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ChemicalBook--->CAS DataBase List--->77287-29-7

77287-29-7

77287-29-7 Structure

77287-29-7 Structure
IdentificationMore
[Name]

(R)-(+)-Methyl (R)-2-chloropropionate
[CAS]

77287-29-7
[Synonyms]

METHYL (R)-(+)-2-CHLOROPROPIONATE
(R)-(+)-2-CHLOROPROPIONIC ACID METHYL ESTER
(R)-(+)-METHYL 2-CHLOROPROPIONATE
(R)-(+)-Methyl (R)-2-chloropropionate
2 METHYL CHLORPROPIONATE
METHYL (R)-(+)-2-CHLOROPROPIONATE, 99% (
2-Methylchloroproprionate
2-Methylchlorproprionate
(2R)-2-Chloropropanoic acid methyl ester
(R)-2-Chloropropionic acid methyl
[EINECS(EC#)]

278-658-5
[Molecular Formula]

C4H7ClO2
[MDL Number]

MFCD00062940
[Molecular Weight]

122.55
[MOL File]

77287-29-7.mol
Chemical PropertiesBack Directory
[alpha ]

26 º (neat)
[Boiling point ]

132-134 °C(lit.)
[density ]

1.152 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.418
[Fp ]

99 °F
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[optical activity]

[α]20/D +26°, neat
[BRN ]

1720590
[CAS DataBase Reference]

77287-29-7(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 2933 3/PG 3
[WGK Germany ]

3
[F ]

19
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29159000
Hazard InformationBack Directory
[Chemical Properties]

Clear colorless liquid
[Uses]

Chiral starting material
[Purification Methods]

Purify the ester by repeated distillation [Walker J Chem Soc 67 916 1895, Walden Chem Ber 28 1293 1985, see also Gless Synth Commun 16 633 1986]. [Beilstein 2 H 248.]
Spectrum DetailBack Directory
[Spectrum Detail]

(R)-(+)-Methyl (R)-2-chloropropionate(77287-29-7)1HNMR
(R)-(+)-Methyl (R)-2-chloropropionate(77287-29-7)IR
(R)-(+)-Methyl (R)-2-chloropropionate(77287-29-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

77287-29-7(sigmaaldrich)
[TCI AMERICA]

Methyl (R)-(+)-2-Chloropropionate,>98.0%(GC)(77287-29-7)
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