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Kupferbromid

Cuprous bromide Struktur
7787-70-4
CAS-Nr.
7787-70-4
Bezeichnung:
Kupferbromid
Englisch Name:
Cuprous bromide
Synonyma:
COPPER BROMIDE;COPPER(I) BROMIDE;cooper bromide;Kupferbromid;Bromocopper(I);CUPROUS BROMIDE;Cupper(Ⅰ)bromide;COPPER(+1)BROMIDE;Copper(l) bromide;coppermonobromide
CBNumber:
CB7311066
Summenformel:
BrCu
Molgewicht:
143.45
MOL-Datei:
7787-70-4.mol

Kupferbromid Eigenschaften

Schmelzpunkt:
504 °C(lit.)
Siedepunkt:
1345 °C
Dichte
4.71 g/mL at 25 °C(lit.)
Flammpunkt:
1345°C
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
L?slichkeit
insoluble in acetone
Aggregatzustand
Powder
Wichte
4.98
Farbe
Pale green to green
Wasserl?slichkeit
Soluble in hydrogen bromide, hydrochloric acid, and ammonium hydroxide. Slightly soluble in water. Insoluble in acetone.
Sensitive 
Air Sensitive
Crystal Structure
Hexagonal, Wurtzite (Zincite) Structure - Space Group P 63mc
Merck 
14,2659
Solubility Product Constant (Ksp)
pKsp: 8.2
Expositionsgrenzwerte
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
Stabilit?t:
Stable, but may be air or light sensitive. Incompatible with alkali metals, strong oxidizing agents.
InChIKey
NKNDPYCGAZPOFS-UHFFFAOYSA-M
CAS Datenbank
7787-70-4(CAS DataBase Reference)
NIST chemische Informationen
Copper(I) bromide(7787-70-4)
EPA chemische Informationen
Copper bromide (CuBr) (7787-70-4)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xi
R-S?tze: 36/37/38-22
S-S?tze: 22-24/25-26-37/39
RIDADR  3260
WGK Germany  3
8-10-23
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  28275900
Giftige Stoffe Daten 7787-70-4(Hazardous Substances Data)
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H318 Verursacht schwere Augensch?den. Schwere Augensch?digung Kategorie 1 Achtung GHS hazard pictogramssrc="/GHS05.jpg" width="20" height="20" /> P280, P305+P351+P338, P310
H410 Sehr giftig für Wasserorganismen mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 1 Warnung GHS hazard pictogramssrc="/GHS09.jpg" width="20" height="20" /> P273, P391, P501
Sicherheit
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P301+P312 BEI VERSCHLUCKEN: Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.

Kupferbromid Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-S?tze Betriebsanweisung:

S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.

Chemische Eigenschaften

Copper(I) bromide is a Pale green to green poeder that decomposes on exposure to light or moisture in air. It forms complexes with hydrochloric and hydrobromic acids and aqueous ammonia.
Cuprous bromide

Verwenden

As catalyst for organic reactions.

synthetische

It is prepared pyrometallurgically with copper metal and elemental bromine in a process similar to that for copper(I) chloride. It can also be produced by the reduction of copper(II) sulfate solutions in the presence of sodium bromide using metallic copper or sulfite as the reducing agent. Copper(I) bromide is used as a polymerization catalyst in organic reactions.

Allgemeine Beschreibung

White powder or crystal. Turns green to dark blue on exposure to sunlight. Sinks and mixes slowly with water.

Air & Water Reaktionen

Mixes slowly with water.

Reaktivit?t anzeigen

Cuprous bromide has weak oxidizing or reducing powers. Redox reactions can however still occur. The majority of compounds in this class are slightly soluble or insoluble in water. If soluble in water, then the solutions are usually neither strongly acidic nor strongly basic. These compounds are not water-reactive.

Health Hazard

INHALATION: Irritation of upper respiratory tract. EYES: Irritation of conjunctivae. SKIN: Irritation, acne-like rash (usually from prolonged exposure). INGESTION: Vomiting caused by local irritant and astringent action of ionic Cu on stomach and intestines. Pain in mouth, esophagus, and stomach. Inorganic bromides produce depression, psychoses, and mental deterioration.

l?uterung methode

Purify it as for cuprous iodide but using aqueous NaBr. [Keller & Wycoff Inorg Synth II 3 1946, Glemser & Sauer in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1006 1965.]

Kupferbromid Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Kupferbromid Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 512)Lieferanten
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7787-70-4(Kupferbromid)Verwandte Suche:


  • COPPER(+1)BROMIDE
  • Copper(I) broMide 99.999% trace Metals basis
  • Copper(I) broMide, 98.5%
  • Copper(i) bromide, 98%, extra pure
  • Copper(I) bromide, min. 98%
  • Bromocopper(I)
  • Copper(I) bromide, Puratronic, 99.998% (metals basis)
  • Cuprous bromide,98%
  • COPPER(I)BROMIDE(RG)
  • Copper(I) broMide, extra pure, 98% 250GR
  • Copper(I)bromide,min.98%
  • copper(i) bromide, puratronic
  • CuBr Copper(I)bromide
  • COPPER(I) BROMIDE, 99.999%
  • Copper(I) bromide, Puratronic(R), 99.998% (metals basis)
  • Copper(I) bromide beads, -10 mesh, 99.99% trace metals basis
  • Copper(I) bromide purum p.a., >=98.0% (RT)
  • Copper(l) bromide
  • Copper(I) bromide, ampuled under argon, 99.995% trace metals basis
  • CUPROUS BROMIDE
  • copperbromide(cubr)
  • coppermonobromide
  • Copperbromideoffwhitepowder
  • Cupper(Ⅰ) bromide
  • Copper(I) bromide, 99.999% metals basis
  • Copper(I)Bromide,>98%
  • CuprousBromide(Anhydrous)
  • Copper(I)bromide,95%min.
  • Copper(I)bromide,97%
  • Copper(I) bromide, extra pure, 98%
  • CUPROUS BROMIDE 99.999%
  • Copper(Ⅰ) bromide
  • Copper(I) bromide, 99%, for synthesis
  • Copper(I) Bromide, 99.9%
  • Copper(I) bromide (99.99%-Cu) PURATREM
  • Cuprous bromide ISO 9001:2015 REACH
  • Kupferbromid
  • Cupper(Ⅰ)bromide
  • Cuprous Bromide pure, 98.5%
  • CUPROUS BROMIDE ANHYDROUS Extra Pure
  • COPPER BROMIDE
  • COPPER(I) BROMIDE
  • cooper bromide
  • Copper bromide (CuBr) (8CI, 9CI, ACI)
  • Copper (I) Bromide Anhydrous 97% Extrapure
  • Copper(I) bromide, 99.998% (metals basis),powder
  • CUPROUS BROMIDE ANHYDROUS 97%
  • 7787-70-4
  • 787-70-4
  • CuBr
  • Click Catalyst and Ligands
  • Click Chemistry
  • Specialty Synthesis
  • Chemical Ligation
  • Catalysis and Inorganic Chemistry
  • 29: Cu
  • Beaded Materials
  • Ceramic Science
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