Diethylene glycol diethyl ether Chemische Eigenschaften,Einsatz,Produktion Methoden
ERSCHEINUNGSBILD
FARBLOSE VISKOSE FLüSSIGKEIT.
CHEMISCHE GEFAHREN
Bildung explosionsf?higer Peroxide wahrscheinlich. Reagiert mit starken Oxidationsmitteln.
ARBEITSPLATZGRENZWERTE
TLV nicht festgelegt (ACGIH 2005).
MAK nicht festgelegt (DFG 2005).
INHALATIONSGEFAHREN
Nur ungenügende Angaben vorhanden über die Geschwindigkeit, mit der eine gesundheitssch?dliche Konzentration in der Luft beim Verdampfen bei 20°C erreicht wird.
WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION: Die Substanz reizt leicht die Augen und die Haut.
WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION
Die Flüssigkeit entfettet die Haut.
LECKAGE
Ausgelaufene Flüssigkeit m?glichst in abdichtbaren Beh?ltern sammeln. Reste mit viel Wasser wegspülen.
R-S?tze Betriebsanweisung:
R36:Reizt die Augen.
R19:Kann explosionsf?hige Peroxide bilden.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Beschreibung
Diethylene glycol diethyl ether, or 2-Ethoxyethyl ether, is an organic solvent used to study the activities of enzymes in aqueous organic mixtures. Diethylene glycol diethyl ether is a solvent for reactions performed at higher temperatures. It is involved in the preparation of nitrocellulose, resins, and adhesives. It is a scrubbing medium to absorb carbonyl sulfide (COS), an impurity in petroleum refineries. It could be used as an absorbent for CO2. This absorbent has a high boiling point (462 K, in SciFinder), indicating that energy for absorbent regeneration and loss were saved. In addition, this absorbent is chemically and thermally stable, non-corrosive, and has low density and viscosity. It is rich in philic-CO2 groups, which makes Diethylene glycol diethyl ether more effective for CO2 capture. Li et al. found that carbonyl and ether groups in the absorbents improved CO2 solubility, and the carbonyl group was more effective than the ether group[1].
Chemische Eigenschaften
colourless liquid
Verwenden
Solvent; high boiling reaction medium.
synthetische
2-Ethoxyethyl ether could be synthesized by reacting 1, 4-dioxane with diethyl ether. ZSM-5-type zeolite was used as the catalyst. This reaction is performed in an autoclave.
Definition
ChEBI: A polyether that consists of undecane in which the carbon atoms at positions 3, 6 and 9 are replaced by oxygen atoms.
Allgemeine Beschreibung
Clear colorless viscous liquid.
Air & Water Reaktionen
Highly flammable. May be sensitive to prolonged exposure to air. Can form explosive peroxides. Vapor-air mixtures are explosive above the flash point. Water soluble.
Reaktivit?t anzeigen
2-Ethoxyethyl ether is incompatible with strong acids. 2-Ethoxyethyl ether is also incompatible with strong oxidizing agents.
Brandgefahr
2-Ethoxyethyl ether is combustible.
Sicherheitsprofil
Moderately toxic by
ingestion. An experimental teratogen. Other
experimental reproductive effects. An eye
irritant. Flammable when exposed to heat or
flame. When heated to decomposition it
emits acrid smoke and irritating fumes. See
also GLYCOL ETHERS.
l?uterung methode
Dry the ether with MgSO4, then CaH2 or LiAlH4, under N2. If sodium is used, the ether should be redistilled alone to remove any products which may be formed by the action of sodium on the ether. As a preliminary purification, the crude ether (2L) can be refluxed for 12hours with 25mL of conc HCl in 200mL of water, under reduced pressure, with slow passage of N2 to remove aldehydes and other volatile substances. After cooling, add sufficient solid KOH pellets (slowly and with shaking until no more dissolves) to give two liquid phases. The upper of these is decanted, dried with fresh KOH pellets, decanted, then refluxed over, and distilled from sodium. It can be passed through (alkaline) alumina prior to purification. [Beilstein 1 IV 2394.]
Diethylene glycol diethyl ether Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
