| Identification | More | [Name]
2-Bromo-5-methoxytoluene | [CAS]
27060-75-9 | [Synonyms]
1-BROMO-4-METHOXY-2-METHYLBENZENE
2-BROMO-5-METHOXYTOLUENE
3-Methyl-4-bromoanisole
4-BROMO-3-METHYLANISOLE
2-Bromo-4-methoxy-1-methylbenzene
Benzene, 1-bromo-4-methoxy-2-methyl-
2-Bromo-5-methoxytoluene 98%
2-Bromo-5-methoxytoluene (4-bromo-3-methylanisole)
4-BROMO-3-METHYLANISOLE 95%
1-Methoxy-3-methyl-4-bromobenzene
2-Methyl-4-methoxyphenyl bromide
Methyl(3-methyl-4-bromophenyl) ether | [Molecular Formula]
C8H9BrO | [MDL Number]
MFCD00060687 | [Molecular Weight]
201.06 | [MOL File]
27060-75-9.mol |
| Chemical Properties | Back Directory | [Appearance]
colorless to light yellow liquid | [Melting point ]
16.5 °C | [Boiling point ]
111-112 °C15 mm Hg(lit.)
| [density ]
1.424 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.561(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
water: soluble (Partially miscible)(lit.) | [form ]
Liquid | [color ]
Clear colorless to slightly yellow | [Specific Gravity]
1.424 | [Water Solubility ]
water: soluble (Partially miscible)(lit.) | [FreezingPoint ]
12.0 to 16.0 ℃ | [BRN ]
1933865 | [CAS DataBase Reference]
27060-75-9(CAS DataBase Reference) | [NIST Chemistry Reference]
2-Bromo-5-methoxytoluene(27060-75-9) | [EPA Substance Registry System]
27060-75-9(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [TSCA ]
Yes | [HS Code ]
29093090 |
| Hazard Information | Back Directory | [Chemical Properties]
colorless to light yellow liquid | [Uses]
2-bromo-5-methoxytoluene could be used to syntheis 4-bromo-3-(bromomethyl)anisole. In specifically, to a CCl4 solution (125 mL) of 2-bromo-5-methoxytoluene (0.050 mol) and NBS (0.055 mol) was added AIBN (0.001 mol), and the mixture was stirred at 80 °C for 18 h. The mixture was diluted with hexane before filtration through a Celite pad. Evaporation of the solvent and washing the residue with ethyl acetate gave 4-bromo-3-(bromomethyl)anisole.
|
|
|