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ChemicalBook--->CAS DataBase List--->50824-05-0

50824-05-0

50824-05-0 Structure

50824-05-0 Structure
IdentificationMore
[Name]

4-(Trifluoromethoxy)benzyl bromide
[CAS]

50824-05-0
[Synonyms]

1-(BROMOMETHYL)-4-(TRIFLUOROMETHOXY)BENZENE
4-(TRIFLUOROMETHOXY)BENZYL BROMIDE
ALPHA-BROMO-4-(TRIFLUOROMETHOXY)TOLUENE
TIMTEC-BB SBB006578
P-TritluromethoxybenzylBromide
4-(Trifluoromethoxy)benzyl
4-(Trifluoromethoxy)benzyl bromide 97%
4-(Trifluoromethoxy)benzylbromide97%
[Molecular Formula]

C8H6BrF3O
[MDL Number]

MFCD00061238
[Molecular Weight]

255.03
[MOL File]

50824-05-0.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless to light yellow liqui
[Melting point ]

22-24°C
[Boiling point ]

82-84 °C10 mm Hg(lit.)
[density ]

1.594 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.48(lit.)
[Fp ]

202 °F
[storage temp. ]

Refrigerated.
[solubility ]

soluble in Chloroform, Methanol
[form ]

Liquid or Low Melting Solid
[color ]

Clear faintly yellow
[Specific Gravity]

1.594
[Sensitive ]

Lachrymatory
[BRN ]

2521451
[InChI]

InChI=1S/C8H6BrF3O/c9-5-6-1-3-7(4-2-6)13-8(10,11)12/h1-4H,5H2
[InChIKey]

JDNPUJCKXLOHOW-UHFFFAOYSA-N
[SMILES]

C1(CBr)=CC=C(OC(F)(F)F)C=C1
[CAS DataBase Reference]

50824-05-0(CAS DataBase Reference)
Questions And AnswerBack Directory
[Uses]

4-Trifluoromethoxybenzyl Bromide is a useful synthetic intermediate. It is used to prepare (nitro)[(trifluoromethoxy)benzyloxy]dihydroimidazo[2,1-b][1,3]oxazines with antitubercular activities. It is also used to synthesize tetrahydronaphthalenols with anti-allergic activities.
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3265 8/PG 2
[WGK Germany ]

3
[Hazard Note ]

Corrosive/Lachrymatory
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29093090
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

4-(Trifluoromethyl)phenylacetic acid-->4-(Trifluoromethoxy)benzoic acid
Hazard InformationBack Directory
[Chemical Properties]

Colorless to light yellow liqui
[General Description]

Polymerizations of 4-(trifluoromethoxy)benzyl bromide, via Friedel-Crafts polymerization using aluminum chloride as a catalyst has been reported.
Spectrum DetailBack Directory
[Spectrum Detail]

4-(Trifluoromethoxy)benzyl bromide(50824-05-0)MS
4-(Trifluoromethoxy)benzyl bromide(50824-05-0)1HNMR
4-(Trifluoromethoxy)benzyl bromide(50824-05-0)13CNMR
4-(Trifluoromethoxy)benzyl bromide(50824-05-0)IR1
4-(Trifluoromethoxy)benzyl bromide(50824-05-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-(Trifluoromethoxy)benzyl bromide, 98%(50824-05-0)
[Alfa Aesar]

4-(Trifluoromethoxy)benzyl bromide, 97%(50824-05-0)
[Sigma Aldrich]

50824-05-0(sigmaaldrich)
[TCI AMERICA]

4-(Trifluoromethoxy)benzyl Bromide,>97.0%(GC)(50824-05-0)
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