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ChemicalBook CAS DataBase List Vanillyl butyl ether
82654-98-6

Vanillyl butyl ether synthesis

4synthesis methods
Vanillyl butyl ether can be used as a cosmetic perfume for the preparation of other functional compositions. It can be synthesized by the reaction of 4-hydroxy-3-methoxybenzyl alcohol and n-butanol.
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Yield:82654-98-6 83%

Reaction Conditions:

with sulfated tungstate at 80; for 3 h;Green chemistry;chemoselective reaction;

Steps:

General procedure for sulphated-tungstate-mediated synthesis of 1-(butoxymethyl)-4-methoxybenzene (Table 3, entry 4)
General procedure: Sulfated tungstate (10 wt%) was added to a mixture of p-methoxybenzyl alcohol (1 g, 7.25 mmol) and n-butanol (1.34 g, 18.11 mmol), and the reaction mixture was stirred at 80 °C for 1 h. The progress of the reaction was monitored by thin-layer chromatography (TLC). After completion of the reaction, the reaction mixture was diluted with EtOAc (15 ml) and filtered to recover the catalyst. The organic layer was concentrated under reduced pressure, and the residue obtained was purified by chromatography on silica gel (60-120) with n-hexane-EtOAc (90:10) as eluent to get pure p-methoxybenzyl ether as a colorless oil.

References:

Katkar, Kamlesh V.;Veer, Sachin D.;Akamanchi, Krishnacharya G. [Synthetic Communications,2016,vol. 46,# 23,p. 1893 - 1901] Location in patent:supporting information

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