Identification | More | [Name]
Methyl 2-chloroacetoacetate | [CAS]
4755-81-1 | [Synonyms]
2-chloro-3-oxobutanoic acid, methyl ester 2-CHLOROACETOACETIC ACID METHYL ESTER METHYL 2-CHLORO-3-OXOBUTANATE METHYL 2-CHLOROACETOACETATE 2-chloro-3-oxo-butanoicacimethylester Methyl 2-chloro-3-oxobutanoate Chloroacetoaceticacidmethylester Butanoic acid, 2-chloro-3-oxo-, methyl ester 2-chloro-3-oxo-butyric acid methyl ester 2-Acetyl-2-chloroacetic acid methyl ester | [EINECS(EC#)]
225-286-6 | [Molecular Formula]
C5H7ClO3 | [MDL Number]
MFCD00008757 | [Molecular Weight]
150.56 | [MOL File]
4755-81-1.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . R36/37/38:Irritating to eyes, respiratory system and skin . R22:Harmful if swallowed. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S27:Take off immediately all contaminated clothing . S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
UN 2810 6.1/PG 3
| [WGK Germany ]
3
| [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29183000 |
Hazard Information | Back Directory | [Chemical Properties]
CLEAR YELLOW LIQUID | [Uses]
Methyl 2-chloroacetoacetate was used in one-pot synthesis of 2-arylimidazole-4-carboxylic acids. It was also used in synthesis of 3,5-disubstituted 1,2,4-triazoles. | [Synthesis Reference(s)]
Synthesis, p. 188, 1987 DOI: 10.1055/s-1987-27886 |
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