| Identification | More | [Name]
Borane-trimethylamine complex | [CAS]
75-22-9 | [Synonyms]
BORANE-TRIMETHYLAMINE
BORANE-TRIMETHYLAMINE COMPLEX
BORON HYDRIDE TRIMETHYLAMINE
TMAB
TRIMETHYLAMINE BORANE
Trimethylamine borane (1:1)
(CH3)3NBH3
Borane, compd. with N,N-dimethylmethanamine (1:1)
Borane, compd. with trimethylamine (1:1)
borane,compd.withn,n-dimethylmethanamine(1:1)
borane,compd.withtrimethylamine(1:1)
Methanamine, N,N-dimethyl-, compd. with borane (1:1)
n,n-dimethyl-methanamincompd.withborane(1:1)
n-dimethylmethanamine)trihydro-((beta-4)-boro
n-dimethylmethanamine)trihydro-((t-4)-boro
Trimethylamine, compd. with borane (1:1)
trimethylamine,compd.withborane(1:1)
trimethylamine-borane(3)complex(1:1)
Trimethylamine-borane(3)-complex(1:1)
trimethylamineborane,tmab | [EINECS(EC#)]
200-850-4 | [Molecular Formula]
C3H12BN | [MDL Number]
MFCD00012420 | [Molecular Weight]
72.95 | [MOL File]
75-22-9.mol |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xn,Xi | [Risk Statements ]
R11:Highly Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S14:Keep away from ... (incompatible materials to be indicated by the manufacturer) .
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S33:Take precautionary measures against static discharges . | [RIDADR ]
UN 1325 4.1/PG 2
| [WGK Germany ]
3
| [RTECS ]
PA0525000
| [F ]
10-21 | [TSCA ]
Yes | [HazardClass ]
4.1 | [PackingGroup ]
II | [HS Code ]
29420000 |
| Hazard Information | Back Directory | [Chemical Properties]
white crystalline powder | [Uses]
Reducing agent for the preparation of plate-type palladium-zinc oxide catalys, reagent for chemical vapor generation and spectrometry determination of elements using amineboranes and cyanotrihydroborate(III) reagents. Catalyst for regioselective reductive opening of benzylidene acetal glycosides and polarity reversal. | [Purification Methods]
It is sublimed using equipment described in Burg and Schlesinger [J Am Chem Soc 59 780 1937I]. Its vapour pressure is 86mm at 100o. It forms colourless hexagonal crystals varying from needles to short lumps, which are slightly soluble in H2O (1.48% at 30o), EtOH (1%), hexane (0.74%) but very soluble in Et2O, *C6H6 and AcOH. It is stable at 125o. [Burg & Schlesinger J Am Chem Soc 59 780 1937, Brown et al. J Am Chem Soc 104 325 1942, Beilstein 4 IV 140.] |
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