Brom[thiobis[methan]]kupfer
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- CAS-Nr.
- 54678-23-8
- Bezeichnung:
- Brom[thiobis[methan]]kupfer
- Englisch Name:
- Copper(I) bromide-dimethyl sulfide
- Synonyma:
- COPPER(I) BROMIDE-DIMETHYL SULFIDE COMPLEX;COPPER(I) BROMIDE DIMETHYL SULFIDE;Bromocopper;Copper(I) bromide methyL;Copper, bromothiobismethane-;COPPER(1)BROMIDE DMS COMPLEX;bromo[thiobis[methane]]copper;COPPER BROMIDE-DIMETHYL SULFIDE;BROMO(DIMETHYLSULFIDE)COPPER(I);COPPER(1) BROMIDE DMS COMPLEX 95%
- CBNumber:
- CB6332325
- Summenformel:
- C2H6BrCuS
- Molgewicht:
- 205.58
- MOL-Datei:
- 54678-23-8.mol
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Brom[thiobis[methan]]kupfer Eigenschaften
- Schmelzpunkt:
- 132 °C (dec.)(lit.)
- Aggregatzustand
- Crystalline Powder and/or Chunks
- Farbe
- Pale brown or pale green
- Wasserl?slichkeit
- Soluble in water. Reacts with water and decomposes.
- Sensitive
- Moisture Sensitive/Air Sensitive
- BRN
- 4386581
- Expositionsgrenzwerte
- ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
- InChIKey
- PMHQVHHXPFUNSP-UHFFFAOYSA-M
- CAS Datenbank
- 54678-23-8(CAS DataBase Reference)
Brom[thiobis[methan]]kupfer Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
off-white to beige, grey or green crystalline
Verwenden
Copper(I) bromide-dimethyl sulfide can be used as catalyst for adding Grignard reagents to fullerenes.
l?uterung methode
Purify it by recrystallisation in the presence of Me2S. A solution of the complex (1.02g) in Me2S (5mL) is slowly diluted with hexane (20mL), and the pure colourless prisms of the complex (0.96g) separate and are collected and dried, m 124-129o(dec). The complex is insoluble in hexane, Et2O, Me2CO, CHCl3 and CCl4. It dissolves in DMF and DMSO, but the solution becomes hot and green indicating decomposition. It dissolves in *C6H6, Et2O, MeOH and CHCl3 if excess of Me2S is added and a colourless solution is obtained. [House et al. J Org Chem 40 1460 1975.] Prior to use, the complex is dissolved in Me2S and evaporated to dryness in the weighed reaction flask [Bourgain-Commer.on et al. J Organomet Chem 228 321 1983].
Brom[thiobis[methan]]kupfer Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Brom[thiobis[methan]]kupfer Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 179)Lieferanten
54678-23-8(Brom[thiobis[methan]]kupfer)Verwandte Suche:
- bromo[thiobis[methane]]copper
- CUPROUS BROMIDE METHYLSULFIDE COMPLEX
- BROMO(DIMETHYLSULFIDE)COPPER(I)
- Copper(I) bromide methylsulfide complex
- Copper, bromothiobismethane-
- COPPER BROMIDE-DIMETHYL SULFIDE
- Copper(I) bromide methyl sulfide complex, Cuprous bromide methyl sulfide complex
- Copper(i)bromide-dimethyl sulfide complex,99%
- Copper (I) bromide dimethylsulphide complex
- Copper(I) bromide dimethyl sulfide complex,Copper(I) bromide methyl sulfide complex, Cuprous bromide methyl sulfide complex
- Copper (I) bromide dimethylsulphide complex 99%
- Copper(I) broMide-diMethyl sulfide coMplex, 99% 10GR
- Copper(Ⅰ) bromide-dimethyl sulfide complex
- Copper(I) broMide diMethyl sulfide coMplex 99%
- COPPERBROMIDE-DIMETHYL SULFIDE COMPLEX
- Cuprous bromide dimethyl sulfide complex
- COPPER(1) BROMIDE DMS COMPLEX 95%
- Copper(I) bromide-dimethyl sulfide ISO 9001：2015 REACH
- C**Copper(I) bromide-dimethyl sulfide
- Copper(I) bromide methyL
- COPPER(I) BROMIDE DIMETHYL SULFIDE
- COPPER(I) BROMIDE-DIMETHYL SULFIDE COMPLEX
- Bromocopper
- COPPER(1)BROMIDE DMS COMPLEX
- 54678-23-8
- CuBrSCH32
- C2H6BrCuS
- CuBrCH3SCH3
- CH32SCuBr
- C2H6SBrCu
- BrC2CuH6S
- Catalysis and Inorganic Chemistry
