Fenchlorphos (ISO)
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Fenchlorphos (ISO) Eigenschaften
- Schmelzpunkt:
- 41.0℃
- Siedepunkt:
- 97℃
- Dichte
- 1.485 g/cm3 (25 ºC)
- Dampfdruck
- 5.29 at 20 °C, 18.6 at 30 °C (Freed et al., 1977)
- Brechungsindex
- 1.5585 (589.3 nm 20℃)
- Flammpunkt:
- -18 °C
- storage temp.
- APPROX 4°C
- L?slichkeit
- Soluble in acetone, carbon tetrachloride, ether, kerosene, methylene chloride, and toluene (Windholz et al., 1983)
- Aggregatzustand
- solid
- Farbe
- White to light brown, waxy solid
- Wasserl?slichkeit
- 40mg/L(room temperature)
- Merck
- 13,8337
- BRN
- 1885571
- Henry's Law Constant
- 8.46 at 25 °C (approximate - calculated from water solubility and vapor pressure)
- Expositionsgrenzwerte
- NIOSH REL: TWA 10 mg/m3, IDLH 300 mg/m3; OSHA PEL: TWA 15 mg/m3; ACGIH TLV: TWA 10 mg/m3.
- EPA chemische Informationen
- Ronnel (299-84-3)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher | Xn,N,F | ||
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R-S?tze: | 21/22-50/53-67-65-38-11 | ||
S-S?tze: | 25-36/37-60-61-62 | ||
RIDADR | UN 1145 3/PG 2 | ||
OEB | B | ||
OEL | TWA: 10 mg/m3 | ||
WGK Germany | 3 | ||
RTECS-Nr. | TG0525000 | ||
HS Code | 29201900 | ||
Giftige Stoffe Daten | 299-84-3(Hazardous Substances Data) | ||
Toxizit?t | LD50 in male, female rats (mg/kg): 1250, 2630 orally (Gaines) | ||
IDLA | 300 mg/m3 |
Bildanzeige (GHS) |
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Sicherheit |
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Fenchlorphos (ISO) Chemische Eigenschaften,Einsatz,Produktion Methoden
ERSCHEINUNGSBILD
WEISSES PULVER.CHEMISCHE GEFAHREN
Zersetzung beim Erhitzen unter Bildung giftiger Rauche mit Chlorwasserstoff, Phosphoroxiden und Schwefeloxiden.ARBEITSPLATZGRENZWERTE
TLV: 10 mg/m?(als TWA); Krebskategorie A4 (nicht klassifizierbar als krebserzeugend für den Menschen); BEI vorhanden; (ACGIH 2005).MAK nicht festgelegt (DFG 2005).
AUFNAHMEWEGE
Aufnahme in den K?rper durch Inhalation des Aerosols, über die Haut und durch Verschlucken.INHALATIONSGEFAHREN
Verdampfen bei 20°C vernachl?ssigbar; eine bel?stigende Partikelkonzentration in der Luft kann jedoch beim Versprühen oder Dispergieren schnell erreicht werden, vor allem als Pulver.WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION:M?glich sind Auswirkungen auf das Nervensystem mit nachfolgenden Kr?mpfen. Cholinesterasehemmer. Die Auswirkungen treten u.U. verz?gert ein. ?rztliche Beobachtung notwendig.
WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION
Tierversuche zeigen, dass die Substanz m?glicherweise Fehlbildungen bei Neugeborenen hervorrufen kann.LECKAGE
NICHT in die Kanalisation spülen. NICHT in die Umwelt gelangen lassen. Verschüttetes Material in abdichtbaren Beh?ltern sammeln; falls erforderlich durch Anfeuchten Staubentwicklung verhindern. Reste sorgf?ltig sammeln. An sicheren Ort bringen. Pers?nliche Schutzausrüstung: Atemschutzger?t, P2-Filter für sch?dliche Partikel.R-S?tze Betriebsanweisung:
R21/22:Gesundheitssch?dlich bei Berührung mit der Haut und beim Verschlucken.R50/53:Sehr giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.
R67:D?mpfe k?nnen Schl?frigkeit und Benommenheit verursachen.
R65:Gesundheitssch?dlich: kann beim Verschlucken Lungensch?den verursachen.
R38:Reizt die Haut.
R11:Leichtentzündlich.
S-S?tze Betriebsanweisung:
S25:Berührung mit den Augen vermeiden.S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S60:Dieses Produkt und sein Beh?lter sind als gef?hrlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S62:Bei Verschlucken kein Erbrechen herbeiführen. Sofort ?rztlichen Rat einholen und Verpackung oder dieses Etikett vorzeigen.
