Omethoat (ISO)
|
|
- CAS-Nr.
- 1113-02-6
- Bezeichnung:
- Omethoat (ISO)
- Englisch Name:
- Omethoate
- Synonyma:
- S6876;s-6876;MODERN;B-45432;FOLIMAT;OMETHOAT;ent25,776;P=O-Rogor;bay 45432;OMETHOATE
- CBNumber:
- CB6109938
- Summenformel:
- C5H12NO4PS
- Molgewicht:
- 213.19
- MOL-Datei:
- 1113-02-6.mol
|
Omethoat (ISO) Eigenschaften
- Schmelzpunkt:
- -27.9°C
- Siedepunkt:
- 135°C
- Dichte
- 1.3200
- Dampfdruck
- 3.3×10-3Pa (20 °C)
- Flammpunkt:
- 100 °C
- storage temp.
- 0-6°C
- L?slichkeit
- Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
- Wasserl?slichkeit
- Miscible
- pka
- 14.40±0.46(Predicted)
- Aggregatzustand
- liquid
- BRN
- 1785256
- Stabilit?t:
- Hygroscopic
- CAS Datenbank
- 1113-02-6(CAS DataBase Reference)
- NIST chemische Informationen
- Omethoate(1113-02-6)
- EPA chemische Informationen
- Omethoate (1113-02-6)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Bildanzeige (GHS) |
|
Alarmwort |
Achtung |
Gefahrenhinweise |
Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
H300 |
Lebensgefahr bei Verschlucken. |
Akute Toxizit?t oral |
Kategorie 2 |
Achtung |
src="/GHS06.jpg" width="20" height="20" /> |
P264, P270, P301+P310, P321, P330,P405, P501 |
H311 |
Giftig bei Hautkontakt. |
Akute Toxizit?t dermal |
Kategorie 3 |
Achtung |
src="/GHS06.jpg" width="20" height="20" /> |
P280, P302+P352, P312, P322, P361,P363, P405, P501 |
H400 |
Sehr giftig für Wasserorganismen. |
Kurzfristig (akut) gew?ssergef?hrdend |
Kategorie 1 |
Warnung |
src="/GHS09.jpg" width="20" height="20" /> |
P273, P391, P501 |
|
Sicherheit |
P264 |
Nach Gebrauch gründlich waschen. |
P264 |
Nach Gebrauch gründlich waschen. |
P270 |
Bei Gebrauch nicht essen, trinken oder rauchen. |
P273 |
Freisetzung in die Umwelt vermeiden. |
P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
P301+P310 |
BEI VERSCHLUCKEN: Sofort GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen. |
|
Omethoat (ISO) Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R21:Gesundheitssch?dlich bei Berührung mit der Haut.
R25:Giftig beim Verschlucken.
R50:Sehr giftig für Wasserorganismen.
S-S?tze Betriebsanweisung:
S1/2:Unter Verschluss und für Kinder unzug?nglich aufbewahren.
S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Verwenden
Omethoate is a systemic insecticide used for the control of (mostly)
sucking insects and mites in a wide variety of crops.
Kontakt-Allergie
Contact dermatitis from omethoate-dimethoxon is rare.
Stoffwechselwegen
Omethoate is the P=O analogue (oxon) of dimethoate. Dimethoate is
metabolised via oxidative desulfuration to omethoate which is the active
anti-acetylcholinesterase metabolite. This biotransformation occurs in all
media: hence the metabolic pathways of both compounds have much in
common. However, degradative pathways acting directly on dimethoate
such as O-demethylation, N-demethylation and hydrolysis of the amide
function mean that the balance between activation and degradative
metabolism will influence their respective selective toxicities. In mammals
there are two main routes of degradation: (i) glutathione transferase
mediated O-demethylation (ii) hydrolysis to N-methylthioglycolamide
which is S-methylated by S-adenosylmethionine and subsequently
thiooxidised. In soil and plants the N-methylthioglycolamide moiety
formed from the hydrolysis of omethoate undergoes a complex series
of C
1, C
2 and C
3 biotransformations ultimately leading to oxalate and
citrate respectively and total degradation to C0
2. The information
reported below is derived largely from an evaluation prepared by the
UK MAFF Pesticide Safety Directorate (PSD, 1993).
