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ChemicalBook >> CAS DataBase List >>Ethyl benzoylformate

Ethyl benzoylformate

CAS No.
1603-79-8
Chemical Name:
Ethyl benzoylformate
Synonyms
ETHYL 2-OXO-2-PHENYLACETATE;ETHYL PHENYLGLYOXYLATE;Benzeneacetic acid, .alpha.-oxo-, ethyl ester;Ethyl oxophenyla;RARECHEM AL BI 0384;ETHYL BENZOYLFORMATE;PHENYLETHYLGLYOXYLATE;Ethyloxophenylacetate;Ethyl oxophenylacetate;Ethylα-oxobenzeneacetate
CBNumber:
CB4299905
Molecular Formula:
C10H10O3
Molecular Weight:
178.18
MDL Number:
MFCD00009120
MOL File:
1603-79-8.mol
Last updated:2025-04-28 21:36:36

Ethyl benzoylformate Properties

Boiling point 138-139 °C/18 mmHg (lit.)
Density 1.122 g/mL at 25 °C (lit.)
refractive index 1.515-1.517
Flash point 113 °C
storage temp. Store below +30°C.
form Liquid
Specific Gravity 1.122
color Clear colorless to greenish
Water Solubility Soluble in water 1143 mg/L @ 25°C .
Sensitive Moisture Sensitive
InChI InChI=1S/C10H10O3/c1-2-13-10(12)9(11)8-6-4-3-5-7-8/h3-7H,2H2,1H3
InChIKey QKLCQKPAECHXCQ-UHFFFAOYSA-N
SMILES C1(C=CC=CC=1)C(=O)C(=O)OCC
LogP 1.974 (est)
CAS DataBase Reference 1603-79-8(CAS DataBase Reference)
FDA UNII AMN28N4D74
NIST Chemistry Reference Benzeneacetic acid, «alpha»-oxo-, ethyl ester(1603-79-8)
EPA Substance Registry System Benzeneacetic acid, .alpha.-oxo-, ethyl ester (1603-79-8)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H314-H227
Precautionary statements  P501-P270-P210-P264-P280-P370+P378-P303+P361+P353-P301+P330+P331-P363-P301+P312+P330-P304+P340+P310-P305+P351+P338+P310-P403+P235-P405
Hazard Codes  Xi
Safety Statements  24/25
WGK Germany  3
Hazard Note  Moisture Sensitive
TSCA  Yes
HazardClass  IRRITANT
HS Code  29183000
NFPA 704
1
0 0

Ethyl benzoylformate price More Price(32)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 258911 Ethyl benzoylformate 95% 1603-79-8 5g $31.8 2024-03-01 Buy
Sigma-Aldrich 258911 Ethyl benzoylformate 95% 1603-79-8 25g $71 2024-03-01 Buy
TCI Chemical B0109 Ethyl Benzoylformate >96.0%(GC) 1603-79-8 5mL $29 2024-03-01 Buy
TCI Chemical B0109 Ethyl Benzoylformate >96.0%(GC) 1603-79-8 25mL $76 2024-03-01 Buy
Alfa Aesar B25292 Ethyl phenylglyoxylate, 98% 1603-79-8 5g $27.65 2024-03-01 Buy
Product number Packaging Price Buy
258911 5g $31.8 Buy
258911 25g $71 Buy
B0109 5mL $29 Buy
B0109 25mL $76 Buy
B25292 5g $27.65 Buy

Ethyl benzoylformate Chemical Properties,Uses,Production

Chemical Properties

clear colorless to greenish liquid

Uses

Ethyl Benzoylformate is a general chemical reagent used in the preparation of diaminoethanediyl bismethylpyridinium salts for designing recyclable organocatalysts.

Application

Ethyl benzoylformate has been used in preparation of 1,5-dihydro-5-deazaflavin derivatives possessing a chiral substituent at N(3) position.

Definition

ChEBI: Ethyl benzoylformate is the ethyl ester of phenylglyoxylic acid. Metabolite observed in cancer metabolism. It has a role as a human metabolite. It derives from a phenylglyoxylic acid.

