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ChemicalBook--->CAS DataBase List--->554-12-1

554-12-1

554-12-1 Structure

554-12-1 Structure
IdentificationMore
[Name]

Methyl propionate
[CAS]

554-12-1
[Synonyms]

C3
FEMA 2742
METHYL PROPANOATE
METHYL PROPIONATE
METHYL PROPYLATE
PROPANOIC ACID METHYL ESTER
PROPIONIC ACID METHYL ESTER
RARECHEM AL BF 0159
TRIANOIC ACID METHYL ESTER
C2H5COOCH3
femanumber2742
Methyl ester of propanoic acid
Methylester kyseliny propionove
methylesterkyselinypropionove
Propionate de methyle
propionatedemethyle
propionatedemethyle(french)
METHYL PROPIONATE, STANDARD FOR GC
METHYL PROPIONATE 98+%
METHYL PROPIONATE OEKANAL
[EINECS(EC#)]

209-060-4
[Molecular Formula]

C4H8O2
[MDL Number]

MFCD00009306
[Molecular Weight]

88.11
[MOL File]

554-12-1.mol
Chemical PropertiesBack Directory
[Appearance]

Methyl propionate is colorless liquid with a sweet, fruity, rum-like odor.
[Melting point ]

-88 °C (lit.)
[Boiling point ]

79 °C (lit.)
[density ]

0.915 g/mL at 25 °C(lit.)
[vapor density ]

3 (vs air)
[vapor pressure ]

40 mm Hg ( 11 °C)
[FEMA ]

2742
[refractive index ]

n20/D 1.376(lit.)
[Fp ]

43 °F
[storage temp. ]

Flammables area
[solubility ]

H2O: soluble16 parts
[form ]

Liquid
[color ]

Clear colorless
[Odor]

at 100.00 %. fresh harsh rum fruity strawberry apple
[Stability:]

Stable. Highly flammable. Incompatible with strong oxidizing agents, acids, bases. Readily forms explosive mixtures with air. Moisture sensitive.
[explosive limit]

2.5-13%(V)
[Odor Type]

fruity
[Water Solubility ]

5 g/100 mL at 20 ºC
[JECFA Number]

141
[Merck ]

14,6112
[BRN ]

1737628
[Dielectric constant]

5.5(19℃)
[LogP]

0.8 at 26.6℃
[CAS DataBase Reference]

554-12-1(CAS DataBase Reference)
[NIST Chemistry Reference]

Propanoic acid, methyl ester(554-12-1)
[EPA Substance Registry System]

554-12-1(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

F,Xn
[Risk Statements ]

R11:Highly Flammable.
R20:Harmful by inhalation.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S24:Avoid contact with skin .
S29:Do not empty into drains .
S33:Take precautionary measures against static discharges .
[RIDADR ]

UN 1248 3/PG 2
[WGK Germany ]

1
[RTECS ]

UF5970000
[Autoignition Temperature]

876 °F
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29155090
[Safety Profile]

Moderately toxic by ingestion. Mildly toxic by inhalation. A skin irritant. A very dangerous fire hazard when exposed to heat, flame, or oxidizers. Explosive in the form of vapor when exposed to heat or flame. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
[Hazardous Substances Data]

554-12-1(Hazardous Substances Data)
[Toxicity]

LD50 orally in Rabbit: 5000 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Propionic acid-->Methyl 4-oxobutanoate
[Preparation Products]

Metalaxyl-->Antioxidant 1010-->Ramipril-->1-Benzyl-4-piperidone-->1-BENZYL-4-HYDROXY-4-(3-TRIFLUOROTOLYL)PIPERIDINOL-->Procymidone-->Methyl 1-benzyl-4-oxo-3-piperidine-carboxylate hydrochloride-->Benalaxyl-->efficient polymer catalyst for acrylation-synthesis and characterigation of polyamide containing supernucleophilic reagent-->CYANOACRYLIC ACID METHYL ESTER-->Ethyl 2-chloropropionate-->antioxidant 1024-->4-Amino-6-chloropyrimidine-->CARBETAMIDE-->Boronal-->Methyl 3-methylthiopropionate-->DICLOFOP-METHYL-->CIS-1,2-DIMETHYL-CYCLOPROPANEDICARBOXYLIC ACID DIMETHYL ESTER-->Disperse Red 127
Hazard InformationBack Directory
[General Description]

A clear colorless liquid. Flash point 28°F. Density about the same as water. Vapors heavier than air. May irritate skin, eyes, and mucous membranes. Used for flavoring and as a solvent.
[Reactivity Profile]

METHYL PROPIONATE(554-12-1) reacts with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction with caustic solutions. Flammable hydrogen is generated with alkali metals and hydrides.
[Air & Water Reactions]

