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ChemicalBook--->CAS DataBase List--->6737-42-4

6737-42-4

6737-42-4 Structure

6737-42-4 Structure
IdentificationMore
[Name]

1,3-Bis(diphenylphosphino)propane
[CAS]

6737-42-4
[Synonyms]

1,3-BIS(DIPHENYLPHOSPHINE)PROPANE
1,3-BIS(DIPHENYLPHOSPHINO)PROPANE
DPPP
Propane-1,3-diylbis(diphenylphosphine)
PROPYLENEBIS(DIPHENYLPHOSPHINE)
TRIMETHYLENEBIS(DIPHENYLPHOSPHINE)
[3-(Diphenylphosphino)propyl](diphenyl)phosphine
1,3-Propanediylbis(diphenylphosphine)
Bis(1,3-diphenylphosphino)propane
Phosphine, 1,3-propanediylbis[diphenyl-
Phosphine, trimethylenebis(diphenyl-
1,3-bis(diphenyphosphino)propane
1,3-bis(diphenyphosphino)propane(dppp)
1,3-Bis(Diphenlphosphino)Propane
1,3-Bis(diphenylphosphino)propane,98%DPPP
DPPP/ 1,3-BIS(DIPHENYLPHOSPHINE)PROPANE
DPPP/1,3-BIS-(DIPHENYLPHOSPHINO)PROPANE
PH2PCH2 CH2CH2PPH2
1,3-propanediylbis[diphenyl-phosphin
1,3-BIS(DIPHENYPHOSPHINO)
[EINECS(EC#)]

229-791-2
[Molecular Formula]

C27H26P2
[MDL Number]

MFCD00003050
[Molecular Weight]

412.44
[MOL File]

6737-42-4.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

63-65 °C (lit.)
[Boiling point ]

529.7±33.0 °C(Predicted)
[Fp ]

235°C
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Granules or Powder
[color ]

White to light yellow-beige
[Water Solubility ]

insoluble
[Sensitive ]

Air Sensitive
[Detection Methods]

HPLC
[BRN ]

2821785
[InChI]

InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
[InChIKey]

LVEYOSJUKRVCCF-UHFFFAOYSA-N
[SMILES]

P(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1
[CAS DataBase Reference]

6737-42-4(CAS DataBase Reference)
[NIST Chemistry Reference]

1,3-Bis(diphenylphosphino)propane(6737-42-4)
[EPA Substance Registry System]

6737-42-4(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[F ]

10-23
[TSCA ]

Yes
[HS Code ]

29310095
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Sodium hydroxide-->Hydrochloric acid-->Ethyl acetate-->Tetrahydrofuran-->Dichloromethane-->Sodium-->Magnesium sulfate-->Acetone-->n-Butyllithium-->Triphenylphosphine-->Lithium-->Diphenylphosphine-->1,3-Dibromopropane-->1,3-Dichloropropane-->3-(diphenylphosphoryl)propyl(diphenyl)phosphine oxide-->Diphenylphosphine oxide-->1-Bromo-3-chloropropane
[Preparation Products]

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride-->3-DODECYLTHIOPHENE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1,3-Bis(diphenylphosphino)propane(6737-42-4).msds
Hazard InformationBack Directory
[Description]

1,3-Bis(diphenylphosphino)propane is a ligand for metal-catalyzed substitution reactions of aryl and vinyl triflates, halides, and carbonates; carbonylation reactions; Grignard coupling; diene alkylation; macrocycle synthesis.
[Chemical Properties]

white to light yellow crystal powde
[Uses]

suzuki reaction
[reaction suitability]

reagent type: ligand
reaction type: C-C Bond Formation
reagent type: ligand
reaction type: Carbonylations
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
Spectrum DetailBack Directory
[Spectrum Detail]

1,3-Bis(diphenylphosphino)propane(6737-42-4)MS
1,3-Bis(diphenylphosphino)propane(6737-42-4)1HNMR
1,3-Bis(diphenylphosphino)propane(6737-42-4)31PNMR
1,3-Bis(diphenylphosphino)propane(6737-42-4)IR1
1,3-Bis(diphenylphosphino)propane(6737-42-4)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1,3-Bis(diphenylphosphino)propane, 97%(6737-42-4)
[Alfa Aesar]

1,3-Bis(diphenylphosphino)propane, 97%(6737-42-4)
[Sigma Aldrich]

6737-42-4(sigmaaldrich)
[TCI AMERICA]

1,3-Bis(diphenylphosphino)propane,>98.0%(GC)(T)(6737-42-4)
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