cis-Hex-3-en-1-ol
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cis-Hex-3-en-1-ol Eigenschaften
- Schmelzpunkt:
- 22.55°C (estimate)
- Siedepunkt:
- 156-157 °C(lit.)
- Dichte
- 0.848 g/mL at 25 °C(lit.)
- Dampfdichte
- 3.45 (vs air)
- Dampfdruck
- 2.26hPa at 25℃
- Brechungsindex
- n
20/D 1.44(lit.)
- FEMA
- 2563 | CIS-3-HEXENOL
- Flammpunkt:
- 112 °F
- storage temp.
- Flammables area
- L?slichkeit
- DMSO: 100 mg/mL (998.40 mM)
- Aggregatzustand
- Liquid
- pka
- 15.00±0.10(Predicted)
- Wichte
- 0.848 (20/4℃)
- Farbe
- APHA: ≤100
- Geruch (Odor)
- at 10.00 % in dipropylene glycol. fresh green cut grass foliage vegetable herbal oily
- Geruchsart
- green
- Biologische Quelle
- synthetic
- Wasserl?slichkeit
- INSOLUBLE
- Merck
- 14,4700
- JECFA Number
- 315
- BRN
- 1719712
- Stabilit?t:
- Stable. Substances to be avoided include strong oxidizing agents and strong acids. Flammable.
- LogP
- 1 at 35℃
- CAS Datenbank
- 928-96-1(CAS DataBase Reference)
- NIST chemische Informationen
- 3-Hexen-1-ol, (Z)-(928-96-1)
- EPA chemische Informationen
- (Z)-3-Hexen-1-ol (928-96-1)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher | F | ||
---|---|---|---|
R-S?tze: | 10 | ||
S-S?tze: | 16 | ||
RIDADR | UN 1987 3/PG 3 | ||
WGK Germany | 1 | ||
RTECS-Nr. | MP8400000 | ||
F | 10 | ||
TSCA | Yes | ||
HazardClass | 3 | ||
PackingGroup | III | ||
HS Code | 29052990 | ||
Giftige Stoffe Daten | 928-96-1(Hazardous Substances Data) | ||
Toxizit?t | The acute oral LD50 value in rats was reported as 4.70 g/kg (3.82-5.58 g/kg) (Moreno, 1973). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Moreno, 1973). |
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cis-Hex-3-en-1-ol Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R10:Entzündlich.S-S?tze Betriebsanweisung:
S16:Von Zündquellen fernhalten - Nicht rauchen.Beschreibung
Leaf alcohol exists as a liquid at room temperature with a characteristic odor of green leaves. It is found in green tea, violet leaf oil, and many types of leaves, herbs, and grasses. Leaf alcohol finds applications in perfumery as floral fragrance. Leaf alcohol is also investigated for its antidiabetic activity.Chemische Eigenschaften
Leaf Alcohol is a colorless liquid with the characteristic odor of freshly cut grass. In small quantities, leaf alcohol occurs in the green parts of nearly all plants. The volatile flavor constituents of green tea contain up to 30%.A stereospecific synthesis of (Z)-3-hexen-1-ol starts with the ethylation of sodium acetylide to 1-butyne, which is reacted with ethylene oxide to give 3-hexyn-1-ol. Selective hydrogenation of the triple bond in the presence of palladium catalysts yields (Z)-3-hexen-1-ol. Biotechnological processes have been developed for its synthesis as a natural flavor compound, for example.
Leaf alcohol is used to obtain natural green top notes in perfumes and flavors. In addition, it is the starting material for the synthesis of (2E,6Z)-2,6-nonadien-l-ol and (2E,6Z)-2,6-nonadien-l-al.
Occurrence
Main constituent of the oil distilled from the infusion of fermented tea leaves. Reported found as the corresponding ester of phenylacetic acid in the oil of Japanese mint (Mentha arvensis); the volatile oil of Thea chinensis contains approximately 26 to 35% 3-hexen-1-ol, whereas larger amounts are reported in the oils of Morus bombysic, Robinia pseudacacia and Raphanus sativus. Probably occurring also in several green leaves and herbs; reported found in the fruit juices of raspberry, grapefruit and others. Also reported in over 200 foods including apple, apricot, banana, citrus peel oils and juices, berries, guava, mango, grapes, pineapple, cabbage, kohlrabi, celery, cucumber, lettuce, leek, peas, sauerkraut, tomato, ginger, peppermint oil, coconut oil, spearmint oil, mustard, parsley, breads, butter, fish, fish oil, cognac, brandy, cider, sherry, grape wines, tea, soybeans, avocado, olive, passion fruit, plum, rose apple, Malay apple, water apple (Syzigium spp.), beans, marjoram, starfruit, broccoli, pear and apple brandies, figs, brussels sprouts, radish, prickly pear, litchi, dill, lovage, pumpkin, corn oil, malt, laurel, kiwifruit and other sourcesDefinition
