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ChemicalBook--->CAS DataBase List--->4930-98-7

4930-98-7

4930-98-7 Structure

4930-98-7 Structure
IdentificationMore
[Name]

2-Hydrazinopyridine
[CAS]

4930-98-7
[Synonyms]

2-HYDRAZINOPYRIDINE
2-PYRIDYLHYDRAZINE
PYRIDIN-2-YL-HYDRAZINE
(2E)-2(1H)-Pyridinone hydrazone
2(1H)-Pyridinone, hydrazone
2(1h)-pyridinone,hydrazone
Hydrazine, 2-pyridinyl-
Pyridine, 2-hydrazino-
Hydrazinopyridine
2-hydrazinylpyridine
2-HYDRAZINOPYRIDINE 97+%
2-HYDRAZINOPYRIDINE PYRIDIN-2-YL-HYDRAZINE
2-Pyridinylhydrazine
[EINECS(EC#)]

225-566-8
[Molecular Formula]

C5H7N3
[MDL Number]

MFCD00006249
[Molecular Weight]

109.13
[MOL File]

4930-98-7.mol
Chemical PropertiesBack Directory
[Appearance]

White to light beige low melting solid
[Melting point ]

41-44 °C (lit.)
[Boiling point ]

90-92 °C/1 mmHg (lit.)
[density ]

1.1118 (rough estimate)
[refractive index ]

1.5340 (estimate)
[Fp ]

>230 °F
[storage temp. ]

2-8°C
[solubility ]

soluble in Methanol
[form ]

crystalline
[pka]

9.72±0.70(Predicted)
[color ]

deep red
[Detection Methods]

GC
[BRN ]

109984
[InChIKey]

NWELCUKYUCBVKK-UHFFFAOYSA-N
[CAS DataBase Reference]

4930-98-7(CAS DataBase Reference)
[NIST Chemistry Reference]

2-Hydrazinopyridine(4930-98-7)
[Storage Precautions]

Store under nitrogen
[EPA Substance Registry System]

4930-98-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[F ]

3-10-34
[HS Code ]

29339900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Hydrochloric acid-->Dichloromethane-->Hydrazinium hydroxide solution-->4-Bromobenzaldehyde-->2-Bromopyridine-->(E)-2-Pyridinecarbaldehyde (2-pyridyl)hydrazone-->2-Pyridinecarboxaldehyde, 2-phenylhydrazone, [C(E)]--->(Z)-2-pyridinecarbaldehyde (2-pyridyl)hydrazone-->2-Chloropyridine-->N-Nitro-2-pyridinamine-->PYRIDINE-2-SULFONIC ACID-->Hydrazine hydrate-->Phenylhydrazine
[Preparation Products]

5-METHYL-2-PYRIDIN-2-YL-2H-PYRAZOL-3-YLAMINE-->1-pyridin-2-yl-5-(trifluoromethyl)-1H-pyrazole-4-carboxylic acid-->ETHYL 5-AMINO-1-PYRIDIN-2-YL-1H-PYRAZOLE-4-CARBOXYLATE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Pyridylhydrazine(4930-98-7).msds
Hazard InformationBack Directory
[Chemical Properties]

White to light beige low melting solid
[Synthesis Reference(s)]

Journal of Medicinal Chemistry, 28, p. 1394, 1985 DOI: 10.1021/jm00148a004
[Purification Methods]

Purify it by distillation under a vacuum and by recrystallisation from Et2O/hexane. [Kauffmann et al. Justus Liebigs Ann Chem 656 103 1962, Potts & Burton J Org Chem 31 251 1966.] The mono-hydrochloride has m 183o(dec) from aqueous HCl, and the di-hydrochloride has m 214-215o. [Beilstein 22 II 487, 22 III/IV 7025, 22/14 V 486.]
Spectrum DetailBack Directory
[Spectrum Detail]

2-Hydrazinopyridine(4930-98-7)MS
2-Hydrazinopyridine(4930-98-7)1HNMR
2-Hydrazinopyridine(4930-98-7)13CNMR
2-Hydrazinopyridine(4930-98-7)IR1
2-Hydrazinopyridine(4930-98-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Hydrazinopyridine 98%(4930-98-7)
[Sigma Aldrich]

4930-98-7(sigmaaldrich)
[TCI AMERICA]

2-Hydrazinopyridine,>98.0%(GC)(T)(4930-98-7)
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