| Identification | More | [Name]
Borane-pyridine complex | [CAS]
110-51-0 | [Synonyms]
BORANE-PYRIDINE
BORANE-PYRIDINE COMPLEX
BORON HYDRIDE PYRIDINE
PYRIDINE BORANE
pyridine-borane (1:1)
PYRIDINE BORANE COMPLEX
(beta-4)-boro
(t-4)-boro
borane-pyridine(1:1)
Boron, trihydro(pyridine)-, (T-4)-
Pyridine, compd. with borane (1:1)
pyridine,compd.withbh3(1:1)
pyridine,compd.withborane(1:1)
Pyridine,compound with borane(1:1)
pyridineborane,pyb
pyridineborane,pyb,in
pyridineborane,pyb,inpyridine
pyridinecompd.withboronhydride
trihydro(pyridine)boron
Pyridine borane, in pyridine | [EINECS(EC#)]
203-773-4 | [Molecular Formula]
C5H8BN | [MDL Number]
MFCD00012435 | [Molecular Weight]
92.93 | [MOL File]
110-51-0.mol |
| Chemical Properties | Back Directory | [Appearance]
clear to slightly hazy colorless to amber liquid | [Melting point ]
10-11 °C(lit.) | [Boiling point ]
102 °C (0.37505 mmHg) | [density ]
0.929 g/mL at 20 °C
| [refractive index ]
n20/D 1.532(lit.)
| [Fp ]
70 °F
| [storage temp. ]
2-8°C
| [solubility ]
very sol methanol, THF, toluene, dichloromethane; sol water, diethyl ether; insol hexane. | [form ]
Liquid | [color ]
Clear to slightly hazy colorless to amber | [Specific Gravity]
0.92 | [Water Solubility ]
reacts slowly | [Sensitive ]
Air & Moisture Sensitive | [BRN ]
3674913 | [Exposure limits]
ACGIH: TWA 1 ppm
OSHA: TWA 5 ppm(15 mg/m3)
NIOSH: IDLH 1000 ppm; TWA 5 ppm(15 mg/m3) | [InChIKey]
RJFWUOJTSKNRHN-UHFFFAOYSA-N | [CAS DataBase Reference]
110-51-0(CAS DataBase Reference) | [NIST Chemistry Reference]
Boron, trihydro(pyridine)-(110-51-0) | [EPA Substance Registry System]
110-51-0(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
F,T,T+ | [Risk Statements ]
R10:Flammable.
R15:Contact with water liberates extremely flammable gases.
R20:Harmful by inhalation.
R24/25:Toxic in contact with skin and if swallowed .
R36/38:Irritating to eyes and skin .
R44:Risk of explosion if heated under confinement.
R36/37/38:Irritating to eyes, respiratory system and skin .
R26:Very Toxic by inhalation. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
UN 1992 3/PG 2
| [WGK Germany ]
2
| [RTECS ]
US3675000
| [F ]
1-10 | [TSCA ]
Yes | [HazardClass ]
4.3 | [PackingGroup ]
II | [HS Code ]
29333990 | [Toxicity]
guinea pig,LD50,intraperitoneal,54mg/kg (54mg/kg),"Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New York, John Wiley & Sons, Inc., 1964Vol. -, Pg. 693, 1964. |
| Hazard Information | Back Directory | [Description]
Borane-pyridine complex is a mild reducing agent with greater hydrolytic stability than NaBH4 in protic solvents and higher
solubility in aprotic organic solvents;
in solution with a weak organic acid or complexed with
Lewis acids it is useful for reductive aminations, reduction of carbonyls, heterocycles,
tosylhydrazones, and oximes;
in strong acid it converts aldehydes to symmetrical ethers; weak
hydroborating agent. | [Chemical Properties]
clear to slightly hazy colorless to amber liquid | [Uses]
Borane-pyridine complex is used for synthesis of α-alkyl-β-hydroxy esters and preparation of Igs conjugated with viral peptide epitopes. It is used as reducing agent for high performance liquid chromatography analysis of oligosaccharides. It is also used as modifier in decant oil affecting its carbonization to mesophase pitch. | [reaction suitability]
reagent type: reductant | [storage]
hydrolytically stable in neutral aqueous solution. Excess
reagent may be decomposed with dilute HCl. Use in a fume hood. |
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