Synthesis Reference(s)

Journal of the American Chemical Society, 82, p. 918, 1960
The Journal of Organic Chemistry, 50, p. 3573, 1985 DOI: 10.1021/jo00219a025
Tetrahedron Letters, 23, p. 3661, 1982 DOI: 10.1016/S0040-4039(00)88651-7

General Description

Enantioselective hydrogenation of ethyl benzoylformate on Pt/Al2O3 modified with dihydrocinchonidine has been studied.

15206-55-0
64-17-5
1603-79-8
Synthesis of Ethyl benzoylformate from Methyl benzoylformate and Ethanol
Global( 251)Suppliers
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Shenyang Simchoice Chemical Co.,Ltd
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Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29730 60
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Hi-Tech Chemistry Corp 		0519-86626038 yuhh@hitechem.com CHINA 810 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21628 55
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Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28172 58
Alchem Pharmtech,Inc. 		8485655694 sales@alchempharmtech.com United States 63687 58
Wuhan Chemwish Technology Co., Ltd 		027-67849912 sales@chemwish.com CHINA 10821 58
Jinan Liheng Biotechnology Co., Ltd. 		15865262812 info@lihengpharm.com CHINA 938 58

View Lastest Price from Ethyl benzoylformate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Ethyl phenylglyoxylate pictures 2025-04-27 Ethyl phenylglyoxylate
1603-79-8
 US $29.00 / g 98.97% 10g TargetMol Chemicals Inc.
Ethyl benzoylformate pictures 2025-03-12 Ethyl benzoylformate
1603-79-8
 US $0.00 / kg 1kg 99% 10000KGS Shaanxi Dideu New Materials Co. Ltd
Ethyl benzoylformate pictures 2019-07-06 Ethyl benzoylformate
1603-79-8
 US $2.00 / kg 1kg 99% 100kg Career Henan Chemical Co
RARECHEM AL BI 0384 PHENYLETHYLGLYOXYLATE PHENYLGLYOXYLIC ACID ETHYL ESTER alpha-oxo-benzeneaceticaciethylester Benzenaceticacid,-oxoethylester Benzeneaceticacid,α-oxo-,ethylester Ethyl oxophenylacetate Ethyloxophenylacetate Ethylα-oxobenzeneacetate Glyoxylic acid, phenyl-, ethyl ester alpha-oxo-benzeneacetic acid ethyl ester Ethyl oxo(phenyl)acetate 98% Ethyl phenylglyoxylate, Ethyl benzoylformate Benzoylformic Acid Ethyl Ester Ethyl Phenylglyoxylate Phenylglyoxylic Acid Ethyl Ester ETHYL PHENYLGLYOXYLATE FOR SYNTHESIS Gloyoxylic acid, phenyl-, ethyl ester 2-Oxo-2-phenylacetic acid ethyl ester 2-Phenylglyoxalic acid ethyl ester Phenyloxoacetic acid ethyl ester Ethyl benzoylformate,95% a-Oxo-benzeneacetic acid ethyl ester Ethyl BenzoylforMate, 97+% Glyoxylicacid,phenyl-,ethylester Oxo-phenyl-aceticacidethylester α-Oxobenzeneaceticacidethylester ETHYL BENZOYLFORMATE BENZOYLFORMIC ACID ETHYL ESTER Benzoylformic acid ethyl ester~Ethyl phenylglyoxylate BENZENACETIC ACID, -OXO ETHYL ESTER 96% PhenylglyoxylicAcidEthylEther Ethyl benzoylformate 98% Ethyl oxophenyla Benzeneacetic acid, α-oxo-, ethyl ester ETHYL 2-OXO-2-PHENYLACETATE ETHYL PHENYLGLYOXYLATE Benzeneacetic acid, .alpha.-oxo-, ethyl ester 1603-79-8 C6H5COCO2C2H5 C6H5COCOOC2H5 Carbonyl Compounds C10 to C11 Building Blocks Esters Organic Building Blocks Pharmaceutical Intermediates Aromatic Esters Esters Phenyls & Phenyl-Het API intermediates Phenyls & Phenyl-Het