| Identification | More | [Name]
PHENYLMAGNESIUM BROMIDE | [CAS]
100-58-3 | [Synonyms]
PHENYLMAGNESIUM BROMIDE
Phenyl magnesium bromide(in ethyl ether)
bromophenyl-magnesiu
phenylmagnesiumbromidesolution
bromophenylmagnesium
PHENYLMAGNESIUM BROMIDE, 3.0M SOLUTION I N DIETHYL ETHER
PHENYLMAGNESIUM BROMIDE SOLUTION, ~1 M I N THF
PHENYLMAGNESIUM BROMIDE SOL., ~3 M IN DI ETHYL ETHER
PHENYLMAGNESIUM BROMIDE, 1.0M SOLUTION I N TETRAHYDROFURAN
Phenylmagnesium Bromide 1.0 M In Tetrahydrofuran
Phenylmagnesium Bromide 3.0 M In Diethyl Ether
Phenylmagnesium bromide, 1M solution in THF
Phenylmagnesium bromide, 2.8M solution in Diethyl ether
PHENYLMAGNESIUM BROMIDE, 1.0-1.2M in TETRAHYDROFURAN
Phenylmagnesiumbromide,3Minether
Magnesium, bromophenyl-
phenylmagnesium bromide, 3m in ether, packaged under argon in resealable chemseal
Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSealTM bottles
Phenylmagnesium Bromide (32% in Tetrahydrofuran, ca. 2mol/L)
Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal bottles | [EINECS(EC#)]
202-867-2 | [Molecular Formula]
C6H5BrMg | [MDL Number]
MFCD00000038 | [Molecular Weight]
181.31 | [MOL File]
100-58-3.mol |
| Chemical Properties | Back Directory | [Appearance]
yellow to orange-brown to brown solution | [Melting point ]
153-154 °C | [density ]
1.134 g/mL at 25 °C
| [Fp ]
−40 °F
| [storage temp. ]
water-free area | [solubility ]
Miscible with tetrahydrofuran. | [form ]
Liquid | [color ]
Yellow to brown | [Specific Gravity]
1.14 | [Water Solubility ]
reacts | [Sensitive ]
Air & Moisture Sensitive | [BRN ]
3588849 | [InChIKey]
ANRQGKOBLBYXFM-UHFFFAOYSA-M | [CAS DataBase Reference]
100-58-3(CAS DataBase Reference) | [EPA Substance Registry System]
100-58-3(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
F+,C,F | [Risk Statements ]
R12:Extremely Flammable.
R14:Reacts violently with water.
R22:Harmful if swallowed.
R34:Causes burns.
R19:May form explosive peroxides.
R11:Highly Flammable. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S33:Take precautionary measures against static discharges .
S29:Do not empty into drains . | [RIDADR ]
UN 3399 4.3/PG 1
| [WGK Germany ]
1
| [F ]
1-3-10 | [TSCA ]
Yes | [HazardClass ]
4.3 | [PackingGroup ]
II | [HS Code ]
29319090 | [Hazardous Substances Data]
100-58-3(Hazardous Substances Data) |
| Raw materials And Preparation Products | Back Directory | [Preparation Products]
2-(Methanesulfonylamino)phenylboronic acid-->Benzophenone imine-->2-Nitrophenylboronic acid-->(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole-->2-Aminoethoxydiphenyl borate-->9-Bromo-9-phenylfluorene-->2-Phenylquinoline-->(S)-(-)-α,α-Diphenyl-2-pyrrolidinemethanol-->Benzhydrol-->1,2,4,5-tetraphenylbenzene-->2-(DIPHENYLMETHYL)-QUINUCLIDIN-3-ONE-->pridinol-->METHYL BIPHENYL-2-CARBOXYLATE-->2,7-Dibromo-9,9'-spiro-bifluorene-->2-Bromo-9,9-diphenyl-9H-fluorene-->1-BROMO-8-PHENYLOCTANE-->3-HYDROXY-3-PHENYL-PIPERIDINE |
| Hazard Information | Back Directory | [Chemical Properties]
Clear light brown to brown solution when properly | [Uses]
Phenylmagnesium Bromide is a reagent used in the preparation of arylcarbonimidic dichlorides via dichloroiodobenzene-mediated gem-dichlorination of aryl isonitriles. | [Definition]
ChEBI: Phenylmagnesium bromide is an arylmagnesium halide. It has a role as a Grignard reagent. | [General Description]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 2.9 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Click here for more information. |
| Questions And Answer | Back Directory | [Reduction agent for preparation of metal carbonyl compound]
In 1890, L.Mond found that when carbon monoxide was burned after being put through the active metal nickel powder, it emitted green light flame. After the resulting gas was cooled, he could obtain colorless liquid (melting point 298K, the boiling point of 316K); if this gas is flowed through a heated glass tube, then it can be seen that the metallic nickel was deposited on the wall. This gas is tetracarbonyl nickel Ni(CO)4. Since the 1960s, people have synthesized a hundreds kinds of such carbonyl compounds and their derivatives. Almost all of the transition metal can form such compounds. This kind of special complex formed through transition metal with carbon monoxide ligands is called metal carbonyls, otherwise known as carbonyl complexes. Metal carbonyl occupies an important position in both theoretical research and practical application in modern inorganic chemistry.
Preparation of metal carbonyl compound can usually via the following methods:
1. Direct synthesis. Most metal carbonyl complexes are prepared by direct combination between metal and carbon monoxide. However, the metal must be new reduction products, and is in a very activated state.
2. Reduction carbonylation effect at high pressure. Apply reducing agent under high pressure to enable the carbonylation reaction between the metal and carbonyl group with the major reducing agents mainly including hydrogen, active metals, phenylmagnesium bromide (C6H5MgBr) and so on.
3. With thermal decomposition or UV irradiation decomposition, we can obtain certain polynuclear carbonyl compounds.
4. Two different kinds of metal carbonyl compounds can interact with each other to give hetero-nuclear carbonyl compound.
| [Related chemical reaction]
1. Phenylmagnesium bromide can react with ferric chloride to give the coupling product. Cyclopentadienyl magnesium bromide can react with ferric chloride to give ferrocene.
2. It can react with chromium trichloride in diethyl ether solution to generate dibenzenechromium.
3. Hexaphenyldilead can be used as the antioxidant of polyphenylene ether lubricant that can be produced from the reaction of lead chloride with phenyl lithium or phenyl magnesium bromide.
4. Take tetrahydrofuran as the solvent, have phenylmagnesium bromide reacted with germanium tetrachloride to obtain tetraphenyl germane.
5. It can be obtained through the low-temperature reaction between lead chloride and phenylmagnesium bromide (Or phenyllithium) in the presence of iodobenzene to derive tetraphenyl lead.
6. Sodium tetraphenylborate is mainly used for the determination of potassium ion, ammonium ion, rubidium ion and cesium ion. It can be obtained with the following process: phenylmagnesium bromide is interacted with boron trifluoride/diethyl ether to generate Tetraphenylboron magnesium bromide first. Evaporate the diethyl ether; add water and then used the calculated amount of sodium carbonate for treatment to obtain it.
The above information is edited by the chemicalbook of Dai Xiongfeng.
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