produced by the combination of methanol and carbon monoxide (carbonylation) in the presence of a strong base, such as sodium methoxide :
CH3OH + CO → HCOOCH3
This process, practiced commercially by BASF among other companies gives 96 % selectivity toward methyl formate, although it can suffer from catalyst sensitivity to water, which can be present in the carbon monoxide feedstock, commonly derived from synthesis gas. Very dry carbon monoxide is, therefore, an essential requirement.
[Chemical Reactivity]

Reactivity with Water Slow reaction to form formic acid and methyl alcohol; reaction is not hazardous; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
[First aid]

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifing upper and lower lids. Seek med-facility. When this chemical has been swallowed, get medi-cal attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.Medical observation is recommended for 24- -48 h afterbreathing overexposure, as pulmonaryedema may bedelayed. As first aid for pulmonary edema, a doctor orauthorized paramedic may consider administering a cortico-steroid spray.
[Environmental Fate]

Photolytic. Methyl formate, formed from the irradiation of dimethyl ether in the presence of chlorine, degraded to carbon dioxide, water, and small amounts of formic acid. Continued irradiation degraded formic acid to carbon dioxide, water, and hydrogen chloride (Kallos and Tou, 1977; Good et al., 1999).
A rate constant of 2.27 x 10-12 cm3/molecule?sec was reported for the reaction of methyl formate and OH radicals in the atmosphere (Atkinson, 1989).
Chemical/Physical. Hydrolyzes slowly in water forming methanol and formic acid (NIOSH, 1997). Hydrolysis half-lives reported at 25 °C: 0.91 h at pH 9, 9.1 h at pH 8, 2.19 d at pH 7, and 21.9 d at pH 6 (Mabey and Mill, 1978).
[storage]

Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Prior to working with this chemical you should be trainedon its proper handling and storage. Before entering confinedspace where this chemical may be present, check to makesure that an explosive concentration does not exist. Methylformate must be stored to avoid contact with strong oxidizers, such as chlorine, bromine, chlorine dioxide, nitrates,and permanganates, since violent reactions occur. Store intightly closed containers in a cool, well-ventilated areaaway from heat. Sources of ignition, such as smoking andopen flames, are prohibited where methyl formate is handled, used, or stored. Metal containers involving the transferof 5 gallons or more of methyl formate should be groundedand bonded. Drums must be equipped with self-closingvalves, pressure vacuum bungs, and flame arresters. Useonly nonsparking tools and equipment, especially whenopening and closing containers of methyl formate.Wherever methyl formate is used, handled, manufactured,or stored, use explosion-proof electrical equipment andfittings.
[Shipping]

This compound requires a shipping label of“FLAMMABLE LIQUID.” It falls in Hazard Class 3 andPacking Group I.
[Purification Methods]

Wash the formate with strong aqueous Na2CO3, dry it with solid Na2CO3 and distil it from P2O5. (Procedure removes free alcohol or acid.) [Beilstein 2 IV 20.]
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

methyl formate(107-31-3).msds
Questions and Answers (Q&A)Back Directory
[Description]

Methyl Formate, also known as methyl methanoate, is the methyl ester of formic acid. The simplest example of an ester, it is a clear liquid with an ethereal odour, high vapor pressure, and low surface tension. It is an aromatic compound found in apples (Neubeller and Buchloh, 1986), and was identified as a volatile constituent in brewed, roasted, and dried coffee (Lovell et al., 1980); Methyl formate is used primarily to manufacture formamide, dimethylformamide, and formic acid. It is also used as a solvent for quick-drying finishes such as lacquers and in organic synthesis.
[References]

Lee, Jae S., J. C. Kim, and Y. G. Kim. "Methyl formate as a new building block in C1 chemistry." Applied Catalysis 57.1 (1990): 1-30.
Handa, Yash Paul, et al. "Insulating Thermoplastic Foams Made With Methyl Formate-Based Blowing Agents." (2006).
Spectrum DetailBack Directory
[Spectrum Detail]

Methyl formate(107-31-3)MS
Methyl formate(107-31-3)1HNMR
Methyl formate(107-31-3)13CNMR
Methyl formate(107-31-3)IR1
Methyl formate(107-31-3)IR2
Methyl formate(107-31-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Methyl formate, extra pure, 97%(107-31-3)
[Alfa Aesar]

Methyl formate, 97%, may cont. up to ca 3% methanol(107-31-3)
[Sigma Aldrich]

107-31-3(sigmaaldrich)
[TCI AMERICA]

Methyl Formate,>98.0%(GC)(107-31-3)
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