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ChemicalBook >> CAS DataBase List >> Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate price.
  • $55 - $2600
  • Product name: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
  • CAS: 35138-22-8
  • MF: C16H24BF4Rh
  • MW: 406.07
  • EINECS:460-220-1
  • MDL Number:MFCD00075045
  • Synonyms:Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,98% [Rh(COD)2]BF4;Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate;Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate;(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate;RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX;Bis(cycloocta-1,5-dien)rhodium(I)-tetrafluoroborat for synthesis;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
42 prices
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  • AK Scientific
  • Alfa Aesar
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  • Ambeed
  • Arctom
  • Biosynth Carbosynth
  • Chemenu
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  • ManufacturerAK Scientific
  • Product numberE814
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
  • Packaging100mg
  • Price$154
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number044031
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
  • Packaging1g
  • Price$600
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number044031
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
  • Packaging5g
  • Price$2600
  • Updated2023-06-20
  • Buy
  • ManufacturerAlichem
  • Product number35138228
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
  • Packaging5g
  • Price$436.8
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number35138228
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
  • Packaging10g
  • Price$705.6
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number35138228
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
  • Packaging25g
  • Price$1380
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA108943
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 98%
  • Packaging100mg
  • Price$58
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1233031
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 98+%
  • Packaging100mg
  • Price$62
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1233031
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 98+%
  • Packaging250mg
  • Price$130
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA108943
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 98%
  • Packaging250mg
  • Price$130
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1233031
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 98+%
  • Packaging1g
  • Price$368
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1233031
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 98+%
  • Packaging5g
  • Price$2096
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS441462
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate ≥98%
  • Packaging100mg
  • Price$114
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS441462
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate ≥98%
  • Packaging250mg
  • Price$170
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS441462
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate ≥98%
  • Packaging1g
  • Price$457
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB45672
  • Product descriptionBis (1,5-Cyclooctadiene) rhodium(I)tetrafluoroborate
  • Packaging2g
  • Price$790
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific E814 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 100mg $154 2021-12-16 Buy
Alfa Aesar 044031 Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 1g $600 2023-06-20 Buy
Alfa Aesar 044031 Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 5g $2600 2023-06-20 Buy
Alichem 35138228 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 5g $436.8 2021-12-16 Buy
Alichem 35138228 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 10g $705.6 2021-12-16 Buy
Alichem 35138228 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 25g $1380 2021-12-16 Buy
Ambeed A108943 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 98% 100mg $58 2021-12-16 Buy
Ambeed A1233031 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 98+% 100mg $62 2021-12-16 Buy
Ambeed A1233031 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 98+% 250mg $130 2021-12-16 Buy
Ambeed A108943 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 98% 250mg $130 2021-12-16 Buy
Ambeed A1233031 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 98+% 1g $368 2021-12-16 Buy
Ambeed A1233031 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 98+% 5g $2096 2021-12-16 Buy
Arctom AS441462 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate ≥98% 100mg $114 2021-12-16 Buy
Arctom AS441462 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate ≥98% 250mg $170 2021-12-16 Buy
Arctom AS441462 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate ≥98% 1g $457 2021-12-16 Buy
Biosynth Carbosynth FB45672 Bis (1,5-Cyclooctadiene) rhodium(I)tetrafluoroborate 2g $790 2021-12-16 Buy

Properties

Melting point :210 °C
Density :0.42 g/cm3 (20℃)
storage temp. :Inert atmosphere,Store in freezer, under -20°C
solubility :Chloroform (Slightly), Methanol (Slightly)
form :Powder
color :Red
PH :7 (5g/l, H2O, 20℃)
Water Solubility :insoluble
Sensitive :Slightly air & moisture sensitive
Exposure limits :ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 InChIKey :IEMMJJILGGBYNZ-GSLAGHMSSA-M
CAS DataBase Reference :35138-22-8(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2		 Danger
Warning		 GHS hazard pictograms P210, P240,P241, P280, P370+P378
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an important application for enantioselective hydrogenation and hydrosilylation.

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