Stoffwechsel
Orally administered omethoate to rats is
rapidly metabolized and excreted in the urine; the main
metabolites are O-demethylomethoate and N-methyl-2-
methylsulfinylacetamide. O-Demethylation and hydrolysis
of the P?S bond are main degradation routes both in
mammals and plants. Omethoate is rapidly degraded in
soils with DT
50 of a few days.
Omethoat (ISO) Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
1113-02-6(Omethoat (ISO))Verwandte Suche:
- Omethoate E.C.,penetrating
- omethoatge
- B-45432
- O,O-dimethyl S-methylcarbamoylmethyl phosphorothioate,omethoate (ISO)
- Omethoate Standard
- 2-(dimethoxyphosphorylthio)-N-methyl-acetamide
- 2-dimethoxyphosphorylsulfanyl-N-methylacetamide
- 2-dimethoxyphosphorylsulfanyl-N-methyl-ethanamide
- Folimat Dimethoate-met
- Omethoate Solution, 100ppm
- 2-dimethoxyphosphinoylthio-n-methylacetamide
- Acetamide, 2-mercapto-N-methyl-, S-ester with O,O-dimethyl phosphorothioate
- acetamide,2-mercapto-n-methyl-,s-esterwitho,o-dimethylphosphorothioate
- BAYER 45,432
- Bayer 45432
- bayer45,432
- bayers-6876
- Dimethoate Oxygen analog
- Dimethoate PO isologue
- Dimethoate-met
- dimethoateoxygenanalog
- dimethoatepoisologue
- dimethoxane(omethoate)
- Dimethyl-S-(N-methyl-carbamoyl-methyl)phosphorothiolate
- ENT 25,776
- ent25,776
- Folimat 4E
- imethoate oxon
- O,O-Dimethyl S-(2-(methylamino)-2-oxoethyl)phosphorothioate
- O,O-Dimethyl S-(N-methylcarbamoylmethyl) phosphorothiolate
- O,O-Dimethyl S-(N-methylcarbamoylmethyl) thiophosphate
- o,o-Dimethyl S-[2-(methylamino)-2-oxoethyl] thiophosphate
- o,o-dimethylphosphorothioates-esterwith2-mercapto-n-methylacetamide
- O,O-Dimethyl-S-((N-methyl-carbamoyl)-methyl)-monothiofosfaat
- o,o-dimethyls-(2-(methylamino)-2-oxoethyl)phosphorothioate
- O,O-Dimethyl-S-(2-oxo-3-azabutyl)-monothiophosphate
- O,O-Dimethyl-S-(N-methylaminoformylmethyl)phosphorothioate
- o,o-dimethyl-s-(n-methyl-carbamoyl)-methyl-monothiophosphat
- O,O-Dimethyl-S-(N-methyl-carbamoyl)-methyl-monothiophosphate
- o,o-dimethyls-(n-methylcarbamoylmethyl)phosphorothiolate
- o,o-dimethyl-s-(n-methyl-carbamoyl-methyl)-thiolphosphat
- O,O-Dimethyl-S-(N-methyl-carbamoyl-methyl)-thiolphosphate
- o,o-dimethyls-(n-methylcarbamoylmethyl)thiophosphate
- O,O-Dimethyl-S-[2-(methylamino)-2-oxoethyl]phosphorothioate
- O,O-Dimetil-S-(N-metil-carbamoil)-metil-monotiofosfato
- O-Analog of dimethoate
- o-analogofdimethoate
- P=O-Rogor
- Phosphorothioic acid, O,O-dimethyl ester, S-ester with 2-mercapto-N-methylacetamide
- Phosphorothioicacid,esters,O,O-dimethyl-S-[2(methylamino)-2-oxoethyl]ester
- phosphorothioicacid,o,o-dimethylester,s-esterwith2-mercapto-n-methylaceta
- PO-Dimethoate
- S6876
- s-6876
- Thiophosphate de O,O-dimethyle et de S-(N-methylcarbamoyl) methyle
- thiophosphatedeo,o-dimethyleetdes-(n-methylcarbamoyl)methyle
- bay 45432
- FOLIMAT