| Identification | More | [Name]
Ethyl benzoylformate | [CAS]
1603-79-8 | [Synonyms]
BENZOYLFORMIC ACID ETHYL ESTER
ETHYL 2-OXO-2-PHENYLACETATE
ETHYL BENZOYLFORMATE
ETHYL PHENYLGLYOXYLATE
PHENYLETHYLGLYOXYLATE
PHENYLGLYOXYLIC ACID ETHYL ESTER
RARECHEM AL BI 0384
alpha-oxo-benzeneaceticaciethylester
Benzenaceticacid,-oxoethylester
Benzeneaceticacid,α-oxo-,ethylester
Ethyl oxophenylacetate
Ethyloxophenylacetate
Ethylα-oxobenzeneacetate
Glyoxylic acid, phenyl-, ethyl ester
Glyoxylicacid,phenyl-,ethylester
Oxo-phenyl-aceticacidethylester
α-Oxobenzeneaceticacidethylester
Benzoylformic acid ethyl ester~Ethyl phenylglyoxylate
BENZENACETIC ACID,-OXO ETHYL ESTER 96%
PhenylglyoxylicAcidEthylEther | [EINECS(EC#)]
216-504-0 | [Molecular Formula]
C10H10O3 | [MDL Number]
MFCD00009120 | [Molecular Weight]
178.18 | [MOL File]
1603-79-8.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to greenish liquid | [Boiling point ]
138-139 °C/18 mmHg (lit.) | [density ]
1.122 g/mL at 25 °C(lit.) | [refractive index ]
1.515-1.517
| [Fp ]
113 °C
| [storage temp. ]
Store below +30°C. | [form ]
Liquid | [color ]
Clear colorless to greenish | [Specific Gravity]
1.122 | [Water Solubility ]
Soluble in water 1143 mg/L @ 25°C . | [Sensitive ]
Moisture Sensitive | [InChI]
InChI=1S/C10H10O3/c1-2-13-10(12)9(11)8-6-4-3-5-7-8/h3-7H,2H2,1H3 | [InChIKey]
QKLCQKPAECHXCQ-UHFFFAOYSA-N | [SMILES]
C1(C=CC=CC=1)C(=O)C(=O)OCC | [LogP]
1.974 (est) | [CAS DataBase Reference]
1603-79-8(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzeneacetic acid, «alpha»-oxo-, ethyl ester(1603-79-8) | [EPA Substance Registry System]
1603-79-8(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3 | [Hazard Note ]
Moisture Sensitive | [TSCA ]
Yes | [HazardClass ]
IRRITANT | [HS Code ]
29183000 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless to greenish liquid | [Application]
Ethyl benzoylformate has been used in preparation of 1,5-dihydro-5-deazaflavin derivatives possessing a chiral substituent at N(3) position. | [Uses]
Ethyl Benzoylformate is a general chemical reagent used in the preparation of diaminoethanediyl bismethylpyridinium salts for designing recyclable organocatalysts. | [Definition]
ChEBI: Ethyl benzoylformate is the ethyl ester of phenylglyoxylic acid. Metabolite observed in cancer metabolism. It has a role as a human metabolite. It derives from a phenylglyoxylic acid. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 82, p. 918, 1960
The Journal of Organic Chemistry, 50, p. 3573, 1985 DOI: 10.1021/jo00219a025
Tetrahedron Letters, 23, p. 3661, 1982 DOI: 10.1016/S0040-4039(00)88651-7 | [General Description]
Enantioselective hydrogenation of ethyl benzoylformate on Pt/Al2O3 modified with dihydrocinchonidine has been studied. |
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