| Identification | More | [Name]
1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE | [CAS]
97239-80-0 | [Synonyms]
1,1'-BIS(DI-I-PROPYLPHOSPHINO)FERROCENE
1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE
BIS[(DIISOPROPYLPHOSPHINO)CYCLOPENTADIENYL]IRON
1,1'-Bis(di-i-propylphosphino)ferrocene,min.98%
1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% | [EINECS(EC#)]
677-500-6 | [Molecular Formula]
C22H36FeP2 10* | [MDL Number]
MFCD02684559 | [Molecular Weight]
418.31 | [MOL File]
97239-80-0.mol |
| Chemical Properties | Back Directory | [Appearance]
orange crystalline powder | [Melting point ]
50-52 °C(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Inert atmosphere,2-8°C | [form ]
Powder | [color ]
orange-yellow | [Water Solubility ]
Insoluble in water. | [InChI]
InChI=1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3; | [InChIKey]
LPBBEMRSRONKMN-UHFFFAOYSA-N | [SMILES]
P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:7,8,9,10,11,19,20,21,22,23| | [CAS DataBase Reference]
97239-80-0(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [TSCA ]
No | [HS Code ]
29319090 |
| Hazard Information | Back Directory | [Chemical Properties]
orange crystalline powder | [Uses]
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined. |
| Questions And Answer | Back Directory | [Reaction]
- Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes
- Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO.
- Pd-catalyzed carbonylative ɑ-arylation of ketones with aryl iodides
- Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters
- Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation
- Ligand for ruthenium-catalyzed C—C coupling reactions of fluorinated alcohols with allenes.
- Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents.
 
|
|
|