Highly flammable. Soluble in water.
[Hazard]

Flammable, dangerous fire risk, explosivelimits in air 2.5–13%.
[Health Hazard]

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
[Potential Exposure]

Used as a solvent; and in making paints, lacquers, and varnishes. Also used in flavorings and fragrances
[Fire Hazard]

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN1248 Methyl propionate, Hazard Class: 3; Labels: 3-Flammable liquid.
[Incompatibilities]

May form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Keep away from heat and moisture.
[Chemical Properties]

colourless liquid
[Chemical Properties]

Methyl propionate has a fruity odor reminiscent of rum with a sweet flavor suggestive of black currant. May be prepared by direct esterification of the acid with methanol in the presence of concentrated H2S04.
[Chemical Properties]

Methyl propionate has a fruity odor reminiscent of rum. It has a sweet flavor suggestive of black currant
[Chemical Properties]

Methyl propionate is colorless liquid with a sweet, fruity, rum-like odor.
[Occurrence]

Reported found in guava, honey, melon, pineapple, raspberry, blackberry, strawberry, cheddar cheese, cooked beef, coffee, soy protein, durian (Durio zibethinus), starfruit, plum brandy, cherimoya, kiwifruit, naranjilla, mussels and rooibus tea (Aspalathus linearis)
[Uses]

In organic synthesis.
[Uses]

Methyl propionate is used as a solvent for cellulose nitrate and lacquers, and as a raw material for the production of paints, varnishes and other chemicals such as methyl methacrylate.
Due to its fruity smell and taste, it is also used in fragrances and flavoring.
[Definition]

ChEBI: Methyl propionate is a carboxylic ester.
[Preparation]

Methyl propionate can be prepared by esterification of propionic acid with methanol. Industrially, it is prepared by the reaction of ethylene with carbon monoxide and methanol in the presence of nickel carbonyl.
[Production Methods]

Methyl propionate is produced by the direct esterification of propionic acid with methanol in the presence of concentrated sulfuric acid .
[Aroma threshold values]

Detection: 100 ppb to 8.8 ppm
[Flammability and Explosibility]

Flammable
[Synthesis]

By direct esterification of the acid with methanol in the presence of concentrated H2SO4
[storage]

Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Prior to working with methyl propionate you should betrained on its proper handling and storage. Before enteringconfined space where this chemical may be present, checkto make sure that an explosive concentration does not exist.Store in tightly closed containers in a cool, well-ventilatedarea away from oxidizers, strong acids, strong bases. Wherepossible, automatically pump liquid from drums or otherstorage containers to process containers. Drums must beequipped with self-closing valves, pressure vacuum bungs,and flame arresters. Use only nonsparking tools and equipment, especially when opening and closing containers ofthis chemical. Wherever this chemical is used, handled,manufactured, or stored, use explosion-proof electricalequipment and fittings.
[Purification Methods]

Wash the ester with saturated aqueous NaCl, then dry it with Na2CO3 and distil it from P2O5. (This removes any free acid and alcohol.) It has also been dried with anhydrous CuSO4. [Beilstein 2 IV 104.]
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

methyl propionate(554-12-1).msds
Questions And AnswerBack Directory
[Description]

Methyl propionate is an organic compound belonging to the family of carboxylic acid esters, which is commonly applied as a solvent for cellulose nitrate and lacquers. It also serves as a raw material in organic synthesis for manufacturing paints, varnishes and other chemical productions such as methyl methacrylate. Besides, the fruity smell and taste of methyl propanoate results in its usage of fragrances and flavoring agents.
Methyl propanoate can be synthesized by esterifying propionic acid with methanol. In the field of industry, it is produced by the reaction of ethylene with carbon monoxide and methanol in the presence of nickel carbonyl.
[References]

https://en.wikipedia.org/wiki/Methyl_propionate
https://pubchem.ncbi.nlm.nih.gov/compound/11124#section=Top
https://www.alfa.com/zh-cn/catalog/A14944/
Spectrum DetailBack Directory
[Spectrum Detail]

Methyl propionate(554-12-1)MS
Methyl propionate(554-12-1)1HNMR
Methyl propionate(554-12-1)13CNMR
Methyl propionate(554-12-1)IR1
Methyl propionate(554-12-1)IR2
Methyl propionate(554-12-1)IR3
Methyl propionate(554-12-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Methyl propionate, 99+%(554-12-1)
[Alfa Aesar]

Methyl propionate, 99%(554-12-1)
[Sigma Aldrich]

554-12-1(sigmaaldrich)
[TCI AMERICA]

Methyl Propionate,>99.0%(GC)(554-12-1)
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