Identification | More | [Name]
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate | [CAS]
35138-22-8 | [Synonyms]
BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA& Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,98+% Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate Also available as trifluoromethanesulfonate and hexafluorophosphate | [EINECS(EC#)]
460-220-1 | [Molecular Formula]
C16H24BF4Rh | [MDL Number]
MFCD00075045 | [Molecular Weight]
406.07 | [MOL File]
35138-22-8.mol |
Chemical Properties | Back Directory | [Appearance]
dark red | [Melting point ]
210 °C
| [density ]
0.42 g/cm3 (20℃) | [storage temp. ]
Refrigerator (+4°C) | [form ]
Powder | [color ]
Red | [PH]
7 (5g/l, H2O, 20℃) | [Water Solubility ]
insoluble | [Sensitive ]
Slightly air & moisture sensitive | [InChIKey]
IEMMJJILGGBYNZ-GSLAGHMSSA-M | [CAS DataBase Reference]
35138-22-8(CAS DataBase Reference) | [Storage Precautions]
Air sensitive;Moisture sensitive;Heat sensitive;Store under nitrogen |
Safety Data | Back Directory | [Hazard Codes ]
F,Xi | [Risk Statements ]
R11:Highly Flammable. R34:Causes burns. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
UN 2921 | [WGK Germany ]
2 | [Hazard Note ]
Irritant | [TSCA ]
No | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
28439000 |
Questions And Answer | Back Directory | [Uses]
- Convenient catalyst precursor, for example, with (R,R)QuinoxP* for asymmetric alkylations and hydrogenations.
- Catalyst precursor with chiral biaryl bisphosphine ligands for [2+2+2] enantioenriched cycloadditions.
|
|
|