| Identification | More | [Name]
PROPANE | [CAS]
74-98-6 | [Synonyms]
DIMETHYLMETHANE
EXPLOSIMETRY STANDARD EX-2
PROPANE, NATURAL
A-108
C3H8
Freon 290
HC290
HC-290
Hydrocarbon propellant
hydrocarbonpropellanta-108
Liquefied petroleum gas
Lpg
normalpropane
n-Propane
Propagas
Propan
propane,highpurity
Propyl hydride
propyldihydride
propylhydride | [EINECS(EC#)]
200-827-9 | [Molecular Formula]
C3H8 | [MDL Number]
MFCD00009359 | [Molecular Weight]
44.1 | [MOL File]
74-98-6.mol |
| Chemical Properties | Back Directory | [Description]
Propane is colourless and odourless, with a mercaptan odour. Like all fossil fuels, propane
is a non-renewable energy source. Propane is a gas derived from natural gas
and petroleum. It is found mixed with natural gas and petroleum deposits. Propane is
called a ‘fossil fuel’ because it was formed millions of years ago from the remains of tiny
sea animals and plants. Propane is a clean-burning, versatile fuel. It is used by nearly
everyone, in homes, on farms, by business, and in industry mostly for producing heat and
operating equipment. Propane is one of the many fossil fuels included in the liquefied
petroleum gas (LPG) family. Because propane is the type of LPG most commonly used in
the United States, propane and LPG are often used synonymously. Butane is another LPG
often used in lighters. | [Appearance]
Propane is a colorless gas that is odorless
when pure (a foul-smelling odorant is often added) | [Melting point ]
-188 °C(lit.)
| [Boiling point ]
-42.1 °C(lit.)
| [density ]
0.564 g/mL at 20 °C(lit.) | [vapor density ]
1.5 (vs air)
| [vapor pressure ]
190 psi ( 37.7 °C)
| [refractive index ]
1.2861 | [Fp ]
-104 °C | [storage temp. ]
-20°C | [form ]
liquid | [pka]
≈ 44 (Gordon and Ford, 1972) | [Stability:]
Stable. Incompatible with strong oxidizing agents. Highly flammable. May form explosive mixtures with air. | [explosive limit]
9.5% | [Odor Threshold]
1500ppm | [Water Solubility ]
62.61mg/L(25 ºC) | [Merck ]
13,7891 | [BRN ]
1730718 | [Henry's Law Constant]
0.706 at 25 °C (Hine and Mookerjee, 1975) | [Dielectric constant]
1.6（Ambient） | [Exposure limits]
TLV-TWA 1000 ppm (OSHA). | [LogP]
2.360 | [Uses]
Propane has been used as a transportation fuel since its discovery. It was first used as an automobile fuel in 1913. It follows gasoline and diesel as the third most popular vehicle fuel and today powers more than half a million vehicles in the United States and 6 million worldwide. The widespread use of propane is hampered by the lack of a distribution system, but it has been used to fuel fleets of buses, taxis, and government vehicles. Also, it is heavily used to power equipment such as forklifts. Propane is cleaner burning than gasoline or diesel and has been used to reduce urban air pollution. Compared to gasoline it emits 10–40% of the carbon monoxide, 30–60% of the hydrocarbons, and 60–90% of the carbon dioxide. An advantage of cleaner burning propane is that engine maintenance is improved because of lower engine deposits and fouling. Propane’s octane ratings range between 104 and 110. The lower emissions are somewhat compromised by propane’s lower energy value; propane has about 75% of the energy content of gasoline when compared by volume. Propane is separated from natural gas and is also produced during petroleum processing. Approximately 53% of the propane produced in the United States comes from the small fraction (less than 5%) found in natural gas and the remainder comes petroleum refining. | [CAS DataBase Reference]
74-98-6(CAS DataBase Reference) | [EPA Substance Registry System]
Propane (74-98-6) |
| Hazard Information | Back Directory | [Chemical Properties]
Propane is released to the living environment from automobile exhausts, burning furnaces,
natural gas sources, and during combustion of polyethylene and phenolic resins.
