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ChemicalBook >> CAS DataBase List >> PHENYLMAGNESIUM BROMIDE

PHENYLMAGNESIUM BROMIDE

PHENYLMAGNESIUM BROMIDE price.
  • $18 - $7045.5
  • Product name: PHENYLMAGNESIUM BROMIDE
  • CAS: 100-58-3
  • MF: C6H5BrMg
  • MW: 181.31
  • EINECS:202-867-2
  • MDL Number:MFCD00000038
  • Synonyms:bromophenylmagnesium;Phenylmagnesium bromide, 2.8M solution in Diethyl ether;PHENYLMAGNESIUM BROMIDE, 1.0-1.2M in TETRAHYDROFURAN;Phenylmagnesiumbromide,3Minether;Magnesium, bromophenyl-;phenylmagnesium bromide, 3m in ether, packaged under argon in resealable chemseal;Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSealTM bottles;Phenylmagnesium Bromide (32% in Tetrahydrofuran, ca. 2mol/L)
33 prices
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Brand
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Apolloscientific
  • Oakwood
  • Rieke Metals
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC
  • Usbiological
Package
  • 10ml
  • 0.25mole
  • 25ml
  • 1mole
  • 50ml
  • 4X25ML
  • 100ml
  • 200ml
  • 250g
  • 500ml
  • 800ml
  • 1L
  • 18l
  • ManufacturerAlfa Aesar
  • Product number087326
  • Product descriptionPhenylmagnesium bromide 3M in ether
  • Packaging100ml
  • Price$61.4
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042859
  • Product descriptionPhenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal? bottles
  • Packaging100ml
  • Price$62.2
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number087326
  • Product descriptionPhenylmagnesium bromide 3M in ether
  • Packaging500ml
  • Price$147.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042859
  • Product descriptionPhenylmagnesium bromide, 3M in ether packaged under Argon in resealable ChemSeal? bottles
  • Packaging500ml
  • Price$184.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH54729
  • Product descriptionPhenylmagnesium bromide, 3M in 2-MeTHF
  • Packaging100ml
  • Price$340
  • Updated2024-03-01
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0003665
  • Product descriptionPHENYLMAGNESIUM BROMIDE 95.00%
  • Packaging100ML
  • Price$2483.25
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0003665
  • Product descriptionPHENYLMAGNESIUM BROMIDE 95.00%
  • Packaging500ML
  • Price$4504.5
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0003665
  • Product descriptionPHENYLMAGNESIUM BROMIDE 95.00%
  • Packaging1L
  • Price$7045.5
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR320048
  • Product descriptionPhenylmagnesium bromide 2M solution in 2-MeTHF
  • Packaging100ml
  • Price$108
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number214282
  • Product descriptionPhenylmagnesiumbromide1.0MinTetrahydrofuran
  • Packaging10ml
  • Price$18
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number214282
  • Product descriptionPhenylmagnesiumbromide1.0MinTetrahydrofuran
  • Packaging25ml
  • Price$25
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number214282
  • Product descriptionPhenylmagnesiumbromide1.0MinTetrahydrofuran
  • Packaging100ml
  • Price$75
  • Updated2021-12-16
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  • ManufacturerRieke Metals
  • Product numberT0440
  • Product descriptionPhenylmagnesium bromide
  • Packaging100mL
  • Price$152
  • Updated2021-12-16
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  • ManufacturerSigma-Aldrich
  • Product number331376
  • Product descriptionPhenylmagnesium bromide solution 1.0 M in THF
  • Packaging50ml
  • Price$61.6
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number331376
  • Product descriptionPhenylmagnesium bromide solution 1.0 M in THF
  • Packaging100ml
  • Price$71.2
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number171565
  • Product descriptionPhenylmagnesium bromide solution 3.0M in diethyl ether
  • Packaging50ml
  • Price$72.4
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar 087326 Phenylmagnesium bromide 3M in ether 100ml $61.4 2024-03-01 Buy
Alfa Aesar 042859 Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal? bottles 100ml $62.2 2024-03-01 Buy
Alfa Aesar 087326 Phenylmagnesium bromide 3M in ether 500ml $147.65 2024-03-01 Buy
Alfa Aesar 042859 Phenylmagnesium bromide, 3M in ether packaged under Argon in resealable ChemSeal? bottles 500ml $184.65 2024-03-01 Buy
Alfa Aesar H54729 Phenylmagnesium bromide, 3M in 2-MeTHF 100ml $340 2024-03-01 Buy
American Custom Chemicals Corporation OGM0003665 PHENYLMAGNESIUM BROMIDE 95.00% 100ML $2483.25 2021-12-16 Buy
American Custom Chemicals Corporation OGM0003665 PHENYLMAGNESIUM BROMIDE 95.00% 500ML $4504.5 2021-12-16 Buy
American Custom Chemicals Corporation OGM0003665 PHENYLMAGNESIUM BROMIDE 95.00% 1L $7045.5 2021-12-16 Buy
Apolloscientific OR320048 Phenylmagnesium bromide 2M solution in 2-MeTHF 100ml $108 2021-12-16 Buy
Oakwood 214282 Phenylmagnesiumbromide1.0MinTetrahydrofuran 10ml $18 2021-12-16 Buy
Oakwood 214282 Phenylmagnesiumbromide1.0MinTetrahydrofuran 25ml $25 2021-12-16 Buy
Oakwood 214282 Phenylmagnesiumbromide1.0MinTetrahydrofuran 100ml $75 2021-12-16 Buy
Rieke Metals T0440 Phenylmagnesium bromide 100mL $152 2021-12-16 Buy
Sigma-Aldrich 331376 Phenylmagnesium bromide solution 1.0 M in THF 50ml $61.6 2024-03-01 Buy
Sigma-Aldrich 331376 Phenylmagnesium bromide solution 1.0 M in THF 100ml $71.2 2024-03-01 Buy
Sigma-Aldrich 171565 Phenylmagnesium bromide solution 3.0M in diethyl ether 50ml $72.4 2024-03-01 Buy

Properties

Melting point :153-154 °C
Density :1.134 g/mL at 25 °C
Flash point :−40 °F
storage temp. :water-free area
solubility :Miscible with tetrahydrofuran.
form :Liquid
color :Yellow to brown
Specific Gravity :1.14
Water Solubility :reacts
Sensitive :Air & Moisture Sensitive
BRN :3588849
InChIKey :ANRQGKOBLBYXFM-UHFFFAOYSA-M
CAS DataBase Reference :100-58-3(CAS DataBase Reference)
EPA Substance Registry System :Magnesium, bromophenyl- (100-58-3)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Phenylmagnesium bromide is an important reagent called as Grignard reagent used in the synthesis of organic and oraganometallic reactions. It is used to prepare phenyl aryl sulphides, sulphoxides, and sulphones. It acts as a strong acid and Lewis acid and undergoes addition reaction with many unsaturated functional groups. It is involved in the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s, 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, o-substituted benzophenones and 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol. In addition to this, it is used for the monalkylation of primary amines to get secondary amines.

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