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ChemicalBook--->CAS DataBase List--->142-92-7

142-92-7

142-92-7 Structure

142-92-7 Structure
IdentificationMore
[Name]

Hexyl acetate
[CAS]

142-92-7
[Synonyms]

1-ACETOXY-HEXANE
2-HEXANOL ACETATE
ACETATE C-6
ACETIC ACID HEXYL ESTER
ACETIC ACID, HEXYL ESTERS MIXTURE
ACETIC ACID N-HEXYL ESTER
C2
CAPROYL ACETATE
CAPRYL ACETATE
FEMA 2565
HEXANYL ACETATE
HEXYL ACETATE
HEXYL ETHANOATE
N-HEXYL ACETATE
1-Hexyl acetate
1-hexylacetate
acetated’hexyle
ethanoicacid,hexylester
Ethanoicacidhexylester
Hexyl alcohol, acetate
[EINECS(EC#)]

205-572-7
[Molecular Formula]

C8H16O2
[MDL Number]

MFCD00009524
[Molecular Weight]

144.21
[MOL File]

142-92-7.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to pale yellowish liquid
[Melting point ]

-80 °C (lit.)
[Boiling point ]

168-170 °C (lit.)
[density ]

0.87 g/mL at 25 °C(lit.)
[vapor pressure ]

5 hPa (20 °C)
[FEMA ]

2565
[refractive index ]

n20/D 1.409(lit.)
[Fp ]

99 °F
[storage temp. ]

2-8°C
[solubility ]

0.4g/l
[form ]

Liquid
[color ]

Clear colorless to pale yellow
[Odor]

at 10.00 % in dipropylene glycol. fruity green apple banana sweet
[Odor Threshold]

0.0018ppm
[Odor Type]

fruity
[Water Solubility ]

immiscible
[JECFA Number]

128
[BRN ]

1747138
[Dielectric constant]

4.4199999999999999
[LogP]

3.3 at 30℃
[CAS DataBase Reference]

142-92-7(CAS DataBase Reference)
[NIST Chemistry Reference]

Hexyl ethanoate(142-92-7)
[EPA Substance Registry System]

142-92-7(EPA Substance)
Safety DataBack Directory
[Risk Statements ]

R10:Flammable.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 3272 3/PG 3
[WGK Germany ]

1
[RTECS ]

AI0875000
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29153990
[Hazardous Substances Data]

142-92-7(Hazardous Substances Data)
[Toxicity]

LD50 orally in Rabbit: 36100 mg/kg LD50 dermal Rabbit > 5000 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Potassium carbonate-->1-Hexanol
[Preparation Products]

Procaine penicillin G
Hazard InformationBack Directory
[General Description]

A colorless liquid with a mild sweet odor. Flash point 113°F. A moderate fire risk. Inhalation may cause adverse effects. Insoluble in water and very soluble in alcohols and ethers. When heated to high temperatures emits acrid smoke and fumes. Used as a solvent and as a propellant in aerosols.
[Reactivity Profile]

HEXYL ACETATE(142-92-7) is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
[Air & Water Reactions]

Highly flammable. Insoluble in water.
[Hazard]

Combustible.
[Health Hazard]

May be harmful by inhalation, ingestion, or skin absorption. May cause irritation.
[Fire Hazard]

Special Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flash back. Container explosion may occur under fire conditions. Forms explosive mixtures in air.
[Description]

Hexyl acetate has a pleasant fruity odor and bittersweet taste suggestive of pear. May be synthesized from n-hexyl alcohol and excess acetic anhydride at the boil or with an excess of acetic acid in the presence of concentrated sulfuric acid.
[Chemical Properties]

clear colorless to pale yellowish liquid
[Chemical Properties]

Hexyl acetate has a pleasant fruity, apple, cherry, pear, floral odor and bittersweet taste suggestive of pear.
[Chemical Properties]

Hexyl Acetate is a liquid with a sweet-fruity, pear-like odor. It is present in a number of fruits and alcoholic beverages and is used in fruit aroma compositions.
[Occurrence]

Reported found in fruital aromas (e.g., Fragaria vesca) and essential oils. Also reported found in apple, apricot, banana, sweet cherry, citrus peel oils and juices, blueberry, black currants, guava, grapes, melon, peach, pear, raspberry, blackberry, strawberry, peas, sauerkraut, rye bread, cheeses, roasted beef, beer, rum, cognac, whiskies, cider, sherry, grape wines, coffee, tea, soybean, olive, passion fruit, beans, starfruit, mango, cauliflower, pear and apple brandy, quince, origanum, lovage leaf, corn oil, mangosteen (Garcia mangostana), Bourbon vanilla, clary sage, nectarine, naranjilla fruit, Chinese quince and chamomile oil.
[Uses]

Hexyl acetate was used to study the activity of diamondback moth sex pheromone and larval frass volatiles, as well as green leaf volatiles from cabbage, on the natural enemies of the pest.
[Uses]

Hexyl Acetate is a flavouring agent due to its fruity odor and it is naturally present in many fruits and alcoholic beverages.
[Uses]

n-Hexyl acetate exhibits antimicrobial activity and can be used to improve the safety of minimally processed fruits. It is a fruity smelling fluid used as flavoring agent or in perfumes. It is a green leaf volatile from cabbage Brassica oleracea var. capitata L. It is used as plasticizers.
[Definition]

ChEBI: The acetate ester of hexan-1-ol.
[Preparation]

From n-hexyl alcohol and excess acetic anhydride at the boil or with an excess of acetic acid in the presence of concentrated sulfuric acid
[Production Methods]

n-Hexyl acetate is prepared from n-hexyl alcohol and excess acetic anhydride or with an excess of acetic acid and concentrated sulfuric acid . Its is also prepared from primary and sec-hexyl alcohols .
It is produced by Aldrich Chemical Corp., Milwaukee, WI, and Penta Manufacturing Co., Fairfield, NJ .
[Aroma threshold values]

Detection: 2 to 480 ppb
[Taste threshold values]

Taste characteristics at 15 ppm: fruity, green, fresh, sweet, banana peel, apple and pear.
[Synthesis Reference(s)]

Tetrahedron Letters, 18, p. 3263, 1977 DOI: 10.1016/S0040-4039(01)83213-5
[Flammability and Explosibility]

Flammable
[Biochem/physiol Actions]

Hexyl acetate has antimicrobial activity and can be used to improve the safety of minimally processed fruits. Hexyl acetate is a fruity smelling fluid used as flavoring agent or in perfumes. Hexyl acetate is a green leaf volatile from cabbage Brassica oleracea var. capitata L.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Hexyl acetate(142-92-7).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Hexyl acetate(142-92-7)MS
Hexyl acetate(142-92-7)1HNMR
Hexyl acetate(142-92-7)13CNMR
Hexyl acetate(142-92-7)IR1
Hexyl acetate(142-92-7)IR2
Hexyl acetate(142-92-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Hexyl acetate, 99%(142-92-7)
[Alfa Aesar]

n-Hexyl acetate, 99%(142-92-7)
[Sigma Aldrich]

142-92-7(sigmaaldrich)
[TCI AMERICA]

Hexyl Acetate,>99.0%(GC)(142-92-7)
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