Propane is both highly inflammable and explosive and needs proper care and management
of workplaces. Its use in industry includes as a source for fuel and propellant for
aerosols. Occupational workers exposed to liquefi ed propane have demonstrated skin
burns and frostbite. Propane also causes depression effects on the CNS. | [General Description]
A colorless gas with a faint petroleum-like odor. PROPANE(74-98-6) is shipped as a liquefied gas under its vapor pressure. For transportation PROPANE(74-98-6) may be stenched. Contact with the unconfined liquid can cause frostbite by evaporative cooling. Easily ignited. The vapors are heavier than air and a flame can flash back to the source of leak very easily. The leak may be either a liquid or vapor leak. The vapors can asphyxiate by the displacement of air. Under prolonged exposure to fire or heat the containers may rupture violently and rocket. | [Reactivity Profile]
PROPANE is incompatible with strong oxidizing agents. | [Air & Water Reactions]
Highly flammable. | [Hazard]
Asphyxiant. Flammable, dangerous fire
risk, explosive limits in air 2.4–9.5%. For storage,
see butane (note).
| [Health Hazard]
Vaporizing liquid may cause frostbite. Concentrations in air greater than 10% cause dizziness in a few minutes. 1% concentrations give the same effect in 10 min. High concentrations cause asphyxiation. | [Potential Exposure]
Flammable gas. May form explosive
mixture with air. Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo-
sions. Keep away from alkaline materials, strong bases,
strong acids, oxoacids, epoxides. Liquid attacks some plas-
tics, rubber and coatings. | [Fire Hazard]
Behavior in Fire: Containers may explode. Vapor is heavier than air and may travel a long distance to a source of ignition and flash back. | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions, includ-
ing resuscitation mask) if breathing has stopped and CPR if
heart action has stopped. Transfer promptly to a medical
facility. When this chemical has been swallowed, get medi-
cal attention. Give large quantities of water and induce
vomiting. Do not make an unconscious person vomit. If
frostbite has occurred, seek medical attention immediately;
do NOT rub the affected areas or flush them with water.
In order to prevent further tissue damage, do NOT attempt
to remove frozen clothing from frostbitten areas. If frostbite
has NOT occurred, immediately and thoroughly wash
contaminated skin with soap and water. | [Shipping]
UN1978 Propane, Hazard Class: 2.1; Labels:
2.1-Flammable gas. UN1075 Petroleum gases, liquefied or
Liquefied petroleum gas, Hazard Class: 2.1; Labels:
2.1-Flammable gas. Cylinders must be transported in
a secure upright position, in a well-ventilated truck.
Protect cylinder and labels from physical damage. The
owner of the compressed gas cylinder is the only entity
allowed by federal law (49CFR) to transport and refill
them. It is a violation of transportation regulations to
refill compressed gas cylinders without the express written
permission of the owner. | [Waste Disposal]
Return refillable compressed
gas cylinders to supplier. Dissolve or mix the material
with a combustible solvent and burn in a chemical
incinerator equipped with an afterburner and scrubber. All
federal, state, and local environmental regulations must
be observed. | [Physical properties]
Propane is a colorless, odorless, flammable gas that follows methane and ethane in the alkane
series. The root word prop comes from the three-carbon acid propionic acid, CH3CH2COOH.
Propionic acid comes from the Greek words protos meaning first and pion meaning fat.It was
the smallest acid with fatty acid properties. Propane is the gas used to fuel barbecues and camp
stoves giving it the common name bottled gas.It is marketed as liquefied petroleum gas (LPG)
or liquefied petroleum; it should be noted that LPG is often a mixture that may contains
butane, butylene, and propylene in addition to propane. In addition to cooking, propane can
be used as an energy source for space heating, refrigeration, transportation, and heating appliances
(clothes dryer).
Propane can be stored as liquid in pressurized (approximately 15 atmospheres) storage tanks
and/or at cold temperatures and vaporizes to a gas at atmospheric pressure and normal temperatures.
This makes it possible to store a large volume of propane as a liquid in a relatively
small volume; propane as a vapor occupies 270 times the volume of propane in liquid form.
