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Tetrahydrofurfurylalkohol

Tetrahydrofurfuryl alcohol Struktur
97-99-4
CAS-Nr.
97-99-4
Bezeichnung:
Tetrahydrofurfurylalkohol
Englisch Name:
Tetrahydrofurfuryl alcohol
Synonyma:
THFA;Tetrahydrofurfuryl;TETRAHYDRO-2-FURANMETHANOL;Oxolane-2-methanol;2-Hydroxymethyl oxolane;Tetrahydrofuran methanol;Tetrahydro-2-furylmethanol;Tetrahydrofurfruyl Alcohol;(tetrahydro-furan-2-yl)-methanol;qothfa
CBNumber:
CB6414751
Summenformel:
C5H10O2
Molgewicht:
102.13
MOL-Datei:
97-99-4.mol

Tetrahydrofurfurylalkohol Eigenschaften

Schmelzpunkt:
-80 °C (lit.)
Siedepunkt:
178 °C (lit.)
Dichte
1.054 g/mL at 25 °C (lit.)
Dampfdichte
3.52 (vs air)
Dampfdruck
2.3 mm Hg ( 39 °C)
Brechungsindex
n20/D 1.452(lit.)
FEMA 
3056 | TETRAHYDROFURFURYL ALCOHOL
Flammpunkt:
183 °F
storage temp. 
Store below +30°C.
L?slichkeit
acetone: miscible(lit.)
Aggregatzustand
Liquid
pka
14.44±0.10(Predicted)
Farbe
Clear
Geruch (Odor)
at 100.00 %. vegetable cauliflower faint warm oily caramel
Geruchsart
vegetable
Explosionsgrenze
1.5-9.7%(V)
Wasserl?slichkeit
soluble
Sensitive 
Hygroscopic
Merck 
14,9213
JECFA Number
1443
BRN 
102723
Dielectric constant
13.48
InChIKey
BSYVTEYKTMYBMK-UHFFFAOYSA-N
LogP
-0.14 at 24.7℃
CAS Datenbank
97-99-4(CAS DataBase Reference)
NIST chemische Informationen
2-Furanmethanol, tetrahydro-(97-99-4)
EPA chemische Informationen
Tetrahydrofurfuryl alcohol (97-99-4)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xi,T
R-S?tze: 36-62-61
S-S?tze: 39-36/37/39
RIDADR  NA 1993 / PGIII
WGK Germany  2
RTECS-Nr. LU2450000
Selbstentzündungstemperatur 282 °C
TSCA  Yes
HS Code  29321300
Giftige Stoffe Daten 97-99-4(Hazardous Substances Data)
Toxizit?t LD50 orally in Rabbit: 1600 mg/kg
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
Sicherheit
P201 Vor Gebrauch besondere Anweisungen einholen.
P202 Vor Gebrauch alle Sicherheitshinweise lesen und verstehen.
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.
P308+P313 BEI Exposition oder falls betroffen: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen.

Tetrahydrofurfurylalkohol Chemische Eigenschaften,Einsatz,Produktion Methoden

ERSCHEINUNGSBILD

FARBLOSE HYGROSKOPISCHE FLüSSIGKEIT.

CHEMISCHE GEFAHREN

Bildung explosionsf?higer Peroxide wahrscheinlich. Reagiert sehr heftig mit starken Oxidationsmitteln, einigen N-Chlor- und N-Bromimiden. Feuer- und Explosionsgefahr.

ARBEITSPLATZGRENZWERTE

TLV nicht festgelegt (ACGIH 2005).
MAK nicht festgelegt (DFG 2005).

AUFNAHMEWEGE

Aufnahme in den K?rper durch Inhalation und über die Haut.

INHALATIONSGEFAHREN

Nur ungenügende Angaben vorhanden über die Geschwindigkeit, mit der eine gesundheitssch?dliche Konzentration in der Luft beim Verdampfen bei 20°C erreicht wird.

WIRKUNGEN BEI KURZZEITEXPOSITION

WIRKUNGEN BEI KURZZEITEXPOSITION:
Die Substanz reizt die Augen, die Haut und die Atemwege. M?glich sind Auswirkungen auf das Zentralnervensystem. Exposition gegenüber hohen Konzentrationen kann zu Bewusstlosigkeit führen.

LECKAGE

Ausgelaufene Flüssigkeit m?glichst in abdichtbaren Beh?ltern sammeln. Reste mit viel Wasser wegspülen.

R-S?tze Betriebsanweisung:

R36:Reizt die Augen.

S-S?tze Betriebsanweisung:

S39:Schutzbrille/Gesichtsschutz tragen.

Chemische Eigenschaften

Tetrahydrofurfuryl alcohol is a colorless to light yellow hygroscopic liquid that has a faint, warm, oily, caramellic odor with a coffee and nut-like flavor at very low levels (0.03 to 1 ppm). Miscible with water, ethanol, ether, acetone, chloroform and benzene, insoluble in paraffin hydrocarbons. It has an extensive history of use as a highly versatile, high purity solvent.

Occurrence

Reported found in shoyu (fermented soya hydrolysate), coffee and fresh mango.

Verwenden

Tetrahydrofurfuryl alcohol is used extensively in various industries as a high-purity, water miscible solvent, and as a chemical intermediate. It was used as Solvent for vinyl resins; dyes for leather; chlorinated rubber; cellulose esters; solvent softener for nylon; vegetable oils; coupling agent; organic synthesis.

