ChemicalBook CAS DataBase List CINNAMONITRILE

CINNAMONITRILE synthesis

15synthesis methods

Product Name:CINNAMONITRILE
CAS Number:4360-47-8
Molecular formula:C9H7N
Molecular Weight:129.16

621-82-9 Synthesis

621-82-9
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4360-47-8
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$58.89/25g

Yield: 89%

Reaction Conditions:

with ammonium hydroxide;oxygen in tert-Amyl alcohol under 3750.38 Torr; for 18 h;Green chemistry;

Steps:

13 3-Phenylacryl alcohol was converted to 3-phenylacrylonitrile
Followed by meso-Co-N / C (800) (35 mg, 0.5 mol% Co)3-phenylpropene alcohol (67 mg,0.5 mL), 28% aqueous ammonia (140 [mu] L) was added to a 10 ml reaction flask and then added1ml tert-amyl alcohol as solvent, placed in the reactor, oxygen to 0.5Mpa, placed in 130 oil bath,The degree of reaction was then measured by GC-MS. After the reaction, the internal standard biphenyl was added and analyzed by GC Product 3-phenylacrylonitrile yield. Reaction 18h, 3-phenylacrylonitrile yield of 89%, selectivity of 97%.

References:

Dalian Institute of Chemical Physics;Gao Shuang;Shang Sensen;Wang Lianyue;Lv Ying CN106883143, 2017, A Location in patent:Paragraph 0058-0060

104-55-2 Synthesis