Cobaltoceniumhexafluorophosphat(1-)
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- CAS-Nr.
- 12427-42-8
- Bezeichnung:
- Cobaltoceniumhexafluorophosphat(1-)
- Englisch Name:
- COBALTOCENE HEXAFLUOROPHOSPHATE
- Synonyma:
- COBALTOCENE HEXAFLUOROPHOSPHATE;BIS(CYCLOPENTADIENYL)COBALT(III);COBALTOCENIUM HEXAFLUOROPHOSPHATE;COBALTICINIUM HEXAFLUOROPHOSPHATE;Cobalticiniumhexafluorophosphate,98%;Cobaltocenium hexafluorophosphate,98%;cobaltocenium hexafluorophosphate(1-);Dicyclopentadienylcobalt hexafluorophosphate;BIS(CYCLOPENTADIENYL)COBALT HEXAFLUOROPHOSPHATE;Bis(cyclopentadienyl)cobalt(1+) hexafluorophosphate
- CBNumber:
- CB2314446
- Summenformel:
- C10H10CoF6P10*
- Molgewicht:
- 334.08
- MOL-Datei:
- 12427-42-8.mol
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Cobaltoceniumhexafluorophosphat(1-) Eigenschaften
- L?slichkeit
- slightly sol. in Dimethylformamide
- Aggregatzustand
- crystal
- Farbe
- yellow
Cobaltoceniumhexafluorophosphat(1-) Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R20/21/22:Gesundheitssch?dlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
Chemische Eigenschaften
yellow powder
Verwenden
Uses:
- Cocatalyst for Heck reaction of aryl iodides with alkenes using palladium as catalyst in water
- Reactant for modification of organometallic electrodes surfaces through cathodic reduction
- Reactant in synthesis and solution self-assembly of side-chain cobaltocenium-containing block copolymers
Synthese
Cobaltocene hexafluorophosphate is readily synthesized from cobalt(II) salts + CpNa, followed by air + HPF6 or NH4PF6. Salts with a wide range of other counterions may be obtained similarly. The cobaltocenium ion
[1] may be precipitated from aqueous solution by a variety of large anions. In addition to PF6 -, convenient counterions include Br3 - and I3 -. The simple halides are hygroscopic, but may be obtained in anhydrous form by removal of water under vacuum.
Cobaltoceniumhexafluorophosphat(1-) Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Cobaltoceniumhexafluorophosphat(1-) Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 69)Lieferanten
12427-42-8(Cobaltoceniumhexafluorophosphat(1-))Verwandte Suche:
- BIS(CYCLOPENTADIENYL)COBALT(III)
- Cobalticiniumhexafluorophosphate,98%
- Bis(cyclopentadienyl)cobalt (II) hexafluorophosphate
- Cobaltocenium hexafluorophosphate,98%
- Bis(cyclopentadienyl)cobalt(1+) hexafluorophosphate
- Bis(cyclopentadienyl)cobalt(1+) hexafluorophosphate(1-)
- Dicyclopentadienylcobalt hexafluorophosphate
- Dicyclopentadienylcobalt(1+) hexafluorophosphate(1-)
- COBALTICINIUM HEXAFLUOROPHOSPHATE
- COBALTOCENE HEXAFLUOROPHOSPHATE
- COBALTOCENIUM HEXAFLUOROPHOSPHATE
- BIS(CYCLOPENTADIENYL)COBALT HEXAFLUOROPHOSPHATE
- BIS(CYCLOPENTADIENYL)COBALT(III) HEXAFLUOROPHOSPHATE
- cobaltocenium hexafluorophosphate(1-)
- Bis(cyclopentadienyl)cobalt(III)Hexafluorophosphate>
- COBALTOCENE HEXAFLUOROPHOSPHATE ISO 9001:2015 REACH
- 12427-42-8
- C10H10CoF6P10
- C5H52CoPF6
- C10H10CoF6P
- C10H10CoPF6
- Classes of Metal Compounds
- Titanocene, etc.
- Transition Metal Compounds
- Co (Cobalt) Compounds
- Metallocenes
- Catalysis and Inorganic Chemistry
- halometallate salts
- Classes of Metal Compounds
- Co (Cobalt) Compounds
- Metallocenes
- Titanocene, etc.
- Transition Metal Compounds
- Catalysis and Inorganic Chemistry
- Chemical Synthesis
- Cobalt