Chemische Eigenschaften
Powder or granules. Insoluble in water; soluble in most organic solvents.Verwenden
Insecticide.Allgemeine Beschreibung
White to light-tan crystalline solid. Mp: 41° C, Density :1.49 g cm-3 at 25°C. Biocidal (toxic to all animal life in differing degrees) by its action as a cholinesterase inhibitor. Used as an insecticide. Degrades readily in the environment by hydrolysis and oxidation.Reaktivit?t anzeigen
FENCHLORPHOS is non-flammable and non-combustible. Decomposes with heating to evolve toxic and corrosive vapors (hydrogen chloride, phosphorus oxides, sulfur oxides). Incompatible with strong oxidizing agents.Hazard
Toxic by ingestion and inhalation. Cholinesterase inhibitor, use may be restricted. Questionable carcinogen.Health Hazard
Ronnel is a weak cholinesterase inhibitor and has low toxicity. On both single and repeated doses, ronnel affects the pseudoesterase of the plasma rather than the true acetylcholinesterase of the red blood cells.Ronnel has not been shown to potentiate the effect of other commonly used organophosphorus insecticides.Sicherheitsprofil
Poison by ingestion and intraperitoneal routes. Moderately toxic by skin contact. A cholinesterase inhibitor. An experimental teratogen. Experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits very toxic fumes of Cl-, POx, and SOx. See also PARATHION and CHLOROPHENOLS.m?gliche Exposition
Ronnel is both an organochlorine and organophosphorus compound; potential danger to those involved in manufacture, formulation and application of this insecticide for farm (livestock) and household uses. Degrades readily in the environment by hydrolysis and oxidation .Environmental Fate
Chemical/Physical. Though no products were identified, the reported hydrolysis halflife at pH 7.4 and 70°C using a 1:4 ethanol/water mixture is 10.2–10.4 hours (Freed et al., 1977). Ronnel decomposed at elevated temperatures on five clay surfaces, each treated with hydrogen, calcium, magnesium, aluminum and iron ions. At temperatures <950°C (125, 300 and 750°C), bentonite clays impregnated with technical ronnel (18.6 wt %) decomposed to 2,4,5-trichlorophenol and a rearrangement product tentatively identified as O-methyl S-methyl-O-(2,4,5-trichlorophenyl) phosphorothioate (Rosenfield and Van Valkenburg, 1965). At 950°C, only the latter product formed. It was postulated that this compound resulted from an acid-catalyzed molecular rearrangement reaction. Ronnel also undergoes base-catalyzed hydrolysis at elevated temperatures. Products include methanol and a new compound that is formed via cleavage of a methyl group from one of the methoxy groups, which is then bonded to the sulfur atom (Rosenfield and Van Valkenburg, 1965).Ronnel is stable to hydrolysis over the pH range of 5–6 (Mortland and Raman, 1967). However, in the presence of a Cu(II) salt (as cupric chloride) or when present as the exchangeable Cu(II) cation in montmorillonite clays, ronnel is completely hydrolyzed via first-order kinetics in <24 hours at 20°C. The calculated half-life of ronnel at 20°C for this reaction is 6.0 hours. It was suggested that decomposition in the presence of Cu(II) was a result of coordination of the copper atom through the oxygen or sulfur on the phosphorus atom resulting in the cleavage of the side chain containing the phosphorus atom forming O,O-ethyl-O-phosphorothioate and 1,2,4-trichlorobenzene (Mortland and Raman, 1967).
Emits very toxic fumes of chlorides, sulfur and phosphorus oxides when heated to decomposition (Lewis, 1990).
