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ChemicalBook CAS DataBase List 2-Chloromethyl-4-methoxy-3,5-dimethylpyridine hydrochloride
86604-75-3

2-Chloromethyl-4-methoxy-3,5-dimethylpyridine hydrochloride synthesis

11synthesis methods
86604-78-6 Synthesis
3,5-Dimethyl-4-methoxy-2-pyridinemethanol

86604-78-6
295 suppliers
$7.00/5g

-

Yield:86604-75-3 100%

Reaction Conditions:

with thionyl chloride in dichloromethane at 20; for 1 h;

Steps:

[2-CHLOROMETHYL-3SS-DIMETHYL-4-METHOXYPYRIDINE] hydrochloride

To a solution [OF 4-METHOXY-3, 5-DIMETHYLPYRIDINEMETHANOL] (25.1 g, 0.15 mol) in dichloromethane (400 mL) was added a solution of thionyl chloride (18.8 g, 0. [158] mol) in dichloromethane (100 mL) over 30 min at room temperature under argon. After an additional 30 min of stirring at room temperature, the solvent was removed under reduced pressure. The solid residue was suspended in hexanes (200 mL) and filtered. The solid was washed with hexanes (50 mL) and air-dried to give 33.3 g (100%) of the title compound as a white solid.

References:

WO2004/9583,2004,A2 Location in patent:Page 156

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