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ChemicalBook CAS DataBase List Zirconium tetrachloride
10026-11-6

Zirconium tetrachloride synthesis

8synthesis methods
Zirconium tetrachloride is obtained as an intermediate in recovering zirconium metal from zircon and other minerals (See Zirconium, Recovery). The tetrachloride is obtained by heating a mixture of zirconium hydroxide and car 1004 bon with chlorine gas
Also, tetrachloride can be made by reacting zirconium hydroxide with hydrochloric acid: Zr(OH)4 + 4HCl → ZrCl4 + 4H2O.
-

Yield:-

Reaction Conditions:

with char coal in neat (no solvent);briquetting with a tenfold excess of char coal; heating the dry briquets at 600-650°C in stream of dry Cl2;; condensation of ZrCl4 in spherical condenser;;

References:

Plotnikov, V. A.;Gitman, E. B. [Zhurnal Prikladnoi Khimii,1946,vol. 19,p. 826 - 832] [Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Zr: MVol., 108, page 285 - 287]

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