Versand/Shipping
UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.Inkompatibilit?ten
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo- sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Store at temperatures <25-30℃. Organothiophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrideds and active metals. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxidesWaste disposal
Incineration with added flam- mable solvent in furnace equipped with afterburner and alkali scrubber . In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesti- cide containers. Must be disposed properly by following package label directions or by contacting your local or fed- eral environmental control agency, or by contacting your regional EPA office.Fenchlorphos (ISO) Upstream-Materialien And Downstream Produkte
Upstream-Materialien
2,4,5-Trichlorphenol
o-(2,4,5-trichlorophenyl) phosphorodichloridothioate
Parathion-methyl (ISO)
DICAPTHON
O,O-Dimethyl(chlor)thiophosphat
Fenitrothion (ISO)
Downstream Produkte
Fenchlorphos (ISO) Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 102)Lieferanten
Firmenname | Telefon | Land | Produktkatalog | Edge Rate | |
---|---|---|---|---|---|
SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 |
sales@sdzschem.com | China | 2930 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28172 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22963 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 |
sales@chemdad.com | China | 39894 | 58 |
TargetMol Chemicals Inc. | +1-781-999-5354 +1-00000000000 |
marketing@targetmol.com | United States | 32159 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 |
sales@tnjchem.com | China | 34563 | 58 |
AFINE CHEMICALS LIMITED | +86-0571-85134551 |
sales@afinechem.com | China | 15350 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 |
info@dycnchem.com | China | 52849 | 58 |
Hangzhou MolCore BioPharmatech Co.,Ltd. | +86-057181025280; +8617767106207 |
sales@molcore.com | China | 49734 | 58 |
GIHI CHEMICALS CO.,LIMITED | +8618058761490 |
info@gihichemicals.com | China | 49984 | 58 |
299-84-3(Fenchlorphos (ISO))Verwandte Suche:
Etrimfos
O,O-Dimethyl-O-(p-N,N-dimethylsul-famoyl)phenylthiophosphat
Dimethyl-2,4,5-trichlorophenylphosphat
3,4-Dichlorphenol
Fenchlorphos (ISO)
2,5-Dichlorphenol
2,4,5-Trichlorphenol
- KORLAN(R)
- ETROLENE
- FENCHLORPHOS
- DOW ET-14
- NANKOR(R)
- RONNEL
- RONNEL(R)
- O,O-DIMETHYL O-(2,4,5-TRICHLOROPHENYL) PHOSPHOROTHIATE
- O,O-DIMETHYL-O-[2,4,5-TRICHLOROPHENYL]-PHOSPHOROTHIOATE
- Blitex
- Dermafos
- Dermafosu
- dermafosu(polish)
- Dermaphos
- Dimethyl (2,4,5-trichlorophenyl) phosphorothionate
- Dimethyl O-(2,4,5-trichlorophenyl) thiophosphate
- Dimethyl trichlorophenyl thiophosphate
- dimethyltrichlorophenylthiophosphate
- Fenchlorfosu
- fenchlorfosu(polish)
- Fenchlorophos
- Fenclofos
- Gesektin K
- Karlan
- Korlan
- Korlane
- Moor Man's Medicated Rid-Ezy
- moorman’smedicatedrid-ezy
- Nanchor
- Nanker
- Nankor
- O-(2,4,5-Trichloor-fenyl)-O,O-dimethyl-monothiofosfaat
- O-(2,4,5-Trichlor-phenyl)-O,O-dimethyl-monothiophosphat
- O-(2,4,5-Tricloro-fenil)-O,O-dimetil-monotiofosfato
- o-(2,4,5-triclorofenil)-o,o-dimetil-monotiofosfato
- O,O-Dimethyl O-(2,4,5-trichlorophenyl) thiophosphate
- o,o-Dimethyl O-(2,4,5-trichlorophenyl)ester
- o,o-dimethylo-(2,4,5-trichlorophenyl)thiophosphate
- O,O-Dimethyl-O-(2,4,5-trichlorphenyl)-thionophosphat
- O,O-Dimethyl-O-2,4,5-trichlorophenylphosphorothionate
- OMS 123
- oms123
- Phenchlorfos
- Phenol, 2,4,5-trichloro-, O-ester with O,O-dimethyl phosphorothioate
- phenol,2,4,5-trichloro-,o-esterwitho,o-dimethylphosphorothioate
- Phosphorothioic acid, O,O-dimethyl O-(2,4,5-trichlorophenyl) ester
- phosphorothioicacid,O-(2,4,5-trichlorphenyl)-,O,O-dimethylester
- phosphorothioicacid,o,o-dimethylo-(2,4,5-trichlorophenyl)ester
- PhosphorothionicacidO,O-dimethyl-O-(2,4,5-trichlorophenyl)ester
- Phosphorthioic acid
- Remelt
- Ronne
- Rovan
- smear
- Thiophosphate de o,o-dimethyle et de o-(2,4,5-trichlorophenyle)
- thiophosphatedeo,o-dimethyleetdeo-(2,4,5-trichlorophenyle)
- thiophosphatedeo,o-dimethyleneetdeo-(2,4,5-trichlorophenyle)(french)
- Trichlormetaphos