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ChemicalBook--->CAS DataBase List--->677-69-0

677-69-0

677-69-0 Structure

677-69-0 Structure
IdentificationMore
[Name]

Heptafluoroisopropyl iodide
[CAS]

677-69-0
[Synonyms]

1,1,1,2,3,3,3-heptafluoro-2-iodo-propane
2-HEPTAFLUOROISOPROPYLIODIDE
2-IODOHEPTAFLUOROPROPANE
2-IODOPERFLUOROPROPANE
HEPTAFLUORO-2-IODOPROPANE
HEPTAFLUOROISOPROPYL IODIDE
PERFLUORO-2-IODOPROPANE
PERFLUOROISOPROPYL IODIDE
1,1,1,2,3,3,3-heptafluoro-2-iodo-propan
Heptafluoroiodopropane
Isoheptafluoropropyliodide
Propane, heptafluoro-2-iodo-
2-Iodo-1,1,1,2,3,3,3-heptafluoropropane
PERFLUORO-ISO-PROPYL IODIDE 98%
2-Iodoheptafluoropropane 98%
2-Iodoheptafluoropropane98%
HEPTAFLUORO-2-IODOPROPANE , STABILIZED WITH COPPER
Heptafluoro-2-iodopropane, 97%, stab. with copper powder
Heptafluoro-2-iodopropane, 97%, stab. with copper
2-Iodoperfluoropropane, Heptafluoroisopropyl iodide, Perfluoroisopropyl iodide
[EINECS(EC#)]

211-643-3
[Molecular Formula]

C3F7I
[MDL Number]

MFCD00042089
[Molecular Weight]

295.93
[MOL File]

677-69-0.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to yellowish liquid
[Melting point ]

-58 °C
[Boiling point ]

40 °C (lit.)
[density ]

2.08 g/mL at 25 °C(lit.)
[vapor pressure ]

7.12 psi ( 20 °C)
[refractive index ]

n20/D 1.329(lit.)
[Fp ]

38°C
[storage temp. ]

Keep Cold
[Specific Gravity]

2.10
[Water Solubility ]

insoluble
[Sensitive ]

Light Sensitive
[BRN ]

1841228
[Exposure limits]

ACGIH: TWA 0.01 ppm
[InChIKey]

BBZVTTKMXRPMHZ-UHFFFAOYSA-N
[CAS DataBase Reference]

677-69-0(CAS DataBase Reference)
[NIST Chemistry Reference]

Propane, 1,1,1,2,3,3,3-heptafluoro-2-iodo-(677-69-0)
[EPA Substance Registry System]

677-69-0(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi,T
[Risk Statements ]

R20:Harmful by inhalation.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

2810
[WGK Germany ]

3
[RTECS ]

TZ3925000
[F ]

8
[Hazard Note ]

Irritant
[TSCA ]

T
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[HS Code ]

29037800
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1,1,1,2,3,3,3-heptafluoro-2-iodo-propane(677-69-0).msds
Hazard InformationBack Directory
[Chemical Properties]

clear colorless to yellowish liquid
[Uses]

Heptafluoro-2-iodopropane may be used in the preparation of perfluoropropyl magnesium bromide and perfluoropropyl magnesium iodide. It may be used as chain-transfer agent in telomerization reactions of:
  • 1,1-difluoroethylene and tetrafluoroethylene
  • CF3I, C2F5I and n-C3F7I with 1,1-difluoroethylene
  • n-C3F7I with tetrafluoroethylene
[General Description]

Heptafluoro-2-iodopropane is a secondary fluoro alkyl iodide. It can be prepared by addition of iodine monofluoride to hexafluoropropene.
[Flammability and Explosibility]

Nonflammable
[Purification Methods]

Purify it by gas chromatography on a triacetin (glyceryl triacetate) column, followed by bulb-to-bulb distillation at low temperature. Store it over Cu powder to stabilise it. UV has max at 271nm ( 240) in pet ether (b 60-80o). [Haszeldine J Chem Soc 1767, 3761 1953, Beilstein 1 III 255, 1 IV 225.]
Spectrum DetailBack Directory
[Spectrum Detail]

Heptafluoroisopropyl iodide(677-69-0)MS
Heptafluoroisopropyl iodide(677-69-0)1HNMR
Heptafluoroisopropyl iodide(677-69-0)13CNMR
Heptafluoroisopropyl iodide(677-69-0)IR1
Heptafluoroisopropyl iodide(677-69-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Heptafluoroisopropyl iodide, 99%(677-69-0)
[Alfa Aesar]

Heptafluoro-2-iodopropane, 97%, stab. with copper powder(677-69-0)
[Sigma Aldrich]

677-69-0(sigmaaldrich)
[TCI AMERICA]

Heptafluoroisopropyl Iodide,>98.0%(GC)(677-69-0)
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