1,3-Dimethoxybenzol
|
|
- CAS-Nr.
- 151-10-0
- Bezeichnung:
- 1,3-Dimethoxybenzol
- Englisch Name:
- 1,3-Dimethoxybenzene
- Synonyma:
- 1,3-DIMETHOXYBENZENE;M-DIMETHOXYBENZENE;RESORCINOL DIMETHYL ETHER;phenylene ether;1,3-methoxybenzenel;FEMA 2385;3-METHOXYANISOLE;M-METHOXYANISOLE;M-xylylene ether;Dimethylresorinol
- CBNumber:
- CB4234977
- Summenformel:
- C8H10O2
- Molgewicht:
- 138.16
- MOL-Datei:
- 151-10-0.mol
|
1,3-Dimethoxybenzol Eigenschaften
- Schmelzpunkt:
- -52°C
- Siedepunkt:
- 85-87 °C7 mm Hg(lit.)
- Dichte
- 1.055 g/mL at 25 °C(lit.)
- Brechungsindex
- n20/D 1.524(lit.)
- FEMA
- 2385 | M-DIMETHOXYBENZENE
- Flammpunkt:
- 190 °F
- storage temp.
- Sealed in dry,Room Temperature
- L?slichkeit
- Miscible with toluene.
- Aggregatzustand
- Liquid
- Farbe
- Clear colorless to slightly brown
- Geruch (Odor)
- at 1.00 % in dipropylene glycol. acid fruity nutmeg neroli
- Geruchsart
- medicinal
- Wasserl?slichkeit
- 1.216g/L(25 ºC)
- JECFA Number
- 1249
- BRN
- 878582
- Dielectric constant
- 4.5(23.0℃)
- LogP
- 2.21
- CAS Datenbank
- 151-10-0(CAS DataBase Reference)
- NIST chemische Informationen
- Benzene, 1,3-dimethoxy-(151-10-0)
- EPA chemische Informationen
- m-Dimethoxybenzene (151-10-0)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher |
Xi |
|
|
R-S?tze: |
36/37/38 |
|
|
S-S?tze: |
24/25 |
|
|
RIDADR |
NA 1993 / PGIII |
|
|
WGK Germany |
2 |
|
|
RTECS-Nr. |
CZ6474000 |
|
|
Hazard Note |
Irritant |
|
|
TSCA |
Yes |
|
|
HS Code |
29093090 |
|
|
Toxizit?t |
mouse,LD50,intraperitoneal,900mg/kg (900mg/kg),BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)BEHAVIORAL: ATAXIABEHAVIORAL: TREMOR,Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 46, Pg. 185, 1957. |
|
|
Bildanzeige (GHS) |
|
Alarmwort |
Warnung |
Gefahrenhinweise |
Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
H227 |
Combustible liquid |
Flammable liquids |
Category 4 |
Warnung |
|
P210, P280, P370+P378, P403+P235,P501 |
|
Sicherheit |
P210 |
Von Hitze, hei?en Oberfl?chen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen. |
P261 |
Einatmen von Staub vermeiden. |
P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
P370+P378 |
Bei Brand: zum L?schen verwenden. |
P403+P235 |
An einem gut belüfteten Ort aufbewahren. Kühl halten. |
P501 |
Inhalt/Beh?lter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen. |
|
1,3-Dimethoxybenzol Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S24/25:Berührung mit den Augen und der Haut vermeiden.
Beschreibung
1,3-Dimethoxybenzene, also known as dimethyl resorcinol or 3-methoxyanisole, belongs to the class of organic compounds known as dimethoxybenzenes. These organic aromatic compounds contain a monocyclic benzene moiety carrying two methoxy groups. 1,3-Dimethoxybenzene has been used in the synthesis of novel oxathiane spiroketal donors. It forms pi- and O-ylidic complexes with dichlorocarbene (CCl(2)).
Chemische Eigenschaften
m-Dimethoxybenzene has a very powerful sweet-earthy, intensely, nut-like aroma.
Occurrence
Reported found in Gruyere de Comte, blue cheeses, filberts and cognac
Verwenden
1,3-Dimethoxybenzene is used for the preparation of oxathiane spiroketal donors. It is also used for the formation of pi- and O-ylidic complexes with dichlorocarbene. Further, it acts as a flavoring agent.
synthetische
From resorcinol by methylation using dimethyl sulfate and alka
Vorbereitung Methode
1,3-Dimethoxybenzene can be produced 1) by Methylation of Resorcinol in weak
aqueous alkali with Dimethylsulfate.
2) from Methanol and Resorcinol with Potassium hydrosuIfate or Sodium naphthalene sulfonate as dehydrating agent.
Allgemeine Beschreibung
1,3-Dimethoxybenzene can be used as a flavoring agent in the food industry. It is reported to be found in the volatiles of port wine and Roquefort cheese.
l?uterung methode
Extract it with aqueous NaOH, and water, then dry it. Fractionally distil it from BaO or Na. [Beilstein 6 IV 5663.]
1,3-Dimethoxybenzol Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
1,3-Dimethoxybenzol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 551)Lieferanten
151-10-0(1,3-Dimethoxybenzol)Verwandte Suche:
- 1,3-Dimethoxybenzene, 97+%
- 3-DiMethoxybenzene
- Benzene,1,3-dimethoxy-
- Dimethylether resorcinolu
- dimethyletherresorcinolu
- Dimethylresorinol
- m-dimethoxy-benzen
- Dimethylresorcinol, Resorcinol dimethyl ether
- 1,3-Dimethoxybenzeen
- Dimethylether resorcinolu (Czech)
- 1,3-dimethyoxy benzene
- Resorcinol dimethlyether
- 1,3-DiMethoxybenzene, 99% 100GR
- 1,3-DiMethoxybenzene, 99% 5GR
- RESORCINOL DIMETHYL ETHER FOR SYNTHESIS
- M-DiMethoxy benze
- 1,3-DiMethoxybenzene >=98%
- FEMA 2385
- DIMETHYLRESORCINOL
- 3-METHOXYANISOLE
- RESCORCINOL DIMETHYL ETHER
- M-PHENYLENEDIMETHYL ETHER
- M-METHOXYANISOLE
- 1,3-dimethoxy-benzen
- Benzene, m-dimethoxy-
- M-DIMETHOXYBENZENE 98+%
- 1,3-Dimethoxybenzene99%
- META-DIMETHOXYBENZENE
- 1,3-Dimethoxybenzol
- RESORCIN-DIMETHYLETHER
- 1,3-DIMETHOXYBENGENE
- M-xylylene ether
- Phloroglucinol Impurity 42
- 1,3-Dimethoxybenzene >
- Dimethoxybenzene USP/EP/BP
- meta-dimethyl hydroquinone
- TIANFU-CHEM CAS NO.151-10-0 1,3-Dimethoxybenzene
- 1,3-methoxybenzenel
- phenylene ether
- M-DIMETHOXYBENZENE
- 1,3-DIMETHOXYBENZENE
- RESORCINOL DIMETHYL ETHER
- 151-10-0
- 150-10-0
- C8H1O2
- 13C6H4OCH32
- C6H4OCH32
- Oxygen Compounds
- Organic Building Blocks
- Ethers
- Building Blocks
- Benzene derivates
- Aromatic Ethers