Application

Tetrahydrofurfuryl alcohol (THFA) is generally regarded as a "green" solvent in industrial applications. THFA is a low cost, biodegradable solvent mainly used as a reactive diluent for epoxy resins and is a good solvent for many of the curative and catalysts used in epoxy formulations. It is also used in the following applications:
Tetrahydrofurfuryl alcohol undergoes chemoselective hydrogenolysis catalyzed by Rh/SiO2 modified with ReOx species to yield 1,5-pentanediol. It undergoes lanthanum-mediated Michael-type addition reaction with maleate to form alkoxybutanedioic acid.
Tetrahydrofurfuryl alcohol was used as refractive-index matching solvent to ensure hard sphere suspension of silica particles for rheological measurements.
Tetrahydrofurfuryl alcohol may be used as an analytical reference standard for the quantification of the analyte in rats and smoke flavoring from rice husk using chromatography techniques.

synthetische

Tetrahydrofurfuryl alcohol is produced by catalytic reduction of furfural with Raney-Ni; also by destructive hydrogenation of lignin.

Definition

ChEBI: Tetrahydrofurfuryl alcohol is a primary alcohol that is methanol in which one of the hydrogens of the methyl group has been replaced by a tetrahydrofuran-2-yl group. It has a role as a protic solvent. It is a primary alcohol and a member of oxolanes.

Allgemeine Beschreibung

Tetrahydrofurfuryl alcohol appears as a clear colorless liquid with a mild odor. Vapors are heavier than air.

Air & Water Reaktionen

Denser than water and soluble in water.

Reaktivit?t anzeigen

Acetyl bromide reacts violently with alcohols or water [Merck 11th ed. 1989]. Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid [Chem. Eng. News 45(43):73. 1967; J, Org. Chem. 28:1893. 1963]. Alkyl hypochlorites are violently explosive. They are readily obtained by reacting hypochlorous acid and alcohols either in aqueous solution or mixed aqueous- carbon tetrachloride solutions. Chlorine plus alcohols would similarly yield alkyl hypochlorites. They decompose in the cold and explode on exposure to sunlight or heat. Tertiary hypochlorites are less unstable than secondary or primary hypochlorites [NFPA 491 M 1991]. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence [Wischmeyer 1969].

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Carcinogenicity

Tetrahydro-2-furanmethanol was not mutagenic to S. typhimurium strains TA100, TA1535, TA1537, or TA98 in an in vitro gene mutation assay or to E. coliWP2uvrA/pKM101 with or withoutmetabolic activation. No chromosomal aberrations or polypoidy were observed when tetrahydro-2-furanmethanol was added to cultured Chinese hamster lung cells with or without metabolic activation .

Tetrahydrofurfurylalkohol Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Tetrahydrofurfurylalkohol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 440)Lieferanten
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97-99-4(Tetrahydrofurfurylalkohol)Verwandte Suche:


  • TETRAHYDROFURFURYL ALCOHOL FCC
  • tetrahydro-2-furylmethanol tetrahydrofurfuryl alcohol
  • 2-Oxolanemethanol
  • Tetrahydrofuran-2-methanol
  • Tetrahydrofurfuryl a
  • Tetrahydrofurfuryl alcohol, 98% 1LT
  • Tetrahydro furfuryl alcoh
  • NSC 15434
  • 2-Furanmethanol,tetrahydro-
  • 2-Hydroxymethyl-Tetrahydrofuran
  • alpha-Tetrahydrofurfuryl alcohol
  • Furfuryl alcohol, tetrahydro-
  • Oxolan-2-methanol
  • Qo tetrahydrofurfuryl alcohol
  • Qo thfa
  • qothfa
  • tetrahydro-2-furanmethano
  • Tetrahydro-2-furanylmethanol
  • Tetrahydro-2-furfuryl alcohol
  • tetrahydrofuran-2-yl-methanol
  • Tetrahydro-2-furanmethanol Tetrahydrofurfuryl alcohol THFA
  • FEMA 3056
  • HPTHFA
  • LABOTEST-BB LT02056580
  • TETRAHYDROFURFURYL ALCOHOL 98+%
  • Tetrahydrofurfuryl alcohol, 99+%
  • thfa (tetrahydrofurfuryl alcohol)
  • TETRAHYDROFURFURYL ALCOHOL (THFA)
  • TETRAHYDROFURFURALALCOHOL
  • tetrahydro-furfurylalcoho
  • Tetrahydrofurfurylalkohol
  • Tetrahydrofuryl carbinol
  • Tetrahydrofurylalkohol
  • tetrahydrofurylalkohol(czech)
  • tetrahydrofurylcarbinol
  • Tetrahydrofurylmethanol
  • TETRAHYDRO-2-FURANCARBINOL
  • (+/-)-TETRAHYDROFURFURYL ALCOHOL
  • TETRAHYDROFURFURYL ALCOHOL
  • THFA(R)
  • [(2R)-2-oxolanyl]methanol
  • TETRAHYDROFURYL ALCOHOL
  • (R)-Tetrahydro-2-furanmethanol
  • etrahydrofurfuryl alcohol
  • TETRAHYDROFURFURYL ALCOHOL, 98%TETRAHYDROFURFURYL ALCOHOL, 98%TETRAHYDROFURFURYL ALCOHOL, 98%
  • Tetrahydrofurfuryl Alcohol >
  • TETRAHYDROFURFURYL ALCOHOL FOR SYNTHESIS
  • Tetrahydrofurfuryl alcohol ISO 9001:2015 REACH
  • Tetrahydrofurfruyl Alcohol
  • 2-Hydroxymethyl oxolane
  • Oxolane-2-methanol
  • (tetrahydro-furan-2-yl)-methanol
  • Tetrahydro-2-furylmethanol
  • Tetrahydrofuran methanol
  • Tetrahydrofurfuryl
  • TETRAHYDRO-2-FURANMETHANOL
  • THFA
  • Tetrahydrofurfuryl alcohol,tetrahydro-2-furanmethanol
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