Identification | More | [Name]
Borane-triethylamine complex | [CAS]
1722-26-5 | [Synonyms]
BORANE-TRIETHYLAMINE BORANE-TRIETHYLAMINE COMPLEX TEAB TRIETHYLAMINE BORANE TRIETHYLAMINE BORANE COMPLEX (C2H5)3NBH3 Borane, complex with triethylamine(1:1) Boron, (N,N-diethylethanamine)trihydro-, (T-4)- n-diethylethanamine)trihydro-((beta-4)-boro N-Triethyl borazane Triethylamine base borane adduct Triethylamine compound with borane (1:1) Triethylamine, compd. with borane (1:1) Triethylamine, complex with borane (1:1) Triethylamine-borane 1 to 1 complex triethylamineborane,teab Borane-triethylamine complex, 95+%, packaged under Argon in resealable ChemSealTM bottles Borane-triethylamine complex, 96%, packaged under Argon in resealable ChemSeal^t bottles Borane-triethylamine complex, 95+%, packaged under Argon in resealable ChemSeal^t bottles | [EINECS(EC#)]
217-022-3 | [Molecular Formula]
C6H18BN | [MDL Number]
MFCD00012423 | [Molecular Weight]
115.02 | [MOL File]
1722-26-5.mol |
Safety Data | Back Directory | [Hazard Codes ]
F,C | [Risk Statements ]
R11:Highly Flammable. R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S33:Take precautionary measures against static discharges . S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
UN 2924 3/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29299090 |
Hazard Information | Back Directory | [Chemical Properties]
clear colourless liquid | [Uses]
As a reducing agent and in hydroboration reactionsBorane-triethylamine complex is used for ethanolysis of amine-borane adducts. It is also used in photochemical hydroboration and oxidation of single-walled carbon nanotubes. Further, it acts as a reactant for the synthesis of silylboranate and N-heterocyclic carbene borane complexes through Lewis base exchange with amine-boranes. It plays an important role in the generation of boron carbide nitride films through low-pressure chemical vapor deposition. | [Purification Methods]
Distil it in a vacuum using a 60cm glass helices-packed column. [Brown et al. J Am Chem Soc 64 325 1942, Ashby & Foster J Am Chem Soc 84 3407 1962, Matsuura & Tolcura Tetrahedron Lett 4703 1968, Beilstein 4 IV 329.] |
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