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ChemicalBook CAS DataBase List (R)-(-)-4-METHYLGLUTARIC ACID 1-MONOMETHYL ESTER
80986-17-0

(R)-(-)-4-METHYLGLUTARIC ACID 1-MONOMETHYL ESTER synthesis

2synthesis methods
Pentanedioic acid, 2-methylene-, 5-methyl ester

93633-32-0
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Pentanedioic acid, 2-methyl-, 5-methyl ester, (2S)-

1233235-12-5
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Yield:-

Reaction Conditions:

with [Rh((R,R)-Cy-SMS-Phos)(MeOH)2]BF4;hydrogen;tert-butylamine in methanol at 20; under 750.075 Torr; for 4 h;optical yield given as %ee;

References:

Zupancic, Borut;Mohar, Barbara;Stephan, Michel [Organic Letters,2010,vol. 12,# 13,p. 3022 - 3025] Location in patent:supporting information; experimental part

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