This makes liquid propane an ideal fuel for transport and storage until needed. | [Characteristics]
Propane demonstrates that the carbon atoms have different characteristics in alkanes with more than two carbon atoms. The terminal carbon atoms in propane are bonded to three hydrogen atoms and one carbon atom. A carbon atom bonded to only one other carbon atom is referred to as a primary or 1° carbon. The central carbon atom in propane is bonded to two other carbon atoms and is called a secondary or 2° carbon. A hydrogen atom has the same classifi cation as the carbon atom to which it is attached. Thus the hydrogen atoms attached to the terminal carbon atoms in propane are called primary (1°) hydrogens, whereas the central atom has secondary (2°) hydrogen. The diff erence in bonds leads to diff erences in reactions and properties of diff erent isomers. For example, breaking a primary bond requires more energy than breaking a secondary bond in propane. This makes formation of the isopropyl radical CH3CHCH3• easier than the n-propyl radical, CH3CH2CH2•. Even though the formation of the isopropyl is more favorable energetically, the greater number of primary hydrogen atoms leads to approximately equal amounts of n-propyl and isopropyl radicals formed under similar reaction conditions.
Oxidation of propane can produce various oxygenated compounds under appropriate conditions, but generally alkanes are relatively unreactive compared to other organic groups. Some of the more common oxidation products include methanol (CH3OH), formaldehyde (CH2O), and acetaldehyde (C2H4O). Propane can be converted to cyclopropane by conversion to 1,3 dichloro-propane using zinc dust and sodium iodine ClCH2CH2CH2Cl--Zn. Nacl--cyclopropane. | [Definition]
ChEBI: Propane is an alkane and a gas molecular entity. It has a role as a food propellant. | [Biochem/physiol Actions]
In addition to facilitating solubilization of lipids, apolipoproteins help to maintain the structural integrity of lipoproteins, serve as ligands for lipoprotein receptors, and regulate the activity of enzymes involved in lipid metabolism. Apolipoprotein E (ApoE) plays an important role in lipid metabolism. It′s interaction with specific ApoE receptor enables uptake of chylomicron remnants by liver cells, which is an essential step during normal lipid metabolism. It also binds with the LDL receptor (Apo B/E). Defects in ApoE are a cause of hyperlipoproteinemia type III. | [Carcinogenicity]
Propane is an anesthetic
and is nonirritating to the eyes, nose, or throat. Direct
skin or mucous membrane contact with liquefied propane
causes burns and frostbite. At air concentration levels
below 1000 ppm, propane exerts very little physiological
action. At very high levels, propane has CNS depressant
and asphyxiating properties; its target organ is the central
nervous system. | [Source]
Schauer et al. (2001) measured organic compound emission rates for volatile organic
compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds
from the residential (fireplace) combustion of pine, oak, and eucalyptus. The gas-phase emission
rate of propane was 169 mg/kg of pine burned. Emission rates of propane were not measured
during the combustion of oak and eucalyptus.
California Phase II reformulated gasoline contained propane at a concentration of 100 mg/kg.
Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without catalytic
converters were 1.62 and 191 mg/km, respectively (Schauer et al., 2002). | [Environmental Fate]
Biological. In the presence of methane, Pseudomonas methanica degraded propane to 1-
propanol, propionic acid, and acetone (Leadbetter and Foster, 1959). The presence of carbon
dioxide was required for “Nocardia paraffinicum” to degrade propane to propionic acid
(MacMichael and Brown, 1987). Propane may biodegrade in two pathways. The first is the
formation of propyl hydroperoxide, which decomposes to 1-propanol followed by oxidation to
propanoic acid. The other pathway involves dehydrogenation to 1-propene, which may react with
water giving propanol (Dugan, 1972). Microorganisms can oxidize alkanes under aerobic
conditions (Singer and Finnerty, 1984). The most common degradative pathway involves the
oxidation of the terminal methyl group forming the corresponding alcohol (1-propanol). The
alcohol may undergo a series of dehydrogenation steps forming an aldehyde (propionaldehyde),
then a fatty acid (propionic acid). The fatty acid may then be metabolized by β-oxidation to form
the mineralization products carbon dioxide and water (Singer and Finnerty, 1984).
