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ChemicalBook--->CAS DataBase List--->13453-80-0

13453-80-0

13453-80-0 Structure

13453-80-0 Structure
IdentificationMore
[Name]

Lithium dihydrogen phosphate
[CAS]

13453-80-0
[Synonyms]

LITHIUM DIHYDROGEN PHOSPHATE
LITHIUM PHOSPHATE MONOBASIC
PHOSPHORIC ACID MONOLITHIUM SALT
lithiumdihydrogenorthophosphate
lithiumdihydrophosphate
lithiumphosphate(lih2po4)
monolithiumphosphate
LITHIUM DIHYDROGENPHOSPHATE 99.99+%
Lithiumdihydrogenphosphate,97%
Lithium dihydrogen phosphate, Phosphoric acid mono
Phosphoric acid dihydrogen lithium salt
[EINECS(EC#)]

236-633-6
[Molecular Formula]

H2LiO4P
[MDL Number]

MFCD00016188
[Molecular Weight]

103.93
[MOL File]

13453-80-0.mol
Chemical PropertiesBack Directory
[Appearance]

White crystalline powder
[Melting point ]

>100°C
[density ]

2.5 g/mL at 25 °C(lit.)
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Powder
[color ]

white
[Specific Gravity]

2.461
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[Water Solubility ]

Slightly soluble in water.
[InChI]

InChI=1S/Li.H3O4P.H/c;1-5(2,3)4;/h;(H3,1,2,3,4);
[InChIKey]

AZOORWHXDYIBGH-UHFFFAOYSA-N
[SMILES]

P(O)(O)(O)=O.[LiH]
[CAS DataBase Reference]

13453-80-0(CAS DataBase Reference)
[EPA Substance Registry System]

13453-80-0(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[RTECS ]

TC6593950
[TSCA ]

Yes
[HS Code ]

28352990
[Toxicity]

mouse,LD50,oral,910mg/kg (910mg/kg),"Aktual'nye Problemy Gigieny Truda. Current Problems of Labor Hygiene," Tarasenko, N.Y., ed. Moscow, Pervyi Moskovskii Meditsinskii Inst., 1978Vol. -, Pg. 28, 1978.
Hazard InformationBack Directory
[Description]

Lithium dihydrogen phosphate, also known as LDP, is a White crystalline powder with the formula LiH2PO4. It is soluble in water. LiH2PO4 is usually prepared by a stoichiometric reaction of Li2СO3 and 85% orthophosphoric acid[1]. It is often used as a raw material for the preparation of cathode materials for lithium batteries or as phosphate in chemical reactions.
[Chemical Properties]

White crystalline powder
[Uses]

Lithium Dihydrogen Phosphate is used in preparation method of lithium hydroxide from lithium-containing low-magnesium brine in lithium phosphate manner.
[Uses]

Precursor for LiMX2O7 (M = Fe, V; x =P, As) cathode materials.1
[General Description]

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[Solubility in water]

At 0°C, the solubility of lithium dihydrogen phosphate in water is about 55.8wt % (126.2 g of LiH2PO4 /100 g of water)[1]. At 22°C, the solubility of lithium dihydrogen phosphate corresponds to ~ 153.8 g of LiH2PO4/100 g of water. At 25°C, it doesn't dissolve in water[2].
[References]

[1] A.P. Voronov, G.N. Babenko, V.M. Puzikov, A.N. Iurchenko, Growth of LiH2PO4 single crystals from phosphate solutions, Journal of Crystal Growth, 2013, 374, 49–52. [2] R. W. Berg, A. V. Nikiforov, N. J. Bjerrum, Vapor pressure and specific electrical conductivity in the H2O–LiH2PO4–LiPO3 system—a novel electrolyte for water electrolysis at elevated temperature.Ionics, 2021, 27, 703–719.
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Lithium dihydrogen phosphate, 97%(13453-80-0)
[Sigma Aldrich]

13453-80-0(sigmaaldrich)
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