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ChemicalBook--->CAS DataBase List--->3958-60-9

3958-60-9

3958-60-9 Structure

3958-60-9 Structure
IdentificationMore
[Name]

2-Nitrobenzyl bromide
[CAS]

3958-60-9
[Synonyms]

2-(BROMOMETHYL)NITROBENZENE
2-NITROBENZYL BROMIDE
A-BROMO-O-NITROTOLUENE
ALPHA-BROMO-2-NITROTOLUENE
ALPHA-BROMO-O-NITROTOLUENE
NITROBENZYL-2 BROMIDE
O-NITROBENZYL BROMIDE
1-(Bromomethyl)-2-nitrobenzene
1-Bromomethyl-2-nitro-benzene
Benzene, 1-(bromomethyl)-2-nitro-
-Bromo-2-mitrotoluene
o-Nitrobenaylbromide
α-Bromo-2-nitrotoluene
a-Bromo-2-nitrotoluene
2-Nitrobenzyl bromide, 98+%
2-Nitrobenzyl
à-bromo-2-nitrotoluene
2-Benzyl bromide
1-Nitro-2-(bromomethyl)benzene
[EINECS(EC#)]

223-558-9
[Molecular Formula]

C7H6BrNO2
[MDL Number]

MFCD00007184
[Molecular Weight]

216.03
[MOL File]

3958-60-9.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

44-46 °C (lit.)
[Boiling point ]

265.51°C (rough estimate)
[density ]

1.6841 (rough estimate)
[refractive index ]

1.6120 (estimate)
[Fp ]

>230 °F
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly)
[form ]

Crystals or Crystalline Powder
[color ]

Yellow to light brown
[Water Solubility ]

insoluble
[Detection Methods]

GC
[BRN ]

638991
[Stability:]

Hygroscopic
[CAS DataBase Reference]

3958-60-9(CAS DataBase Reference)
[NIST Chemistry Reference]

2-Nitrobenzyl bromide(3958-60-9)
[Storage Precautions]

Moisture sensitive
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

3
[F ]

4.8-19-21
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29049085
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Carbon tetrachloride-->2,2'-Azobis(2-methylpropionitrile)-->2-Nitrotoluene-->1-(Methoxymethyl)-2-nitrobenzene
[Preparation Products]

2-NITRO-ALPHA-TOLUENESULFONYL CHLORIDE-->2,3,4,5-TETRAHYDRO-1H-BENZO[E][1,4]DIAZEPINE-->Phenyl carbamate-->2,2'-DINITRODIBENZYL
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Nitrobenzyl bromide(3958-60-9).msds
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powde
[Uses]

2-Nitrobenzyl bromide is used in the preparation of S-2-nitrobenzyl-cysteine by reaction with L-cysteine. It is also used for the introduction of the 2-nitrobenzyl protecting group in organic synthesis. It plays an important role in the production of expectorant agent. Further, it is employed for caging unprotected cysteine-containing or thiophosphorylated peptides in aqueous solution. In addition to this, it is used in the preparation of (R)- and (S)-3-amino-3,4-dihydro-1H-quinolin-2-one.
[Biochem/physiol Actions]

2-Nitrobenzyl bromide reacts with L-cysteine to form S-2-nitrobenzyl-cysteine which was used for modification of ultra-low-gelling-temperature (ULGT) agarose.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Nitrobenzyl bromide(3958-60-9)MS
2-Nitrobenzyl bromide(3958-60-9)1HNMR
2-Nitrobenzyl bromide(3958-60-9)13CNMR
2-Nitrobenzyl bromide(3958-60-9)IR1
2-Nitrobenzyl bromide(3958-60-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Nitrobenzyl bromide, 97%(3958-60-9)
[Alfa Aesar]

2-Nitrobenzyl bromide, 98+%(3958-60-9)
[Sigma Aldrich]

3958-60-9(sigmaaldrich)
[TCI AMERICA]

2-Nitrobenzyl Bromide,>98.0%(GC)(3958-60-9)
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