Photolytic. When synthetic air containing propane and nitrous acid was exposed to artificial
sunlight (λ = 300–450 nm), propane photooxidized to acetone with a yield of 56% (Cox et al.,
1980). The rate constants for the reaction of propane and OH radicals in the atmosphere at 298 and
300 K were 1.11 x 10-12 cm3/molecule?sec (DeMore and Bayes, 1999) and 1.3 x 10-12
cm3/molecule?sec (Hendry and Kenley, 1979). Cox et al. (1980) reported a rate constant of 1.9 x
10-12 cm3/molecule?sec for the reaction of gaseous propane with OH radicals based on a value of 8
x 10-12 cm3/molecule?sec for the reaction of ethylene with OH radicals.
Chemical/Physical. Incomplete combustion of propane in the presence of excess hydrogen
chloride resulted in a high number of different chlorinated compounds including, but not limited to
alkanes, alkenes, monoaromatics, alicyclic hydrocarbons, and polynuclear aromatic hydrocarbons.
Without hydrogen chloride, 13 nonchlorinated polynuclear aromatic hydrocarbons were formed
(Eklund et al., 1987).
Complete combustion in air yields carbon dioxide and water. | [Solubility in organics]
(vol %):
Alcohol (790 at 16.6 °C and 754 mmHg), benzene (1,452 at 21.5 °C and 757 mmHg), chloroform
(1,299 at 21.6 °C and 757 mmHg), ether (926 at 16.6 °C and 757 mmHg), and turpentine (1,587 at
17.7 °C and 757 mmHg) (Windholz et al., 1983). | [Solubility in water]
(vol %):
Alcohol (790 at 16.6 °C and 754 mmHg), benzene (1,452 at 21.5 °C and 757 mmHg), chloroform
(1,299 at 21.6 °C and 757 mmHg), ether (926 at 16.6 °C and 757 mmHg), and turpentine (1,587 at
17.7 °C and 757 mmHg) (Windholz et al., 1983). | [Purification Methods]
Purify propane by bromination of the olefinic contaminants. Propane is treated with bromine for 30minutes at 0o. Unreacted bromine is quenched, and the propane is distilled through two -78o traps and collected at -196o [Skell et al. J Am Chem Soc 108 6300 1986]. It autoignites at 450o and the flash point is -104o. It is highly FLAMMABLE and is available in metal cylinders. [Beilstein 1 H 103, 1 I 33, 1 II 71, 1 III 204, 1 IV 175.] | [Toxicity evaluation]
Some sources classify propane as a simple anesthetic, although
it can principally be classified as a simple asphyxiant.
Concentrations that are high enough to displace oxygen would
be expected to cause lightheadedness, loss of consciousness,
and possibly death from asphyxiation. |
| Safety Data | Back Directory | [Hazard Codes ]
F+ | [Risk Statements ]
R12:Extremely Flammable. | [Safety Statements ]
S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
UN 1978 2.1
| [WGK Germany ]
-
| [RTECS ]
TX2275000
| [F ]
4.5-31 | [Autoignition Temperature]
842 °F | [DOT Classification]
2.1 (Flammable gas) | [HazardClass ]
2.1 | [Safety Profile]
Central nervous system
effects at high concentrations. An
asphyxiant. Flammable gas. Highly
dangerous fire hazard when exposed to heat
or flame; can react vigorously with oxidizers.
Explosive in the form of vapor when
exposed to heat or flame. Explosive reaction
with ClO2. Violent exothermic reaction with
barium peroxide + heat. To fight fire, stop
flow of gas. When heated to decomposition
it emits acrid smoke and irritating fumes. | [Hazardous Substances Data]
74-98-6(Hazardous Substances Data) | [IDLA]
2,100 ppm [10% LEL] |
|
| Company Name: |
Bhuruka Gases Ltd
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| Tel: |
+91-7760976502 +91-8041818200 |
| Website: |
www.bhurukagases.com |
| Company Name: |
Maharashtra Gas Co
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| Tel: |
+91-8097713800 +91-9833780675 |
| Website: |
www.maharashtragas.com |
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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