ChEBI: A primary alcohol that consists of (3Z)-hex-3-ene substituted by a hydroxy group at position 1.synthetische
By the reaction of butyne-1 with ethylene oxide and subsequent selective reduction to the eis isomer (Bedoukian, 1967).Allgemeine Beschreibung
cis-3-Hexen-1-ol is one of the key volatile constituents of green leaf volatiles(GLV) that can act as an attractant to various insects. It is emitted by green plants when they are physically damaged.Einzelnachweise
[1] NPCS Board of Consultants & Engineers, Industrial Alcohol of Technology Handbook, 2010[2] A. Shirwaikar, K. Rajendran and C. Kumar, Oral Antidiabetic Activity of Annona squamosa Leaf Alcohol Extract in NIDDM Rats, Pharmaceutical Biology, 2004, vol. 42, 30-35
cis-Hex-3-en-1-ol Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Natriumacetylid
But-1-in
Natrium
Hex-1-in-3-ol
Hex-3-in
Triphenylphosphin
Lithium
Ammoniak, wasserfrei
Hex-3-en-1-ol
5,6-Dihydro-2-methyl-2H-pyran
(E)-Hex-4-en-1-ol
trans-Hex-3-en-1-ol
Downstream Produkte
(Z)-Hex-3-enylformiat
Hex-3-enylisovalerat
1-Propylallylacetat
cfs-3-trans-2-Hexenyl propionate(mixtme)
cis-3-Hexenai
(Z)-Hex-3-enyl-2-methylbutyrat
(Z)-Hex-3-enylbutyrat
(2E,6Z)-Nona-2,6-dien-1-ol
(Z)-Hex-2-ensure
cis-Hex-3-en-1-ylmethylcarbonat
CIS-5,8,11,14,17-EICOSAPENTAENOIC ACID METHYL ESTER
(Z)-Hex-3-enylbenzoat
(Z)-1-Methoxyhex-3-en
cis-Hex-3-en-1-ol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 524)Lieferanten
Firmenname | Telefon | Land | Produktkatalog | Edge Rate | |
---|---|---|---|---|---|
Henan Xiangduo Industry Co., Ltd. | +86-15981848961 +86-15981848961 |
sales@xiangduochem.com | China | 497 | 58 |
Shandong Deshang Chemical Co., Ltd. | +86-0531-8875-2665 +8613153039501 |
info@deshangchem.com | China | 662 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8615531157085 |
abby@weibangbio.com | China | 8806 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 |
sales1@chuanghaibio.com | China | 5889 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 20267 | 58 |
Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 |
admin@zlchemi.com | China | 3692 | 58 |
JINING XINHE CHEMICAL CO., LTD | +8615318402391 |
sales@xinhepharma.com | China | 809 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21634 | 55 |
Hangzhou FandaChem Co.,Ltd. | +8615858145714 |
FandaChem@Gmail.com | China | 8771 | 55 |
Shanxi Naipu Import and Export Co.,Ltd | +86-13734021967 +8613734021967 |
kaia@neputrading.com | China | 1001 | 58 |
928-96-1(cis-Hex-3-en-1-ol)Verwandte Suche:
(+)-Cloprostenol
Hydratase, Phosphopyruvat
Pregnenolon
DEOXYNIVALENOL
3-Methyl-2-buten-1-ol
2-Methyl-6-methylenoct-7-en-2-ol, Dihydroderivat
Carboxylase, Phosphopyruvat (Phosphat)
Ethylacetat
2,2,6,6-Tetramethylpiperidin-4-ol
19-Hydroxyandrost-4-en-3,17-dion
Colchicin
Geraniol
(Z)-Hex-3-enylacetat
(Z)-3-Hexenylsalicylat
2,5-Dichlor-3,6-dihydroxybenzochinon
2,5-Dihydroxy-p-benzochinon
Tetroquinon
Ethyl-3-ethyl-2-methyl-4-oxo(cyclohex-2-en)carboxylat
- cis-Hex-3-enol
- Hex-3(Z)-enol
- HEXEN-30L-1
- TIMTEC-BB SBB007739
- cfs-3-Hexen-1-ol
- leaf alcohol >=99.0%
- CIS-III-Hexenol
- Leaf Alcoho
- Ye Chun
- cis-3-Hexen-1-
- Leaf alcohol cis-Hex-3-en-1-ol
- cis-3-Hexen-1-ol≥ 99% (GC)
- cis-3-Hexen-1-ol
- LEAF ALCOHOL
- HEXENOL, CIS-3-
- C3 HEXENOL
- CIS-3-HEXEN-1-YL ALCOHOL
- lef alcohol
- HEXEN-3-OL-1, cis
- CIS-3-HEXEN-1-OL >=98% FCC
- LEAF ALCOHOL:CIS-3-HEXEN-1-OL
- cis-3-Hexen-1-ol,98%
- cis-3-Hexen-1-ol Odor Standard
- 3-HEXENOL-1
- HEXENOL CIS-3 (VERDALOL C)
- (Z)-3-hexenol,(Z)-3-hexen-1-ol
- 3-Hexen-1-ol, (3Z)-
- CIS-3-HEXENOL(LEAF ALCOHOL)
- CIS-3-HEXENOL, NATURAL
- (Z)-Hex-3-ene-1-ol
- (Z)Hex-3-enol
- 1-Hydroxyhex-3-ene
- 3-(Z)-Hexenol
- 3-Hexan-1-ol
- 3-Hexen-1-ol, cis-
- 3-Hexenol, cis-
- 3-Hexenylalcohol
- CIS-III-Hexenol 98%
- cis-3-Hexenyl alcohol
- Folic alcohol
- Leafalcohol=Blteralkohol
- CIS-3-HEXEN-1-OL=BLTERALKOHOL=CIS-3-HEXENOL
- (Z)-3-Hexene-1-nol
- ENT-25091
- Blatteralkohol
- Blatteralkohol (German)
- cis-3-1-Hexenol
- cis-3-hexen-1-o
- cis-3-Hexen-1-ol Odor
- cis-3-Hexen-1-ol>
- LEAF ALC0HOL
- 3Z-6OH
- Foliar alcohol
- cis-3-HEXEN-1-OL, 98%cis-3-HEXEN-1-OL, 98%cis-3-HEXEN-1-OL, 98%
- cis-3-HEXEN-1-OL (LEAF ALCOHOL) FCC
- cis-3-Hexene-1-ol
- Z-3-Hexenol
- (3Z)-3-Hexen-1-ol